The invention relates to a lithium-ion power battery electrolyte. The lithium-ion power battery electrolyte comprises four components, namely, quaternary ammonium chloride, a hydrogen bond donor, lithium salt electrolyte and polyethylene glycol PEG, wherein the mole ratio of the quaternary ammonium chloride and the hydrogen bond donor is (1 to1)-(1to3); the concentration of the lithium salt electrolyte in the electrolyte is 0.1-3.0mol/L, and the PEG is 0.1%-90% of total mass of the electrolyte. On one hand, an ionic liquid guarantees the high security and fire resistance of electrolysis, on the other hand, and the price of the lithium-ion power battery electrolyte is low; meanwhile, a PEG component is added in the electrolyte, the compatibility of an electrolyte and a lithium-ion battery material is improved, and the property of electrolyte is improved. The lithium-ion power battery electrolyte provided by the invention has properties of good security property, fire resistance, high temperature characteristic and withstand voltage property and the like.