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248results about How to "High plasticizing efficiency" patented technology

Polyester plasticizer and chlorine-containing resin compositions

The polyester-based plasticizer of the present invention is obtained by reacting (a) a diol component, (b) an organic dicarboxylic acid component, and (c) a terminal terminator, and the average molecular weight of the polyester-based plasticizer is 500-5000, wherein, the (a) diol component is composed of 100 mole parts of 2-methyl-1,3-propanediol, 10-1000 mole parts of 3-methyl-1,5-pentanediol and 0-1000 mole parts of other aliphatic diols; the (b) organic dicarboxylic acid component is composed of 100 mole parts of adipic acid and 0 to 100 mole parts of other organic dicarboxylic acids; the (c) terminal The terminator is composed of monohydric aliphatic alcohol or monohydric aliphatic organic acid. The polyester plasticizer of the present invention has excellent plasticizing efficiency and can impart excellent oil resistance to synthetic resins such as chlorine-containing resins.
Owner:ADEKA CORP

Epoxy cardanol-based glycidyl ether as well as preparation method and application thereof

The invention discloses an epoxy cardanol-based glycidyl ether plasticizer as well as a preparation method and application thereof. The preparation method comprises the following steps: taking cardanol and epoxy chloropropane as main raw materials and carrying out ring-opening addition reaction and ring-closure reaction to synthesize an intermediate product cardanol-based glycidyl ether; and further uniformly mixing the intermediate product with organic acid and a catalyst, heating to a certain temperature, dripping a peroxide source to carry out epoxidation reaction to obtain a crude product, leaving the crude product to stand, layering, performing neutralization and dehydration on the crude product after the reaction so as to obtain an epoxy cardanol-based glycidyl ether plasticizer. The plasticizer is non-toxic, has relatively high plasticizing efficiency and can endowing resin products with favorable thermal stability and mechanical property; and moreover, by taking the cardanol which is low in cost and easy to get as raw material, the epoxy cardanol-based glycidyl ether plasticizer integrates the advantages of being environment-friendly and being reproducible, complies with the developing trend of the plastic additive industry and has wide application and favorable application prospect.
Owner:INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY

Preparation method of acrylic ester type processing aid with multilayer gradient core-shell structure

ActiveCN103467663AProcess parameters are reasonableReduce material and process costsEmulsionSolubility
The invention relates to a preparation method of an acrylic ester type processing aid with a multilayer gradient core-shell structure, belonging to the field of modification of functional macromolecular materials. The preparation method comprises the following process steps: (1) under the condition of stirring at 30 DEG C, adding deionized water, an initiator A, an emulsifier, a co-emulsifier, a dispersant, a soft monomer and a crosslinking agent into a reaction kettle, and performing pre-emulsification to obtain a pre-emulsion; (2) heating the pre-emulsion to a temperature less than or equal to 90 DEG C, and performing a thermal reaction to obtain a soft monomer core layer emulsion; and (3) adding an initiator B, alpha olefin and a monomer which has a solubility parameter similar to that of PVC (polyvinyl chloride) into the soft monomer core layer emulsion, and sequentially polymerizing 1-5 layers of rigid polymer shells with a solubility parameter similar to that of polyvinyl chloride to obtain the acrylic ester type processing aid. The obtained PVC processing aid has the advantages of low price, good effect of promoting plasticization, excellent weathering resistance, capability of improving impact properties of a product and the like, and can be widely applied to the fields of PVC building door and window profiles, pipes, wires, cables, small-scale household appliances and the like.
Owner:乌鲁木齐市华泰隆化学助剂有限公司

