The invention, which belongs to the technical field of functional nano materials, provides a preparation method of a bismuth-doped polymerized carbon nitride nano composite material containing carbondefects. The method comprises the following steps: step 1, preparing ultrathin PCN nanosheets; and step 2, preparing a bismuth-doped polymerized carbon nitride (Bi/CV-PCN) nano composite material containing carbon defects. According to the preparation method, 2, 4, 6-triaminopyrimidine is introduced into a CN structure through supramolecular aggregation and ion melt polycondensation to obtain theultrathin PCN nanosheet, the crystallinity of PCN is controlled, and visible light absorption is enhanced. Then, a Bi/CV-PCN nano composite material is synthesized by utilizing a mild and simple one-pot hydrothermal method. Under the synergistic effect of an SPR effect caused by Bi doping and CVs, the photoactivity and the photoelectrochemical stability of the composite material are further improved, and charge separation is accelerated.