44 results about "Bis-triazine" patented technology

The invention relates to a triazine series oligomer and the compound method. The method has the following steps: adding solvent into cyanuric chloride, dropping alkylol amine and acid roping agent to gain substitute of cyanuric chloride; heating, dropping diamidogen and acid roping agent to gain the substitute of cyanuric chloride; adding diamidogen and acid roping agent into reaction solution, heating, pumping, washing, and drying to gain triazine series oligomer. The invention has strong charring and expanding ability, and good thermal stability. It has advantages of continuously reaction process, short reaction time, simple compounding technology, little organic solvent, and easy to recycle organic solvent.

The invention discloses seven novel 2,2'-dipyridine bridged bis-triazine compounds, particularly 6,6'-di(5,6-dialkyl-1,2,4-triazinyl-3-yl)-2,2'-dipyridine compounds with the side chain alkyl group of isobutyl, 3-methylbutyl, 4-methylamyl, 3-methylhexyl, 5-methylhexyl, 2-cyclopentylethyl or 2-cyclohexylethyl group and a preparation method thereof.2,2'-dipyridyl-6,6'-diiminohydrazide and alkyl substituted alpha-dione used as initial raw materials are heated to perform dehydration cyclization reaction for 5-24 hours by using tetrahydrofuran / triethylamine as a reaction solvent, thereby obtaining the seven 6,6'-di(5,6-dialkyl-1,2,4-triazinyl-3-yl)-2,2'-dipyridine compounds. The method has the characteristics of mild conditions, accessible raw materials, high target product yield and the like, and is simple to operate.

The invention relates to a fabric in dyeing industry, especially relates to white fabric. A high light fastness ultra-white fabric includes fabric to be treated. The bleaching process of the high light fastness ultra-white fabric is obtained by fluorescent whitening agent treatment and reduction bleaching. The fluorescent whitening agent mainly comprises derivatives of bis-triazine diphenyl ethylene. Preparation of the high light fastness ultra-white fabric includes steps of: putting the fabric to be treated into a treatment bath, adding pre-treatment agents BFN-07, hydrogen peroxide stabilizer PSL, NaOH, H2O2 in sequence, direct heating to 98 DEG C., keeping temperature for 60 minutes, lowering temperature, discharging water, neutralizing and water washing, adding the fluorescent whitening agent for treatment, and reduction bleaching or the like. The ultra-white fabric has great light fastness, meets the requirement for high-grade clothes and sport clothing, is great in hand-feeling and comfortable for wearing.

The invention belongs to the technical field of liquid whiteners, and particularly relates to a stilbene bis triazine liquid whitener and a preparation method thereof. The liquid whitener composition is composed of a fluorescent whitening agent C.I.71, polylol, polyethyleneglycol, a non-polyethyleneglycol nonionic surfactant, a cosolvent, sodium citrate, a preservative and deionized water. The composition is a transparent liquid with lower viscosity, can be stably stored at -15-45 DEG C for 6 months without stratification, caking or precipitation, can be easily added into a laundry detergent, and has obvious effects on enhancing the comprehensive detergency of the laundry detergent and especially whitening the white textiles.

The invention relates to a triazinone preparation method, which comprises: carrying out a hydrolysis reaction on 1-chloropinacolone at a temperature of 80-140 DEG C under the actions of a solvent andan alkali to obtain a compound I, wherein the solvent is water; carrying out an oxidation reaction on the compound I in the presence of oxygen by using Pt as a catalyst under a neutral or weakly basiccondition to obtain a compound II; and carrying out a ring closure reaction on the compound II and thiocarbohydrazide under the catalysis of an acid to obtain triazinone, wherein the structure formula of the compound I is defined in the specification, and the structure formula of the compound II is defined in the specification. According to the present invention, 1-chloropinacolone is used as theraw material, and the water is used as the solvent, such that the generation of high salt wastewater can be avoided; Pt is used as the catalyst, and oxygen is used as the oxidant, such that the use of hydrogen peroxide can be avoided, and the catalyst can be recycled so as to reduce the raw material cost; and the production method is simple, meets the environmentally friendly requirement, and issuitable for industrial production, and the yield and the content of the final product are high.

