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102results about How to "Maintain bond strength" patented technology

Initiator systems, polymerisable compositions, and uses thereof for bonding low surface energy substrates

InactiveUS6939932B2Reduction and elimination of yellowingEasy to prepareFireproof paintsAntifouling/underwater paintsSurface energyChemistry
Use of an initiator system comprising:
    • a combination of an organoborane and a polyaziridine, in a ratio of
    • aziridine groups to boron atoms of greater than 1.3:1,
as an initiator of polymerisation in an adhesive composition for bonding a low surface energy substrate;
provided that the initiator system does not contain more than a trace amount of a complex of organoborane with a complexing agent selected from:
  • an amine other than a polyaziridine;
  • a complexing agent comprising at least one hydroxide;
  • a complexing agent comprising at least one alkoxide; or
  • amidine complexing agent.
  • An initiator system as described is of the formula VI:
      • wherein R1 is C1-C10 alkyl,
        • R2 and R3, which may be the same or different, are, C1-C10 alkyl or C3-C10 cycloalkyl, phenyl, or phenyl-substituted C1-C10 alkyl or C3-C10 cycloalkyl, provided that any two of R1-R3 may optionally be part of a carbocyclic ring;
        • R5 is a polyvalent radical,
        • R6 and R7 which may be the same or different are H or C1-C10 alkyl, particularly C1-4 alkyl, especially methyl, and
        • y is a number of at least 2, particularly 2-4, especially 3, and the value of x multiplied by y is greater than 1.3.
    Particular examples of initiator compounds include, trimethylol propane tris(3-(2-methyl aziridino))propionate and trimethylol propane tris-3-N-aziridinyl propionate.
    Owner:LOCTITE (R&D) LIMITED

    Adhesive used for low surface energy surface bonding, and preparation method thereof

    The invention discloses an adhesive used for low surface energy surface bonding. The adhesive used for low surface energy surface bonding is composed of, by weight, 30 to 40 parts of butyl acrylate, 10 to 15 parts of methyl methacrylate, 3 to 4 parts of acrylic acid, 30 to 40 parts of hydroxyethyl acrylate, 1 to 3 parts of N-hydroxymethyl acrylamide, 10 to 15 parts of hydrogenation modified rosin,0.5 to 1 part of an emulsifier, 0.1 to 0.2 parts of an initiator, 0.5 to 1.5 parts of nano-SiO2, 1 to 2 parts of an unsaturated silane coupling agent, and 80 to 120 parts of water. According to a preparation method, a nonsaturated silane coupling agent is adopted for surface treatment of nanometer particles, and then organic-inorganic nanometer composite pressure-sensitive adhesive emulsion synthesis is carried out so as to obtain a finished product. acrylic ester is taken as a main component, cooperation of soft and hard monomers and functional monomers is adopted, hydrogenation modified rosin is adopted for modification of the viscosity, and the siloxane coupling agent is adopted for modification of nano-SiO2, so that the adhesive possesses excellent wettability and bonding performanceon low surface energy materials.
    Owner:SHENZHEN NIKTO TAPE NEW MATERIAL CO LTD
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