39results about How to "Inhibition of hydration dispersion" patented technology

The invention discloses a high-temperature resistant polymer fluid loss agent for drilling fluid and a preparation method thereof. The polymer fluid loss agent is characterized in that the polymer fluid loss agent is a copolymer generated by olefine acid, alkenyl amide, alkenyl azululanone and alkenyl quaternary ammonium through reaction, molecules of the copolymer contain 800 to 1,800 structural units, and viscosity average molecular weight is 500,000 to 1,200,000. The polymer fluid loss agent can resist temperature of more than 245 DEG C in the drilling liquid, has good protective colloid performance to the drilling liquid, improves the quality of a filter cake, has good fluid loss reduction effect in fresh water, aggravated fresh water, salt water and the like, can simultaneously inhibit hydration and dispersion of clay and has good rheology.

The invention relates to a nanometer emulsion blocking agent used for drilling fluid, and a preparation method and application thereof. The nanometer emulsion blocking agent is prepared through polymerization by dispersing at least two double-bond-contained monomers into water containing an emulsifier and a co-emulsifier in an weak alkali environment under the action of a catalyst; and raw materials participating in reaction comprise, by weight, 40 to 60 parts of the double-bond-contained monomers, 2 to 6 parts of the emulsifier, 1 to 4 parts of the co-emulsifier, 0.1 to 0.5 part of the catalyst and 30 to 50 parts of the water. Accordingn to the invention, a particle size of a dispersed particle in the nanometer emulsion blocking agent is distributed in a nanoscale and is less than 500 nm, so the nanometer emulsion blocking agent has good blocking effect, cen block micropores and be casted into microcracks, and is capable of reducing pore pressure transmission, maximumly reducing differential pressure sticking and effectively inhibiting hydration dispersion of clay; the nanometer emulsion blocking agent is stable in high salinity and has the advantages of convenient use, no toxicity, no pollution and easy degradation; and the preparation method of the nanometer emulsion blocking agent has the advantages of reasonable process, mild and controllable conditions, no post treatment, low cost and benefit ratio, and facilitation to industrial production.

The invention relates to a dendritic quaternary ammonium salt shale inhibitor as well as a preparation method and application thereof. The dendritic quaternary ammonium salt shale inhibitor is a modified product obtained by quaterisation reaction of terminal amino dendritic polymer, cyclic ether and tertiary amine. The preparation method comprises the following steps: dissolving the terminal amine dendritic polymer into a dissolving solvent, then slowly dropwise adding the tertiary amine, stirring for 0.5 to 3 hours at a room temperature, and then slowly dropwise adding the cyclic ether; raising the temperature to be 40 to 90 degree centigrade after dropwise adding is finished, and reacting for 2 to 12 hours; removing the dissolving solvent through evaporation, adding a deposition solvent to deposit out a solid body, and vacuum-drying the solid body, thereby obtaining the dendritic quaternary ammonium salt shale inhibitor. The dendritic quaternary ammonium salt shale inhibitor provided by the invention has excellent inhibition performance, can effectively inhibit hydration dispersion of active clay shale (high montmorillonite content), and can effectively perform an inhibition effect under a low concentration.

The present invention relates to composite metal zwitterions polymer and its preparation. They are used as treating agent for drilling fluid and well completion fluid. The composite metal zwitterions polymer is prepared through re-compounding cationic, anionic and non-ionic monomer and metal hydroxide in certain proportion and vaporizing and desolvating flash polymerization. The composite metal zwirrerions polymer has excellent filtration property, clay hydration dispersion inhibiting property, rheological property and pollution and temperature resistance in fresh water, salty water and saturated mud.

