The invention belongs to the technical field of glass lining glaze, and specifically discloses a one-time enameling and low-temperature firing glass lining glaze for oil field pipeline corrosion prevention, and a preparation method and applications thereof. The glass lining glaze is prepared from the following components in percentage by weight: 30 to 50% of SiO2, 5 to 20% of B2O3, 1-5% of Al2O3,2-5.5% of Li2O, 4 to 16.5% of K2O and Na2O; 1-6% of CaO, 1-1.5% of MnO2, 0.3 to 2% of CoO, 0.5 to 2% of NiO, 1 to 8% of CaF2, 1.2 to 7.5% of TiO2, 0.5 to 4% of ZrO2, 0.5 to 5% of ZnO, 0.5 to 5% of SnO2, 0 to 4% of MoO3, 0 to 3% of SrO, 0 to 2.5% of CeO2 and 0.5 to 8.5% of BaO. The highest firing temperature of the glass lining glaze is lower than 800 DEG C, an anticorrosive coating layer can be manufactured through one-time enameling, the production efficiency of the pipeline anticorrosive coating layer can be greatly improved, and the glass lining glaze is suitable for corrosion prevention ofoil field pipelines.