Production method of super-transparent soft PVC (polyvinyl chloride) film

The invention discloses a production method of a super-transparent soft PVC (polyvinyl chloride) film, which comprises the following steps: 1) screening a PVC resin powder to obtain a powder A; 2) stirring the powder A with a plasticizer, a stabilizer, a lubricant and a pigment to obtain a mixed powder B; 3) cooling the mixed powder B by stirring to obtain a mixed powder C; 4) carrying out pressurized banburying on the mixed powder C by a Banbury mixer to obtain a colloid D; 5) carrying out roll plastification on the colloid D to obtain a colloid E; 6) secondary open milling: carrying out roll plastification on the colloid E to obtain a colloid F; 7) adding the colloid F into a filtering machine to obtain a melting charge G; and 8) carrying out roll forming on the melting charge G, cooling, carrying out edge trimming and rolling to obtain the super-transparent soft PVC film. The method can avoid the problem of insufficient plastification and ensure the plastification degree of the product, thereby obtaining the super-transparent soft glass; and the super-transparent soft PVC film has the characteristics of smooth surface, no crack, no bubble, uniform color, high heat resistance, high cold resistance, high aging resistance, high load resistance, strong acid/alkali resistance and favorable light transmittance.
Owner:佛山龙塑工业塑胶有限公司

Environment-friendly migration-resistant epoxy fatty acid cyclohexyl plasticizer and preparation method thereof

The invention discloses an environment-friendly migration-resistant epoxy fatty acid cyclohexyl plasticizer and a preparation method thereof. The plasticizer is prepared from unsaturated fatty acid and cyclohexanol through esterification and epoxidation, the technological process is simple, strong continuity and high yield are realized, and the situation that a plasticizer manufacture factory adjusts the process route greatly and increases additional mechanical equipment input is avoided since the process of the plasticizer disclosed by the invention is completely compatible with the synthesis process of a conventional epoxy fatty acid methyl ester plasticizer. Under the same conditions, the migration rate of the plasticizer prepared through the method is only about 1 / 5 of that of the conventional epoxy fatty acid methyl ester plasticizer in PVC, the flash point of the plasticizer prepared through the method is 20-30 DEG C higher than that of the conventional epoxy fatty acid methyl ester plasticizer, and meanwhile, the plasticizer disclosed by the invention has the advantages of no toxicity, environment friendliness, good compatibility with polyvinyl chloride resin, high plasticizing efficiency and the like, can replace or partially replace phthalate plasticizers to be used for manufacturing polyvinyl chloride artificial leather, food-grade hoses, fresh-keeping films, infusion apparatuses, blood transfusion bags, medical gloves, children's toys, cables and wires and the like and has a wide application prospect.
Owner:SICHUAN UNIV

Film crushing plasticator

The invention relates to the field of recycling of waste plastics and provides a film crushing plasticator. The film crushing plasticator comprises a machine frame and further comprises a crushing, stirring and preplasticizing device, a plasticizing and toughening device and an exhaust air filter device, wherein the crushing, stirring and preplasticizing device is provided with a feeding hopper and a discharging outlet; the plasticizing and toughening device comprises a barrel provided with a barrel heating device and connected with the machine frame, a middle spiral push rod connected with the barrel in a pivoted mode, a plurality of outer spiral push rods distributed in the circumferential direction of the middle spiral push rod and connected with the barrel in a pivoted mode, and a spiral push rod drive device; and the barrel is provided with a plasticizing inlet located at the rear portion of the side body of the barrel and communicating with the discharging outlet, a plasticizing outlet located in the front end of the barrel, and an exhaust hole communicating with an inlet of the exhaust air filter device. The film crushing plasticator is good in effect of mixing, extruding and rubbing of plasticized raw materials in the plasticizing process, gas is exhausted easily, and prepared plastic renewable raw materials are good in toughness.
Owner:NINGBO LVHUA RUBBER & PLASTIC MACHINERY IND & TRADE

Method for preparing plant fiber-based foamed thermoplastic masterbatch

The invention discloses a method for preparing plant fiber-based foamed thermoplastic masterbatch. The method comprises the following specific steps: (A) crushing plant fibers, adding an alkali liquor swelling agent, soaking the processed plant fibers, and drying the soaked plant fibers after carrying out ultrasonic reaction; (B) adding a modified plasticizer, carrying out heating reaction for 30-90min, carrying out filtration after cooling, cleaning filter residues, and drying the cleaned filter residues; and (C) mixing plasticized plant fiber powder, a plastic matrix and auxiliaries, adding the mixture in an extruder, carrying out squeezing granulation to obtain the plant fiber-based foamed thermoplastic masterbatch. By the adoption of the invention, the glass transition temperature of natural plant fibers is optimized, the hot melting flowing property of the natural plant fibers is improved after being modified by the composite modified plasticizer, the wood-plastic plasticizing torsional force is effectively reduced, the energy consumption is greatly reduced, the cost is reduced, meanwhile, the mechanical property of the foamed thermoplastic masterbatch product can be improved by more than 25%, the impact resistance and the ductility are greatly improved, the material density is reduced, and thus the method has relatively high promotion and application values.
Owner:JIANGSU ACAD OF AGRI SCI

