The invention discloses a method for controlling brittleness Laves phases in the laser additive manufacturing process of a nickel-based high-temperature alloy. Firstly, laser additive manufacturing technological parameters are initially optimized, and a cooling medium is adopted for cooling the bottom of a base material; then a laser modulation technology is used for modulating a laser source, and superior laser modulation parameters are obtained, wherein the peak power of square waves ranges from 600 W to 1000 W, the pulse frequency of the square waves ranges from 10 HZ to 100 HZ, and the duty ratio of the square waves ranges from 0.3 to 0.6; the wave peak power of sawtooth waves ranges from 600 W to 1200 W, the wave trough power of the sawtooth waves is 0 W, and the pulse frequency of the sawtooth waves ranges from 10 HZ to 100 HZ; and according to the parameters of sine waves, the wave peak power ranges from 600 W to 1000 W, the wave trough is 0 W, and the pulse frequency ranges from 10 HZ to 100 HZ; and finally, laser additive manufacturing and forming of the nickel-based high-temperature alloy are conducted according to the above parameters, and a formed part with all small equiaxial dendritic structures and small discrete Laves phases is obtained. By means of the laser modulation method, the precipitation behavior of the Laves phases in the laser additive manufacturing process of the nickel-based high-temperature alloy can be effectively controlled, the cracking sensibility of parts obtained through laser additive manufacturing is reduced, and the microstructure is improved.