The invention discloses a method for producing 2-alkylene grease cyclic ketone by adopting a bionic catalytic system. According to the method, grease cyclic ketone and aliphatic aldehyde are used as raw materials, under the light irradiation, amido substances are used as catalysts, and reaction is carried out in the existence of protonic acid and metal ions to generate 2-alkylene grease cyclic ketone. The catalyst system after the organic phase separation can be cyclically used. The 2-alkylene grease cyclic ketone is an important midbody for synthesizing various kinds of spices (such as methyl dihydrojasmonate, delta- lactone). The traditional process has most obvious problems that a acid-base solution catalytic system is adopted, so the recovery and cyclic use difficulty of the catalyst is very high, in addition, the product yield is low, many high-boiling-point byproducts are generated, the reaction selectivity is poor, a large quantity of waste water is generated, and resource waste and environment pollution are caused. The method provided by the invention has the advantages that the traditional unrecoverable solution catalytic system is omitted and is replaced by the bionic catalytic system which can be recovered and can be cyclically used, the clean production technology is used for modifying the original process, and simultaneously, the resource saving, the sufficient utilization and the environment protection are realized.