The invention discloses a high-combustion-value fuel rod and a manufacturing process thereof. A formula of the high-combustion-value fuel rod adopts the following weight percentage: 20 to 40% of paulownia saw dust, 10 to 30% of paulownia bark, 5 to 12% of waster carbon powder, 2 to 6% of acidic pulp mill waste liquor, 15 to 40% of food sludge, 3 to 10% of waste paper pulp, 2 to 6% of glass cement and 4 to 12% of calcium oxide. Compared with the prior art, the high-combustion-value fuel rod and the manufacturing process thereof, which are disclosed by the invention, have the following advantages that: in the invention, by performing a reaction on the paulownia bark and the acidic pulp mill waste liquor under a certain conditions, the material structure in the paulownia bark is improved, combustible components in the high-combustion-value fuel rod are kept, and active components in the high-combustion-value fuel rodare increased, so that the fuel rod can be sufficiently burnt; macromolecular substances in the high-combustion-value fuel rod are degraded into low molecular weight organic matter, so that not only is a raw material easy to form, but also an adhesion degree of the fuel rod can be reinforced, and residues and offcut in the machining process are reduced; combustion heat of the fuel rod reaches about 4,600 Kcal/kg; the fuel rod can be used for equipment or processes with high requirements for heat.