The invention discloses a poly-modified 2, 2-dimethyl-1, 3-
propylene glycol ester as well as a preparation method and an application thereof. The poly-modified 2, 2-dimethyl-1, 3-
propylene glycol ester is prepared from raw materials containing furandicarboxylic acid or an ester thereof,
terephthalic acid or an ester thereof, 2, 2-dimethyl-1, 3-
propylene glycol and a compound containing an
isocyanate group through an
esterification reaction and / or an ester exchange reaction, a condensation
polymerization reaction and a chain extension reaction in sequence. The molecular weight of the
copolyester is increased by introducing a compound containing an
isocyanate group to react with hydroxyl-terminated or carboxyl-terminated
polyester, and furandicarboxylic acid is introduced into a
terephthalic acid 2, 2-dimethyl-1, 3-propylene glycol ester
chain segment to improve the
gas barrier property of the
copolyester and increase the bio-based content, which can get rid of the dependence of the
polyester industry on
petroleum resources, and finally the poly-modified 2, 2-dimethyl-1, 3-propylene glycol ester with high molecular weight, high
gas barrier property and excellent mechanical properties is prepared. The poly-modified 2, 2-dimethyl-1, 3-propylene glycol ester provided by the invention can provide a new available material for the fields of packaging, films and the like.