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381results about "Carboxyl rubber adhesives" patented technology

Benzimidazole diamine curing type epoxy adhesive and preparation method thereof

InactiveCN102031082AHigh tensile and shear strength at room temperatureConvenient sourceNon-macromolecular adhesive additivesCarboxyl rubber adhesivesViscous liquidElectronics
The invention relates to a benzimidazole diamine curing type epoxy adhesive and a preparation method thereof. The adhesive is prepared from the following raw materials: a component A, namely a benzimidazole diamine curing agent and a component B, wherein the component B is prepared from terminal carboxyl group butadiene-nitrile rubber, epoxy resin and a reactive diluent. The preparation method comprises the following steps of: (1) adding the terminal carboxyl group butadiene-nitrile rubber and the epoxy resin into a reaction kettle, reacting at the temperature of 90 DEG C with stirring, cooling to the temperature of 50 DEG C, adding the reactive diluent, and stirring at the temperature of 80 DEG C to obtain homogeneous and transparent viscous liquid, namely the component B; and (2) mixingthe components A and B, and stirring uniformly to obtain the adhesive. The tensile shear strength of the adhesive is 33.5MPa at the room temperature, and the adhesive has wide application prospect infields of electronics and microelectronics, rigid copper-clad laminates, motors, aerospace and the like; and the preparation process is simple, is low in cost and is convenient to operate, the resources of reaction raw materials are wide, and the adhesive can be conveniently industrially produced.
Owner:DONGHUA UNIV +1

High-performance thermosetting epoxy asphalt binder and preparation method thereof

The invention discloses a high-performance thermosetting epoxy asphalt binder, comprising a part A component and a part B compound, wherein the part A component comprises 100 weight parts of epoxy resin, 20-35 weight parts of flexibilizer, 0.5-2 weight parts of promoter, and 8-20 weight parts of diluent; the part B component comprises 300-350 weight parts of asphalt, 150-160 weight parts of flexible curing agent, 10-15 weight parts of promoter, 2-5 weight parts of compatilizer, and 100 weight parts of diluent; and the ratio of the part A component to the part B component is 100:350-440. According to the invention, by using flexible long-chain fatty acid anhydride as the curing agent and carrying out solidification reaction on the curing agent with the epoxy resin, a stereo cross-linked structure is formed, and the bonding capability and water resistance of asphalt are increased; by using liquid rubber as the flexibilizer, the flexibility of the epoxy asphalt binder is raised to adapt to the flexibility of a steel plate, and by prereacting the flexibilizer with epoxy resin firstly for grafting, the compatibility between the epoxy asphalt binder and asphalt is raised. The epoxy asphalt binder is suitable for bonding and waterproofing of steel bridge floor, cement concrete bridge floor, tunnel, highway and other pavements. The invention also discloses a preparation method of the epoxy asphalt binder.
Owner:NANJING UNIV

High-performance tyre curtain glue stock containing resorcinol-formaldehyde adhesion system

The invention relates to a high performance tire fabric rubber compound with a resorcinol-formaldehyde adhesion system, and comprises outer layer cord fabric rubber compound and cushion rubber compound. The key points are that: the invention is made by a plurality of raw materials, wherein, the adhesion system thereof adopts the resorcinol-formaldehyde adhesion system. The raw materials of the outer layer cord fabric rubber compound are natural rubber, rosin extended styrene-butadiene rubber, butadiene rubber, carbon black N330/N660, zinc oxide, stearic acid, age inhibitor 4010NA/RD /BLE, oil-extended butadiene sulphur powder (S), aromatic oil, accelerant CZ/TMTD, RF-90 resin and adhesive RA-65. The raw materials of cushion the rubber compound are natural rubber, rosin extended styrene-butadiene rubber, carbon black N330/N660, zinc oxide, stearic acid, age inhibitor 4020/RD, oil-extended butadiene sulphur powder (S), aromatic oil, accelerant CZ/TMTD/DM, vulcanized agent DTDM, RF-90 resin and adhesive RA-65. The invention is essentially used for the outer layer cord fabric rubber compound and the cushion rubber compound in a bias tire. H pullout force can be obviously enhanced by using the rubber compound of the invention; the problem of cord fabric delaminating in practical use can be reduced by using the bias tire made from the rubber compound of the invention.
Owner:SICHUAN TYRE & RUBBER CO LTD

Flame retardant adhesive composition, and adhesive sheet, coverlay film and flexible copper-clad laminate using same

