The invention discloses polymer alloy for rubber ducts. The alloy comprises the following raw materials in part by weight: 20 to 30 parts of CM135B, 70 to 80 parts of NBR3305, 4 to 6 parts of magnesium oxide, 4 to 6 parts of coumarone resin, 25 to 35 parts of high abrasion carbon black, 60 to 80 parts of general purpose carbon black, 5 to 15 parts of white carbon black, 6 to 12 parts of dibutyl ester, 1.2 to 2.5 parts of sulphur, 0.5 to 1.5 parts of accelerating agents CZ, 3 to 8 parts of composite curing agents EataMixTCHC, 10 to 20 parts of distilled aromatic extracts(DAE), 0.5 to 1.5 parts of anti-aging agents RD, 0.3 to 0.8 part of antiscorching agents CTP and 15 to 25 parts of white bole. According to the invention, the alloy improves the abrasion resistance, the ozone aging resistance, the weathering ageing resistance and the fire resistance of acrylonitrile-butadiene rubber, improves the rolling and the extruding of rubber stocks, improves the fineness of the rubber stocks, reduces shrinking percentage, improves the tensile strength and the tearing resistance of the rubber stocks, has small permanent deformation, improves the oil resistance and the corrosion resistance of the rubber stocks, prolongs the service life, effectively reduces production costs and further increases the quality of products.