This invention discloses a kind of no damage fetching core borehole liquid and its preparation method. It is made up of the water 100000- 160000, NaCl 15000-19000, Na2CO3 200-400, NaOH 50-150, PAC-SL 150-550, FLOWZAN 200-600, Starch 1200-1800, the modified SOLTEX 1200-1800, Baracarb(5) CaCO3 a 2000-4000, Baracarb(50) CaCO3 b 2000-4000, Baracarb(600) CaCO3 c 2000-4000. The character of the no damage fetching core borehole liduid is in that: it has no damage to the core and the stratum; it has the good lubricating ability and has the good capability in cleaning well and inhibiting the drill chip disperses; the additive such as the FLOWZAN, the starch and the PAC-SL are all degraded by the organism. The Baracarb crushed by the marble is the inorganic additive and has no pollution to the environment; also it can not change the wetting property of the petrosal.

The invention provides an inverse emulsion polymer and a preparation method and application thereof, the method is as follows: first, emulsification of an oil phase material and a water phase material which includes monomers A, B and C, a first emulsifier and water to obtain monomer emulsion; and polymerization of the monomer emulsion in the presence of an initiator to obtain the inverse emulsion polymer, wherein the monomer A is selected from water soluble allyl sulfonate; the monomer B is selected from one or more of acryloyl morpholine, vinyl caprolactam and vinyl morpholine, and the monomer C is selected from acrylate compounds comprising polyoxyethylene and alkyl. The temperature and salt resistance, calcium resistance and inhibiting capability of the inverse emulsion polymer are further enhanced, during application of the inverse emulsion polymer as a drilling fluid treatment agent, the inverse emulsion polymer not only has the effect of good filtrate loss reduction, viscosity increase, flow type adjustment, inhibition of hydration dispersion of clay and drilling cuttings at high temperature, can improve the quality of filter cake, improves drilling liquid lubrication, and is applicable to all types of water-based drilling fluids.

The invention relates to the technical field of drilling fluid auxiliaries, and provides an environment-friendly type drilling fluid anti-wear agent with high temperature resistance and a preparation method of the environment-friendly type drilling fluid anti-wear agent. The environment-friendly type drilling fluid anti-wear agent with the high temperature resistance comprises raw materials as follows: phosphorus pentasulfide, isooctyl alcohol, oleic acid, diethyl ammonium phosphate, potassium hydroxide, a molybdenum di-zinc compound, dimethyl silicon oil, zinc carbonate, aluminum distearate and water. The environment-friendly type drilling fluid anti-wear agent with the high temperature resistance is prepared from a natural polymer material, biomass oil and lipid through modified synthesis and esterification reaction, is not only an environment-friendly type drilling fluid auxiliary, but also can reduce wear, decrease frictional resistance and torque, increase the drilling rate and reduce drilling cost effectively and has higher tolerable temperature and higher salt intrusion resistance, thereby having more popularization value and further having better rock fragment hydrated dispersion inhibition capacity and better shale expansion inhibition function, and accordingly, the environment-friendly type drilling fluid anti-wear agent with the high temperature resistance is the environment-friendly drilling fluid auxiliary with the high temperature resistance and has the characteristics of advancement, maturity and economic efficiency.

The invention discloses an environment-friendly pseudo oil-based drilling fluid and a preparation method thereof. The drilling fluid comprises the following raw materials in ratio: 0.6-0.8 part of polyamine inhibitor, 12-15 parts of methyl glucoside, 2-3 parts of nano-emulsion, 0.2-0.4 part of high temperature protective agent, 0-30 parts of barite, 1-3 parts of bentonite, 0.1-0.3 part of sodium carbonate, 0.1-0.3 part of sodium hydroxide, 0.2-0.5 part of low viscosity parker, 0.1-0.2 part of zwitter-ion coating agent, and 80-100 parts of water. The preparation method comprises the following steps: 1) respectively adding sodium hydroxide and sodium carbonate in water, and stirring; 2) adding the bentonite in the water, stirring at high speed, and standing at normal temperature; 3) stirring the solution of the step 2), adding methyl glucoside in the stirring process, and continuously stirring; 4) orderly adding the zwitter-ion coating agent, the low viscosity parker, the high temperature protective agent, the polyamine inhibitor and the nano-emulsion in the solution in the step 3) at intervals of stirring; and 5) regulating the density of the drilling fluid.