The invention relates to a continuous production method of a multi-kettle serial triazine herbicide. A metered cyanuric chloride solution is pre-cooled and mixed with alkylamine R1 in a mixer to entera first-stage reaction kettle, continuous discharging is conducted, after a heat exchanger is passed, the cyanuric chloride solution is neutralized with alkali in the mixer and enters a first-stage neutralization kettle, after a reaction is completed, the cyanuric chloride solution passes through a continuous water separator and the heat exchanger and is mixed with alkylamine R2 in the mixer to enter a second-stage reaction kettle, the continuous discharging is conducted, after the cyanuric chloride solution passes through the heat exchanger, the cyanuric chloride solution is mixed with the alkali in the mixer to enter a second-stage neutralization kettle, after the neutralization, a aqueous phase is separated by a continuous layerer, a solvent is removed, and drying is conducted to obtain a triazine product. The production method has the advantages of high productivity, good production stability, high efficiency, high product quality and the like, is particularly suitable for technical transformation of existing production enterprises, has a low transformation cost, basically does not add novel reaction equipment, and is easily mastered by existing enterprises.

The triazine exciplex material based on phosphine oxide and carbazole and its preparation method and application are to solve the technical problem that the existing blue light exciplex acceptor materials are few. The structure of the triazine exciplex material based on phosphine oxide and carbazole of the present invention is as follows: preparation method: monobromotriphenyltriazine, carbazole compound, anhydrous K 2 CO 3 After adding CuI to 1,3-dimethyl-2-imidazolinone for reaction, the intermediate compound is purified; then the intermediate compound is reacted with diphenylphosphine and palladium acetate in anhydrous DMF, and then purified to obtain the triazine exciplex-like materials. The material can be used in TADF and phosphorescent organic electroluminescent devices.

The present invention relates to a herbicidal composition containing mesotrione and amenzazone, which uses mesotrione and amenzazone as active ingredients, and the weight ratio of the active ingredients is mesotrione: amfenflumele =1~90:90~1, the active ingredient accounts for 1%~99% by weight of the herbicidal composition. The herbicidal composition of the present invention can be used for soil sealing and post-emergence stem and leaf treatment by compounding mesotrione and amenzazone. The application period is long, the weeding effect is good, and the dosage is less than 1% of triazine agents. / 3-1 / 5, and can solve the problems of safety and water pollution after cropping, so the combination of the two has good economic and social benefits.

The invention relates to a continuous production method of a multi-kettle serial triazine herbicide. A metered cyanuric chloride solution is pre-cooled and mixed with alkylamine R1 in a mixer to entera first-stage reaction kettle, continuous discharging is conducted, after a heat exchanger is passed, the cyanuric chloride solution is neutralized with alkali in the mixer and enters a first-stage neutralization kettle, after a reaction is completed, the cyanuric chloride solution passes through a continuous water separator and the heat exchanger and is mixed with alkylamine R2 in the mixer to enter a second-stage reaction kettle, the continuous discharging is conducted, after the cyanuric chloride solution passes through the heat exchanger, the cyanuric chloride solution is mixed with the alkali in the mixer to enter a second-stage neutralization kettle, after the neutralization, a aqueous phase is separated by a continuous layerer, a solvent is removed, and drying is conducted to obtain a triazine product. The production method has the advantages of high productivity, good production stability, high efficiency, high product quality and the like, is particularly suitable for technical transformation of existing production enterprises, has a low transformation cost, basically does not add novel reaction equipment, and is easily mastered by existing enterprises.

The invention provides a preparation method of a fused-ring pyridone compound, and belongs to the field of pharmaceutical chemicals. The method comprises the following steps: performing a reaction ona morpholine ring compound with an activating reagent to obtain a morpholine ring compound with a leaving group; then adding a pyridone compound and performing a reaction under certain conditions to obtain a triazine compound; and adding a reducing agent, and performing a reaction under different conditions to respectively obtain a racemic fused-ring pyridone compound or a chiral fused-ring pyridone compound. The method has the characteristics of high product purity, high yield, low cost, simplicity in operation and the like.

