The invention belongs to the technical field of membranes, and particularly relates to a
mesoporous silica /
anodic aluminum oxide heterojunction membrane as well as a super-
assembly preparation methodand application thereof. The
hydrogen bonding force between silica and surface of
anodic aluminum oxide is used, the
anodic aluminum oxide is used as a substrate, by means of a spin-
coating method, alayer of ultrathin, regular, ordered and thickness-controllable
mesoporous silica film on the anodic aluminum
oxide substrate through an interface super-
assembly and
evaporation-induced self-assemblyconstruction strategy, and therefore the
mesoporous silica / anodic aluminum
oxide heterojunction membrane is obtained. The
heterojunction membrane comprises a negatively charged mesoporous channel withsmall mesoporous silica and a positively charged nano channel with the anodic aluminum
oxide, so that abundant transmission channels are provided for ions; and the bipolar
membrane structure with different charges can provide abundant channels for
ion transmission, so that the
internal resistance of
ion transmission is greatly reduced, and the application in the aspect of energy capture is facilitated. Meanwhile, the invention provides a method for constructing a nano-fluidic device with
ion selectivity and
salinity difference energy capture, and a new idea is provided for constructing a
solid-state nano-channel membrane.