The invention discloses a polyamine inhibitor for a water-based drilling fluid and a preparation method of the polyamine inhibitor. The structural formula of the polyamine inhibitor is as shown in thespecification. The preparation method includes the steps of firstly, weighing, by weight, 75-80 parts of maleic anhydride, 210-215 parts of triethanolamine, 8-12 parts of glacial acetic acid and 348-352 parts of tap water; secondly, placing the weighed maleic anhydride and triethanolamine in a reaction kettle under normal temperature; thirdly, rising the temperature in the reaction kettle to 80-90 DEG C in 4 minutes, and keeping the temperature for 30 minutes; fourthly, rising the temperature to 180 DEG C after the heat preservation, and using a vacuum pump to keep pressure in the reaction kettle in a 20mm mercury column state to perform reaction for 4 hours; fifthly, after the reaction, cooling and performing pressure relief, and cooling to 90 DEG C; sixthly, adding the glacial acetic acid and the tap water when required temperature is reached, and performing reaction for 2 hours to obtain the polyamine inhibitor. The polyamine inhibitor is applicable to a shale gas water-based drilling fluid system.

The invention belongs to the field of surfactants and particularly relates to a highly-inhibitive foaming agent for foam drilling of shale formation and a preparation method of the foaming agent. The foaming agent which is a surfactant is structurally characterized in that a quaternary ammonium salt and polyoxyalkyl ether structure in strong electric charge interaction with shale is introduced while an appropriate hydrophobic carbon chain length is kept. The preparation method includes that alkyl polyoxyalkyl ether dimethyl tertiary amine and methane chloride are subjected to quaternary amination to obtain a surfactant sample. When the foaming agent is applied to the shale formation, remarkable inhibition performance and salt tolerance are provided wile great foaming performance is guaranteed.

The invention relates to the technical field of well drilling, and discloses a cementing plugging type wall fixing agent as well as a preparation method and application thereof. The method comprises the following steps: (1) preparing a dispersion system A from nano silicon dioxide, preparing a dispersion system B from gamma-(methacryloyloxy) propyltrimethoxysilane, mixing the dispersion system A and the dispersion system B, adjusting the pH value to 8-9, adding phenothiazine for reaction, filtering after the reaction is finished, and washing and drying a product; (2) mixing the modified silicon dioxide prepared in the step (1), acrylamide, acrylic acid, sodium p-styrenesulfonate, dimethyl diallyl ammonium chloride, 1-ethyl-(3-dimethylaminopropyl) carbodiimide, dopamine hydrochloride and water, introducing protective gas to remove oxygen, and adding an initiator to react; and (3) washing, drying and crushing the product obtained in the step (2) to obtain the wall fixing agent. The wall fixing agent disclosed by the invention is beneficial to maintaining and even enhancing rock strength, so that an effect of stabilizing a fractured formation well wall is achieved.

The invention discloses a high-temperature water-based drilling fluid. The high-temperature water-based drilling fluid comprises, by weight, 103 to 104 parts of base slurry, 1 to 1.5 parts of a filtrate reducer I, 1.5 to 2 parts of a filtrate reducer II, 2 to 2.5 parts of a filtrate reducer III, 2 parts of polyethylene glycol, 1 to 1.5 parts of aminosilanol, 3 to 5 parts of potassium chloride, 2 to 2.5 parts of a lubricant, 0.6 to 1 part of calcium carbonate powder with a size of 600 to 800 meshes, 1.2 to 1.5 parts of modified diatomite with a size of 400 to 500 meshes and barite with an addition amount that allows the high-temperature water-based drilling fluid to be weighted to 1.4-1.7 g/cm<3>. The invention also discloses a preparation method of the high-temperature water-based drillingfluid. The drilling fluid has the beneficial effects of resisting high temperature and reducing the permeability and the filter loss of the drilling fluid.

