The invention discloses a method for preparing 4-amidogen-3,6-dichloropyridine-2-formic acid by means of catalytic electrolysis, and belongs to the field of production of chemical products. The technical problems that when 4-amidogen-3,5,6-trichloropyridine-2-formic acid is used for preparing the 4-amidogen-3,6-dichloropyridine-2-formic acid by means of electrolysis, the electrolysis time is long, the energy consumption is high, and selectivity is poor are solved. According to the scheme for solving the above technical problems, during electrolysis of the 4-amidogen-3,5,6-trichloropyridine-2-formic acid, a catalyst is added, the specific temperature, the PH value and other conditions are combined, chlorine on a pyridine ring is desorbed, a final product is the 4-amidogen-3,6-dichloropyridine-2-formic acid, and the catalyst is filtered and washed in the aftertreatment procedure to be recycled and reused. On the basis of electrolysis, low input is increased, the content and yield of the product are increased, and the energy consumption is reduced.