Single-component reaction-type polyurethane hot melt adhesive and preparation method thereof

The invention discloses single-component reaction-type polyurethane hot melt adhesive. The single-component reaction-type polyurethane hot melt adhesive is prepared from the following raw materials: polyurethane prepolymer, a chain extender, tackifying resin, a latent curing agent and filler, wherein the polyurethane prepolymer is formed by polymerizing polyalcohol with a molecular weight of 500 to 3000, polyisocyanate and a catalyst; and the raw material composition also comprises a plasticizer, wherein the plasticizer is dioctyl phthalate and/or diethylene glycol dibenzoate. The components of the single-component reaction-type polyurethane hot melt adhesive of the invention are mixed with plasticizers, the plasticizers are dioctyl phthalate and/or diethylene glycol dibenzoate, the two substances have high plasticizing efficiency for the polyurethane and low volatility and have good low-temperature flexibility; and by adding the plasticizers, the interaction between polymer macromolecular chains can be weakened, the elasticity and flexibility of the polymer materials of the polyurethane hot melt adhesive can be improved, and the high-temperature and low-temperature resistance of the hot melt adhesive can be improved.
Owner:JIANGSU RUIDE NEW ENERGY TECH

Waste plastic film recovery processing system and method

The invention provides a waste plastic film recovery processing system and method. The waste plastic film recovery processing system comprises a crushing dry washer, a pelleting system and a cooling device, wherein the crushing dry washer is used for crushing waste plastic film into plastic film chips and separating out dust and impurities carried by the plastic film chips in a dry washing mode; the pelleting system is used for plastifying the purified plastic film chips into plastic grains through hot wind; and the cooling device is used for cooling the plastified plastic grains into a normal temperature state to be discharged. The waste plastic film recovery processing method comprises the steps of crushing and purifying of the waste plastic film, pelleting and cooling, so that the plastic grains are obtained. According to the waste plastic film recovery processing system and method, renewable resources are effectively recycled, the automation degree is high, the processing steps are fewer, the energy consumption is low, and the efficiency is high; no waste water or smoke or odor is generated in the plastic film recovery processing process; and good environmental benefits and economic benefits are achieved, and the application prospects are broad.
Owner:韩吉生

Preparation method and product of adipate epoxy plasticizer

The invention discloses a preparation method of adipate epoxy plasticizer, which comprises the following steps: (1) extracting fatty acid in vegetable oil leftovers; (2) performing reduction reaction on the obtained long-chain fatty acid under the catalytic reduction action of lithium aluminum hydride, thus obtaining long-chain fatty alcohol; (3) mixing the long-chain fatty alcohol and adipic acid, and adding a reverse micelle nano aluminum oxide catalyst, thus obtaining a system solution containing adipic acid di(long-chain fatty ester); (4) performing epoxy reaction, thus obtaining a finished product solution; and (5) introducing chlorine gas into the epoxy finished product solution, simultaneously performing ultraviolet irradiation until the chlorination reaction is completed, and then treating to obtain the modified epoxy plasticizer. The invention also discloses the epoxy plasticizer prepared by the method. According to the invention, the long-chain alcohol group is introduced into the molecular structure of the adipic acid, so that the plasticizing efficiency of the product is greatly improved, the raw material cost is low, and the comprehensive recovery of the vegetable oil leftovers is realized; and meanwhile, the epoxy group in the plasticizer enhances the heat resistance, stability and compatibility of the product.
Owner:浙江嘉澳环保科技股份有限公司
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