The invention provides black liquid charcoal. The raw materials of the charcoal comprise at least fuel wood, shrubs, branches, barks, wood processing residues or deserted artificial boards and the like, two components of the raw materials and alkali lignin are mixed, and then cooling compression molding is conducted through a pressing machine, and carbonization is conducted so that the black liquid charcoal is made. The fuel wood, the shrubs, the branches, the barks, the wood processing residues or the deserted artificial boards and the like are hard to be utilized by machine-made charcoal manufacturing and are usually burned off or rotted, utilization degree is low, the alkali lignin is also a problem in black liquid recycling management, the alkali lignin is produced by soda pulping or sulfate pulping through acidification, the alkali lignin has the characteristics of high-viscosity and high-calorific value, the two components of the raw materials and the alkali lignin are mixed and then the cooling compression molding is conducted through the pressing machine, and carbonization is conducted so that the black liquid charcoal is made. The produced carbon is high in caloric value, not prone to crushing, high in application range and utilization rate, in addition a large number of alkali lignin resources produced in the process of pulping and papermaking can be utilized sufficiently, and therefore the pressure of environmental management is relieved.