The invention discloses a 5,10,15,20-tetra-aryl diphenanthrene (9,10-b:9,10-1)-22,24-diseleno porphyrin compound which is obtained by the reaction of phenanthro-pyrrole and 2,5-di(aryl hydroxyl methyl) selenophen under low temperature and catalysis of BF3 Et2O in anaerobic atmosphere. The Soret spectral bands of the compound appear in 521nm, compared with tetraphenyl diseleno porphyrin without conjugated aromatic ring at beta-site, the Soret spectral bands are red shifted by 52nm and enter a green light zone above 500nm. The compound has wide application prospects in such areas as photodynamics therapy photosensitizer, OFETs (organic field effect tubes), molecular antenna, light energy converter, optical conversion material, molecular switch, molecular logic gate, molecular wire, organic solar battery, organic electroluminescence, non-linear optical material, optical storage, molecular identification and medicine and so on.