The invention discloses a new type of glass fiber, which relates to the technical field of new materials. The glass fiber is mainly composed of SiO2, Al2O3 and CaO raw materials, and on this basis, MgO, ZrO2, TiO2, Fe2O3, Na2O, K2O and Li2O and other components are introduced. The manufacturing process includes raw material mixing and melting, acid leaching, water cleaning, heat treatment, post-surface treatment, etc. The glass fiber prepared by the above process has high silica content, smooth appearance and uniform color, which can be well applied to Various post-processing manufacturing processes, excellent high temperature resistance, can be used for a long time below 1100°C, has good ablation performance, better high temperature resistance, chemical corrosion resistance and elastic modulus, and can be widely used in the manufacture of precision instruments Heat protection parts, ablation materials, thermal insulation materials and other fields.