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52 results about "Propionic acid ester" patented technology

Water-based hyperbranched polyester resin as well as preparation method and application thereof

The invention relates to the technical field of synthetic polyester resin and particularly discloses water-based hyperbranched polyester resin as well as a preparation method and an application thereof. The preparation method comprises the steps as follows: dihydroxyl methyl propionic acid, an esterification catalyst and partial polyol are added to a container, heated to 140-150 DEG C and kept atthe constant temperature for 3-3.5 h to obtain first-generation hyperbranched hydroxyl polyester resin; when the reaction degree reaches 90% or above, polyol and organic sulfonate are added, the mixture is heated to 180-200 DEG C and reacts until the solution in the container is transparent; then, unary fatty acid and binary acid are added, the mixture is heated to 200-220 DEG C, when the acid value is decreased to 15 mgKOH/g, heating is stopped, cooling is performed, and alcohol ether cosolvents are added for dilution to obtain the water-based hyperbranched polyester resin. The polyester resin has good water solubility and high soil content, paint prepared from the polyester resin has low construction viscosity and good construction fluidity and forms thick films once, and the films are compact and have good physical and mechanical performance and chemical resistance.
Owner:CHANGSHA UNIVERSITY

Preparation method of nano coating

The invention provides a preparation method of a nano coating. In the method, nano-composite size is adopted and added with fillers and various auxiliary agents; the mixture is mixed and reacts in a reaction kettle, sheared, emulsified, milled and dispersed in a sand mill, concocted in a paint mixing kettle and filtered in a filter so as to prepare the nano coating. The method comprises the following steps: step 1: concocting nano calcium carbonate size; step 2: preparing nano-composite size; step 3: employing the reaction kettle for mixing and reaction; step 4: employing a high-speed shear emulsifying machine for shearing and emulsifying for 30min; step 5: transferring the size to the sand mill for milling and dispersion for 2-3 times, with 30-50min per times; step 6: transferring the size to the paint mixing kettle to be stirred, adding phenylethylene-propyl ethylene acid ester emulsion, a film forming auxiliary agent and a defoamer while stirring and finally adding propylene glycol and a bactericide; step 7: adjusting the pH value to 8-9; step 8: adding a thickener to ensure the viscosity to be 3000-4000 MPa.S; step 9: adopting a coating filter for filtering and preparing the finished product after filtering. The coating is bactericidal, nontoxic, tasteless and resistant to 300000 times of washing.
Owner:马秀荣

Continuous production method of 3-mercaptopropionic acid alkyl ester and 3, 3'-trithiodipropionic acid dialkyl ester

The invention discloses a continuous production method of 3-mercaptopropionic acid alkyl ester and 3, 3'-trithiodipropionic acid dialkyl ester. The method comprises the following steps: reacting 3, 3'-dithiodipropionic acid dialkyl ester with hydrogen sulfide to generate 3-mercaptopropionic acid alkyl ester and 3, 3'-trithiodipropionic acid dialkyl ester; 3-alkyl mercaptopropionate is easy to separate and purify in a reduced pressure distillation mode; continuously reacting the residual 3, 3'-dithiodipropionic acid dialkyl ester with hydrogen sulfide, and continuously converting the residual 3, 3'-dithiodipropionic acid dialkyl ester into 3, 3'-trithiodipropionic acid dialkyl ester, and therefore, the continuous production process of 3-mercaptopropionate and 3, 3'-dialkyl trithiodipropionate is realized through continuous enhanced mass transfer feeding and reaction units of hydrogen sulfide raw materials and liquid raw materials, continuous phase separation units, distillation separation units and feedback control of process products to the reaction units. The synthesis method does not adopt an organic solvent, does not generate inorganic salt byproducts, has no strict requirements on the purity of raw materials, and is easy to industrialize.
Owner:靳浩田

Preparation method of high-performance acrylate-type resin

ActiveCN105037620AImprove wear resistanceImprove yellowing defectsCoatingsPotassium persulfateMeth-
The invention relates to a preparation method of high-performance acrylate-type resin. The preparation method includes the steps of (1) adding water, sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether and 2-acrylamide-2-methylpropanesulfonic acid; (2) increasing the temperature and stirring the materials and adding a monomer A; (3) performing emulsification for 40 min, increasing the temperature to 70 DEG C and feeding backflow water; (4) increasing the temperature to 85 DEG C and adding a potassium persulfate solution; (5) performing a reaction for 2 h, adding fluticasone propionic ester, performing stirring reaction to obtain a core-layer emulsion; (6) adding dropwisely a monomer B and the potassium persulfate solution to the core-layer emulsion, and performing a stirring reaction after dropwise addition; (7) decreasing the temperature to 50 DEG C, adding the sodium dodecyl benzene sulfonate and the fatty alcohol-polyoxyethylene ether, and performing the reaction for 70 min; and (8) performing a reaction at 70 DEG C for 1 h and adding ammonia water to regulate the pH value to 7-8 to prepare the acrylate-type resin. The preparation method not only greatly improves wear resistance of the acrylate-type resin but also improves the defect of yellowing of a film formed by an emulsion of the acrylate-type resin.
Owner:珠海市卓和化工科技有限公司

Method for stereoselective resolution of 2-(4-methylphenyl)propionic acid enantiomer catalyzed by candida rugosa lipase

The invention discloses a novel chiral resolution method for obtaining a single enantiomer of 2-(4-methylphenyl)propionic acid, namely a method for synthesizing a single enantiomer of 2-(4-methylphenyl)propionic acid by enzymatically catalyzed stereoselective hydrolysis of 2-(4-methylphenyl)propionate enantiomers. Based on high selectivity and high catalytic efficiency of candida rugosa lipase, 2-(4-methylphenyl)propionate enantiomers are hydrolyzed to obtain (+)-2-(4- methylphenyl)propionic acid with high optical purity; based on the interaction of cyclodextrin to 2-(4-methylphenyl)propionateenantiomers, the conversion rate of 2-(4-methylphenyl)propionate is improved; the conversion rate of a substrate and the optical purity of the product can be as high as 40.76% and 96.24%, respectively, and the stereoselectivity E is as high as 145; the method overcomes the problems of low optical purity, low yield, environmental pollution and the like of general resolution technology, and can achieve high conversion rate and high selectivity of hydrolysis of 2-(4-methylphenyl)propionate enantiomers, so as to realize non-toxic, harmless and environmental-friendly resolution of chiral compoundsand mild reaction conditions; and the aims of simple equipment, easy operation, low cost and the like are achieved.
Owner:HUNAN INSTITUTE OF SCIENCE AND TECHNOLOGY
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