The invention belongs to manufacture of fiberglass reinforced polyester (FRP) pipes, and particularly relates to an FRP anode tube and a preparation method thereof. The conductive FRP anode tube is composed of an inner conductive antiseptic layer, a conductive layer, a transition layer and a structure layer, wherein the inner conductive antiseptic layer, the conductive layer, the transition layer and the structure layer are sequentially composited into a whole from inside to outside, two ends of the conductive layer extend and are exposed out of two ends of the conductive FRP anode tube, and the conductive layer is made of metal mesh. The preparation method includes processing steps of cleaning a mould, manufacturing the inner conductive antiseptic layer, manufacturing the conductive layer, manufacturing the transition layer, solidifying for the first time, winding to manufacture the structure layer, solidifying for the second time, demoulding and the like. According to the FRP anode tube and the preparation method thereof, the technical problem in the prior art of being high in product electric resistivity is solved. The existing product has the advantages of being low in electrical resistivity (electric resistance of a DN 300 FRP pipe with the length of 5 meters is 20-30 ohms), reasonable in process design and the like.