The invention discloses a triazine lignin-based magnetic adsorption material and a preparation method thereof. The preparation method comprises the following steps of: dispersing lignin and magnetic Fe3O4 in a solvent medium; reacting a mixed liquid in the previous step with cyanuric chloride at 0-120 DEG C for 2-48 hours under the catalytic action of alkali; and performing separation and purification to obtain the triazine lignin-based magnetic adsorption material. The preparation method is simple and convenient in preparation process, high in yield and low in cost. The molecular structure ofthe prepared magnetic adsorption material contains rich heteroatom adsorption sites such as nitrogen and oxygen, so that the magnetic adsorption material can quickly adsorb heavy metal ions and organic pollutants in a water body with high capacity, has excellent magnetic response performance, has the advantages of easiness in magnetic separation, recycling performance and the like, and can be applied to the fields of heavy metal ion and organic dye-containing wastewater treatment, water body purification and the like in mining, electrolysis, printing and dyeing and other industries.

The invention discloses a method for preparing 3-mercapto-5-methyl-1,2,4-triazole from a triazine ring, comprising the following steps in sequence: (1) dissolving the triazine ring in water to obtain the triazine ring solution; (2) adding acid to the triazine ring solution to adjust the pH value of the solution to 2-3; (3) heating up and refluxing; (4) after refluxing, cooling and solid-liquid separation to obtain a filtrate; (5) decompressing the filtrate Distill until a white solid appears; (6) Cool the temperature for solid-liquid separation to obtain a solid material; (7) Dry to obtain 3-mercapto-5-methyl-1,2,4-triazole. The present invention uses triazine ring as raw material to prepare 3-mercapto-5-methyl-1,2,4-triazole through transformation, the process is simple, the yield is high, the generated three wastes are few, the environmental pollution is small, and the A new efficient and safe preparation method.

The invention discloses a method for decomposing and recovering methylhydrazine residues of triazine rings. Adding residues of triazine rings, water and copper salt into a reaction bottle, starting stirring, raising the temperature to 80-130°C for 2-5 hours, and following the reaction Carry out, extract distillate fraction from reaction bottle, distill distillate after distillate adds alkali, distill out composition and be the mixture of methylhydrazine and water. The present invention hydrolyzes the by-product triazine ring residue to recover methylhydrazine and is used for the synthesis of 2-methylthiosemicarbazide, further synthesizing the triazine ring, utilizing waste resources, solving the problem that the industrialization of the triazine ring residue is difficult to handle, and realizing The triazine ring residue is recycled to methylhydrazine and then to the triazine ring. No solvent is used, which eliminates the disadvantages of flammability, explosion and high cost of organic solvents; the raw material is only the triazine ring residue reacts with water, and the copper salt is used as a catalyst to recover and produce methylhydrazine, and hydrolyze the triazine ring residue into small Molecular salt, easy to handle, safe and environmentally friendly, low cost, suitable for industrial production.

The invention belongs to the technical field of a fluorescent whitening agent and a preparation method thereof, and particularly relates to a special stilbene bis-triazine fluorescent whitening agent for detergents and a preparation method thereof. The special stilbene bis-triazine fluorescent whitening agent for detergents mainly solves the problems of poor whitening effect and high cost in the existing fluorescent whitening agent. The technical scheme is as follows: the preparation method of the stilbene triazine fluorescent whitening agent comprises the following steps: (1) weighing raw materials; (2) preparing a product IV; (4) uniformly mixing aniline and meta-chloroaniline, and adding the product IV in the step (3) to obtain products V, VI and VII; (5) preparing a composition of I, II and III; (6) carrying out acid precipitation; (7) drying; and (8) preparing the stilbene triazine fluorescent whitening agent. The stilbene triazine fluorescent whitening agent has the advantages of favorable whitening effect, low cost and the like.