The invention discloses a production method of a polymer for a drilling fluid, comprising the following steps: dissolving 2-methyl-2- acyloxy propyl sulfonate in water, then adding water in equimolar sodium hydroxide, stirring for dissolving and cooling, mixing the two mixtures and then adding a proper amount of acrylamide and acrylic acid, stirring for dissolving, heating up the mixed liquid to 35 DEG C with introducing nitrogen, then adding an initiating agent having an amount accounting for 0.05-0.08 % of the total weight of acrylamide and acrylic acid, uniformly stirring, then introducing nitrogen for a certain time, reacting for 8-10 h at a constant temperature of 35 DEG C to obtain a gel product, cutting and pelleting the gel product, and drying to obtain the polymer for the drilling fluid. The polymer produced by the invention has strong salt resistance and calcium pollution resistance, strong ability to inhibit clay hydrating and dispersing, and strong flocculation and coating capacities, can be applied in fresh water drilling fluid, salt-water drilling fluid, saturated salt-water drilling fluid, seawater drilling fluid and other drilling fluids, and has good compatibility with other treating agents to drilling fluid.

The invention relates to mosaic shielding drilling fluid, which comprises the following components by weight content: 0.2-8.5% of mosaic shielding agent, 0-5% of adhesion agent, 0-8% of weighting agent and the balance of base liquid, the mosaic shielding agent is added in water with a monomer, an initiator, a dispersant and rigid core, the components are uniformly stirred and heated to a reaction, and then dried to obtain the drilling fluid. The drilling fluid has unidirectional plugging effect due to usage of the mosaic shielding agent, and has good adaptability for inlet apertures with different shapes due to elastic variability characteristic, and the oil well production power can not be influenced.

The invention belongs to the technical field of water-soluble cationic compounds in petroleum drilling oilfield chemistry, and provides a modified cationic compound and a preparation method thereof, and a solid phase chemical cleaning agent for drilling fluids, wherein the modified cationic compound has a structure represented by a formula I, R is C1-C5 alkyl, X is halogen, t is an arbitrary integer selected from 0-6, and the solid phase chemical cleaning agent comprises an iron salt, an ammonium salt, a silicate and the modified cationic compound. According to the present invention, the solidphase chemical cleaning agent for drilling fluids is obtained by using the modified cationic compound, wherein the modified cationic compound has the structure represented by the formula I, and has double effects of flocculation and inhibition, such that the inhibition ability of drilling fluids and the drilling fluid solid phase removal efficiency can be improved so as to achieve low solid phaserapid drilling. The formula I is defined in the specification.

The invention provides a water-based drilling fluid composition and a water-based drilling fluid. The water-based drilling fluid composition comprises the following components in parts by weight: 100 parts of water, 4-10 parts of a filtrate reducer, 2-7 parts of a cationic polyacrylamide polymer inhibitor and 2-9 parts of a nano silicon dioxide blocking agent. On one hand, positive charges carried by the electropositive drilling fluid system containing the cationic polyacrylamide polymer inhibitor can reduce negative potentials of clay minerals and drilling cuttings, and well wall stability is promoted. And on the other hand, the nano-sized silicon dioxide blocking agent can reduce filtrate invasion and pressure transfer effect, so that the water-based drilling fluid can effectively solve the problem of borehole wall instability in the shale formation drilling process based on the two effects. Meanwhile, the electropositive drilling fluid system containing the cationic polyacrylamide polymer inhibitor can inhibit dispersion of drilling cuttings, so that the drilling speed is increased, and the raw materials are wide in source and low in cost.

The invention discloses an organic salt weighting agent which comprises an organic salt, the molecular formula of the organic salt is AR(COO)nMn, wherein A is a heteroatom or a group with a heteroatom, R is an organic carbon chain with a carbon number of 1-6, COO<-> is an organic carboxylate radical, and M is a metal cation or an ammonium ion. The organic salt weighting agent disclosed by the invention has the chemical molecular structure characteristics of formate, namely contains organic acid radicals such as COO <-> and cations such as low-valence alkali metal ions, shows relatively high density and relatively good temperature-resistant stability and inhibitive ability, can resist various types of pollution, and is beneficial to protecting an oil and gas reservoir. The drilling speed can be increased by using the drilling fluid, and production verifies that the drilling fluid is very suitable for drilling operation of complex wells in the Duha oil field.