The invention discloses an all-solid-state lithium battery, a garnet solid-state electrolyte and a preparation method thereof. The garnet solid-state electrolyte comprises a matrix, wherein the matrixa garnet-type fast ionic conductor LiaMbLacZrdNeO12, M includes one or more of Al, Sr, Sc, Ca, Ba and Y, and N includes one or more of Ta and Nb; the surface of the matrix is coated with a solid lubricant so as to modify the interface of the solid-state electrolyte, and the solid lubricant includes one or more of WS2, WSe2, NbSe2, NbS2, MoSe2, TaS2, TaSe2, TiS2 and TiTe2. The solid-state electrolyte is in full surface contact with the garnet-type fast ionic conductor via the solid lubricant, thereby being conducive to improving the interface between crystal grains of the solid-state electrolyte and between an electrode and the solid-state electrolyte, thus acquiring low interface impedance, and significantly improving the durability and cycle performance of the battery.