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34results about How to "Strong resistance to yellowing" patented technology

Preparation method of modified polytetrafluoroethylene dispersion concentrated solution

InactiveCN107652386AHigh Limit Membrane ThicknessImprove application processabilityTetrafluoroethylenePolymer science
The invention relates to a preparation method of a modified polytetrafluoroethylene dispersion concentrated solution. The polymerization reaction is carried out in three stages: in the first stage, controlling a reaction pressure to be in a range of 1.0-1.8 MPa and adding 20-30% of tetrafluoroethylene monomers and 40-60% of modified monomers; in the second stage, controlling the reaction pressureto be in a range of 2.0-3.0 MPa and adding 60-70% of tetrafluoroethylene monomers; and in the third stage, controlling the reaction pressure to be in a range of 2.0-3.0 MPa and adding residual tetrafluoroethylene monomers and residual modified monomers. According to the method disclosed by the invention, the pressure is operated in a variable pressure mode in the polymerization process, and recycling is performed twice in an intermediate process for realize a soft-hard-soft three-layer molecular structure of particles, so that the application processing performance of the dispersed concentrated solution is improved fundamentally, and the obtained polytetrafluoroethylene dispersion concentrated solution has the characteristics of extremely high yellowing resistance, good surface glossiness,high limit film-crack thickness, high smoothness, high cracking resistance, excellent non-viscosity and the like.
Owner:ZHONGHAO CHENGUANG RES INST OF CHEMICALINDUSTRY CO LTD

Self-repairing yellowing-resistant paint surface protective film and preparation method thereof

The invention discloses a self-repairing yellowing-resistant paint surface protective film and a preparation method thereof. The paint surface protective film is sequentially composed of a release film layer I, a pressure-sensitive adhesive layer, a TPU base material, a self-repairing coating and a release film layer II from bottom to top. The self-repairing coating is made of thermocuring functional polyurethane acrylate resin and comprises 20-50% of functional monomer modified acrylic resin, 10-30% of polymer polyol, 40-60% of a diluting solvent, 10-20% of a curing agent, 0.2-0.5% of a catalyst and 0.5-2% of an auxiliary agent, the TPU base material is optical-grade aliphatic TPU, the pressure-sensitive adhesive is an acrylate adhesive, and the release film layer is a PET silicone oil release film. The paint surface protective film prepared by the invention not only has excellent yellowing resistance and self-repairing performance, but also has high transparency, high glossiness, excellent scratch resistance, acid and alkali resistance, rain spot resistance and the like, so that the self-repairing yellowing-resistant paint surface protective film is suitable for the fields of automobile, furniture films and the like.
Owner:南阳金牛彩印集团有限公司 +1

Thermocuring self-repairing paint surface protective film and preparation method thereof

The invention provides a thermocuring self-repairing type paint surface protective film and a preparation method thereof. The paint surface protective film is sequentially composed of a release film layer A, a pressure-sensitive adhesive layer, a base material layer, a self-repairing coating and a release film layer B from bottom to top. The self-repairing coating is made of self-repairing thermocuring type modified polyurethane acrylate resin and comprises 10-18% of functionalized acrylic resin I, 10-18% of functionalized acrylic resin II, 12-35% of polymer polyol, 30-50% of a solvent, 15-30% of a curing agent, 0.05-0.2% of a catalyst and 0.3-1.0% of auxiliaries, and the base material is made of optical-grade aliphatic TPU, the pressure-sensitive adhesive is an acrylate adhesive, and the release film layer is a PET silicone oil release film. The paint surface protective film is simple in preparation process and easy for industrial batch production, the self-repairing coating has excellent scratch resistance, self-repairing performance, aging resistance, corrosion resistance, pollution resistance and the like after being thermally cured, and the self-repairing paint surface protective film can be widely applied to the fields of automobile and furniture paint surface protection, electronic equipment screen protection and the like.
Owner:南阳金牛彩印集团有限公司

Preparation method of anti-yellowing polyurethane artificial flower

The invention belongs to the technical field of polyurethane artificial flowers and particularly relates to a preparation method of anti-yellowing polyurethane artificial flowers. The preparation method comprises the following steps: stirring and mixing a component B and a component A according to an isocyanate index of 1.3 at the temperature of 75-80 DEG C, pouring the mixture into a preheated mold, demolding the shaped flowers after 12-15 minutes, and performing standing treatment for 7 days after demolding, thereby obtaining the yellowing-resistant polyurethane artificial flower. Compared with the prior art, the method is simple; by reasonably selecting an isocyanate raw material and a polyol raw material, reasonably controlling the isocyanate index and increasing free-NCO groups underthe condition of ensuring the mechanical strength, urea bonds are generated by cross-linking with water in the reaction process, so that the content of the urea bonds in chain segments is increased, and then the hydrophobicity of the composite material is improved; in addition, the benzene ring-containing polyester polyol is reasonably compounded, so that the mechanical properties of polyurethanecan be ensured, the influence of moisture in air on the prepared simulation flower is avoided, and the yellowing resistance is high.
Owner:界首市希捷仿真花卉有限公司

A kind of wide temperature dimming film and preparation method thereof

The invention relates to a wide temperature polymer dispersed liquid crystal which comprises a wide temperature polymer dispersed liquid crystal layer. Transparent conductive film layers are arrangedon the upper surface and the lower surface of the wide temperature polymer dispersed liquid crystal layer, and a sandwich structure is formed; the wide temperature polymer dispersed liquid crystal layer is made from wide temperature liquid crystals, wide temperature liquid crystal UV glue and introns. The clearing point of the wide temperature liquid crystals ranges from 95 DEG C to 119 DEG C, thefreezing point is lower than -30 DEG C or lower than -40 DEG C; the wide temperature liquid crystals are of a multiphenyls structure. The invention further provides a preparation method of the wide temperature polymer dispersed liquid crystal and the wide temperature liquid crystal UV glue applied to the same. The developed wide temperature polymer dispersed liquid crystal not only can keep normal on-state transparent under the low-temperature environment at -30--40 DEG C, but also has switch response under the high-temperature hostile environment at 80-100 DEG C, the excellent high and low temperature resistant property is achieved, the product can be selected for use according to different areas and special environments, and the polymer dispersed liquid crystal product application market is effectively expanded.
Owner:ZHUHAI SINGYES NEW MATERIALS TECH CO LTD

Production process of color-changeable stain-resistant leather mobile phone rear cover

The invention relates to a production process of a color-changeable stain-resistant leather mobile phone rear cover and relates to the technical field of mobile phone decoration and explosion prevention. The production process comprises the following steps that 1, embossed paper or an embossed film with leather texture is coated with a coating, a thermochromic material or a photochromic material or color sizing or color paste which is different in color and is fused with each other is added into the coating, then drying, curing and shaping are carried out, and a leather layer with the embossed paper or the embossed film is obtained; 2, the surface of the leather layer is coated with acrylic adhesive or silica gel or pressure-sensitive adhesive so as to form an adhesive layer on the leather layer; 3, a layer of a release film is attached to the adhesive layer; 4, the embossed paper or the embossed film is torn off, and the other surface of the leather layer is coated with a stain-resistant coating so as to form a stain-resistant layer on the other surface of the leather layer; and 5, the release film is stripped, and the adhesive layer is attached to the mobile phone rear cover layer to obtain the color-changeable stain-resistant leather mobile phone rear cover. By means of the production process, the functionality and aesthetic property of the mobile phone rear cover can be improved.
Owner:HENGSHAN JIACHENG NEW MATERIAL
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