The invention discloses an additive inhibiting 
biomass boiler coking. The additive is prepared from, by 
mass, 35-65% of kaolin, 30-60% of CaO and 5-35% of Mg(OH)2. When the additive is used, the addition proportion accounts for 0.5-2% of the total 
mass of 
biomass fuel. The additive can be directly mixed with 
biomass uniformly, then enters a 
combustion furnace by means of a feeding 
system of the boiler, and can be sprayed into a 
hearth uniformly along with an air inlet 
system, use is easy, and operation is easy. The additive has large 
porosity, the reaction area of the additive and the biomass fuel can be increased, pores in the surface of the additive have adsorption performance, 
alkali metal such as K and Na can be adsorbed to the surface of the additive effectively, the 
chemical reaction is carried out so that a high-melting-point substance can be generated, and ash deposition and 
slag bonding of the heated face are reduced; the amount of the adopted additive is small, efficiency is high, the coking resistant effect is remarkable, and the ash fusion point of the biomass can be remarkably increased.