The invention discloses a preparation method of a hollow spherical
barium-
strontium-
titanate powder material. The preparation method comprises the following steps of: adopting a hard template method for preparation: using glucose as a
raw material, using deionized water as a
solvent, and using cetylammonium
bromide as a dispersing agent to prepare a carbon-sphere template with negative charges onthe surface; dropping
metal precursor solution to the surfaces of the carbon spheres in batches, utilizing in-situ
hydrolysis reaction of the surfaces to prepare C@BSTO precursor composite microspheres, removing central carbon cores by high-temperature
calcination, and obtaining hollow spherical
barium-
strontium-
titanate powder with cubic
perovskite phase. For the obtained
powder, the size is uniform, the
crystallinity and the
dispersity are good, the size can be adjusted to be 0.7-3mu m by controlling the concentration of
metal ions, and the shell layer is about 90-300nm in thickness. The preparation method disclosed by the invention has the beneficial effects that the raw materials are easy to obtain, the
hazard to the health of a
human body is less due to no
toxicity and corrosiveness,the requirements for equipment are low; in addition, the preparation method has the characteristics that the process is simple, the process parameters are easily controlled, the product is stable in quality and is easily industrialized.