30results about How to "Increased maximum power density" patented technology

A reverse electrodialysis device, including an anode, a cathode, one or more single cells spaced apart from each other between the anode and the cathode, each single cell including a cation exchange membrane and an anion exchange membrane, and a shielding membrane disposed to define spaces between the anode and the single cell and / or between the cathode and the single cell. The cation exchange membrane and the shielding membrane include a porous polymer substrate and a polymer electrolyte incorporated into pores in the substrate.

The invention relates to a fuel cell gas diffusion layer, in particular to an integrated diffusion layer and its preparation method and application. The preparation method of the present invention uses carbon fiber as the skeleton, composites multi-walled carbon nanotubes, uses nitrogen methyl pyrrolidone as the dispersant to disperse at high speed, polytetrafluoroethylene (PTFE) as the binder and water-repellent agent, and adopts vacuum suction filtration molding method A new one-piece diffusion layer is made in one step. The integrated diffusion layer of the present invention replaces the traditional diffusion layer composed of carbon paper and microporous layer, and when it is applied to the cathode of a direct methanol fuel cell or as the cathode and anode diffusion layer at the same time, the maximum power density of a single cell is compared with that of a commercial diffusion layer. Improvements of 20% and 35%, respectively. The integrated diffusion layer of the present invention is applied to the oxygen electrode of zinc-air battery, and the maximum power density is as high as 200mA cm ‑2 , which also provides a potential direction for the exploration of new diffusion layer processes and materials with high performance and low cost for fuel cells.

A kind of nickel-cobalt binary catalyst that promotes the direct oxidation of sodium borohydride is characterized in that: (1) under normal temperature and pressure, prepare 0.2mol / dm 3 nickel chloride (NiCl 2 ·6H 2 O), 0.0000~0.0300mol / dm 3 Cobalt Chloride (CoCl 2 ·6H 2 O) and 4mol / dm 3 Ammonium chloride (NH 4 The mixed solution of Cl) is an electrodeposition solution; (2) Assembling a two-electrode system: a 1cm×2cm polished Ni sheet is placed in the above solution as a cathode, wherein the working area of ​​the Ni sheet is 1cm×1cm, and a carbon rod (3) Using the constant current method, in a constant temperature water bath at 298.15K, with a deposition current of 2A, and a deposition time of 20s, deposit Ni and Co on the above smooth Ni sheet. The nickel-cobalt catalyst prepared by electrodeposition has a porous structure, and the addition of cobalt makes the catalyst have a larger average pore size and porosity, which significantly increases the specific surface area, increases the number of catalytic active sites, and reduces the resistance to be overcome in the direct oxidation reaction. The charge transfer of the electrode reaction is enhanced; at the same time, the discharge potential of the fuel is reduced, the discharge efficiency of the fuel is significantly improved, and the oxidation performance of the fuel is improved.

The invention provides a composite anode of a direct-methanol fuel cell and a manufacturing method thereof. The invention is characterized in that the composite anode is composed of a supporting layer, a diffusion layer and a catalyzing layer, wherein, the diffusion layer is the structure of a network channel which is composed of carbon nano-tubes. The typical characteristics of the preparation process are that: (1) a certain amount of the carbon nano-tubes or the carbon nano-tubes added with a certain amount of other carbon materials are dispersed in isopropanol aqueous solution to obtain a sizing agent (A); (2) a certain amount of polyfluortetraethylene latex is added into the (A) and evenly dispersed to form serosity (B); (3) the (B) is evenly coated on the supporting layer, and the diffusion layer (C) loaded by the supporting layer is formed after 300-350 DEG C high-temperature roasting; (4) the (C) is coated with a layer of PtRu catalyst and then heat pressed with a cathode and aNafion membrane to obtain a membrane electrode aggregation (MEA). Therefore, the transmission efficiency of the fuel at the anode is improved and the internal resistance of the battery is reduced so as to enhance the power density and service life of the battery.

The invention discloses a novel proton blocking composite cathode material and its preparation method and application. The molecular formula of the cathode material is (1‑x)PrBa 0.5 Sr 0.5 Cu 2 o 5‑δ ‑xCe 0.8 SM 0.2 o 2‑δ , wherein, x=0.1~0.5. The novel proton-blocking composite cathode material provided by the present invention can be used as a cathode material for a fuel cell. Due to the use of the PBSC-SDC composite cathode material, the prepared single cell not only has a higher open circuit voltage and a lower polarization resistance, Can output higher maximum power density. It also has good thermal matching, which helps to improve the thermal stability of the single cell.

The invention discloses a CO2 mineralizing power generation method using sodium bicarbonate as an alkaline leaching agent, a battery is divided into a positive electrode zone and a negative electrode zone by a cation exchange membrane, the negative electrode zone contains a supporting electrolyte, the positive electrode zone contains a leaching solution formed by alkaline solid waste and the sodium bicarbonate, after a conductive path is formed by a positive electrode and a negative electrode, CO2 is introduced into the negative electrode for ionization into H<+> and HCO3<->, the H<+> is reduced into H2, the H2 is recycled back to the positive electrode, and oxidized into the H<+>, the H<+> and OH<-> of a positive electrode liquid are neutralized, and the sodium bicarbonate is generated from the HCO3<-> and Na<+> from the positive electrode zone. The sodium bicarbonate in a negative electrode liquid is continuously generated and circulated to the positive electrode zone, caustic soda is extracted, suspension is filtered and leached, filtrate is used as a positive electrode electrolyte, and the positive electrode liquid with the OH<-> consumed is recycled to the negative electrode zone. By means of heating, the CO2 mineralizing power generation method can improve the electricity production performance, is suitable for power generation of weak alkaline solid waste, can be applied to steel making industry to achieve three purposes of emission reduction, solid waste treatment and power generation, and has high practical value.