The invention relates to the technical field of metallurgical
processing, in particular to a preparation method of a long-service-life doped
tungsten bar. The problem that an existing
tungsten bar is short in service life is solved. The preparation method comprises the following steps: adding a
doping material and a composite surfactant into blue
tungsten oxide, uniformly mixing, adding a combined binder after
hydrogen reduction, carrying out layered pressing in a layered filling and multi-point filling manner to obtain a
green body, and carrying out high-temperature
sintering and acid
pickling in stages; and
coating aluminum
oxide on the surface of the pickled semi-finished product by taking trimethylaluminum and
oxygen as raw materials to obtain the long-service-life doped tungsten bar. The density and high-temperature
oxidation resistance of the doped tungsten bar are improved by changing the adding amount of blue
tungsten oxide, the component proportion of the
doping material and the adding amount of the
doping material, the combined binder and the composite surfactant and adjusting the pressure of each time of pressing, the temperature and time of different stages of high-temperature
sintering and the
deposition temperature and time during aluminum
oxide coating; and the effect of prolonging the service life of the doped tungsten bar is achieved.