InactiveUS20060234043A1Excellent flame retardancy and electrical characteristicExcellent characteristicsNon-macromolecular adhesive additivesAdhesive articlesEpoxyCopper foil
Provided is a flame retardant adhesive composition including (A) a halogen-free epoxy resin, (B) a thermoplastic resin and/or a synthetic rubber, (C) a curing agent, (D) a nitrogen-containing polyphosphate compound, and (E) a curing accelerator. Also provided are an adhesive sheet having a layer including the above composition, and a protective layer for covering the layer including the composition; a coverlay film having an electrically insulating film, and a layer including the above composition provided on top of the film; a flexible copper-clad laminate having an electrically insulating film, a layer including the above composition provided on top of the film, and copper foil; and a method of bonding two substrates, including the steps of sandwiching the above adhesive sheet between two substrates, and curing the adhesive sheet. Further provided are a process for producing the adhesive sheet, a process for producing the coverlay film, and a process for producing the flexible copper-clad laminate. The halogen-free adhesive composition yields a cured product, on curing, that exhibits excellent flame retardancy and anti-migration properties. The composition can be used for producing an adhesive sheet, a coverlay film, and a flexible copper-clad laminate. The adhesive sheet can be used for a method of bonding two substrates.
Owner:SHIN ETSU CHEM IND CO LTD

Halogen-free flame-retardant epoxy resin composition, and adhesive film and copper-clad plate prepared from same

ActiveCN102127289AHigh tracking characteristicsHigh CTIFilm/foil adhesivesSynthetic resin layered productsOrganic solventCopper foil
The invention relates to a halogen-free flame-retardant epoxy resin composition, and an adhesive film and a copper-clad plate prepared from same. The halogen-free flame-retardant epoxy resin composition comprises bisphenol A type epoxy resin, carboxylic group terminated butylnitrile rubber, phosphorus-containing resin, nitrogen flame retardants, amine curing agents, a curing accelerator, a fillerand an organic solvent. The adhesive film prepared from the halogen-free flame-retardant epoxy resin composition comprises a release film and the halogen-free flame-retardant epoxy resin composition coated on the release film. The copper-clad plate prepared from the halogen-free flame-retardant epoxy resin composition comprises a laminated sheet, an adhesive film clad on one side or two sides of the laminated sheet, and a copper foil pressed and clad on the adhesive film, wherein the laminated sheet comprises a plurality of glued bonding sheets; and the adhesive film comprises a release film and the halogen-free flame-retardant epoxy resin composition coated on the release film. The halogen-free flame-retardant epoxy resin composition has a high creepage tracking characteristic and good comprehensive performance such as flame retardancy and the like.
Owner:GUANGDONG SHENGYI SCI TECH

Low-halogen-content fire-retardant adhesive and flexible copper clad laminate prepared from same

The invention relates to a low-halogen-content fire-retardant adhesive and a flexible copper clad laminate prepared from the same. The low-halogen-content fire-retardant adhesive comprises synthetic rubber, brominated epoxy resin, biphenyl type epoxy resin, phosphonitrile compounds, an aromatic amine curing agent, an imidazole curing accelerator, inorganic filler, an ion exchanger, an oxidation inhibitor and a solvent. The flexible copper clad laminate prepared from the fire-retardant adhesive comprises a polyimide film, a low-halogen-content fire-retardant adhesive layer and copper foil, wherein the low-halogen-content fire-retardant adhesive layer is coated on the polyimide film, and the copper foil is pressed on the low-halogen-content fire-retardant adhesive layer. The fire-retardant adhesive has low halogen content, excellent flexibility, heat resistance, adhesion property and humidity resistance. The flexible copper clad laminate has excellent flexibility, folding resistance, deflection resistance, dip soldering resistance, ion mobility resistance and high peeling strength, the flame retardance reaches the UL94V-0 grade, and the flexible copper clad laminate is suitable for manufacturing a flexible printed circuit board.
Owner:GUANGDONG SHENGYI SCI TECH

Sheet/branch silver-coated copper powder and green halogen-free low-silver-content economical electrically conductive adhesive capable of replacing traditional electrically conductive adhesives with high silver contents

The invention relates to sheet/branch silver-coated copper powder, a green halogen-free low-silver-content economical electrically conductive adhesive capable of replacing traditional electrically conductive adhesives with high silver contents, and a preparing method of the electrically conductive adhesive. The morphology of the sheet/branch silver-coated copper powder is in a sheet shape and/or a branch shape. The silver coating area rate on the surface of copper powder is 90-95%. The content of a zinc-aluminum alloy in the silver-coated copper powder is lower than 15 wt%. The electrically conductive adhesive comprises following raw materials by weight: 60-90% of the sheet/branch silver-coated copper powder, 0-30% of micron order silver power, 6-12% of epoxy resin, 1-8% of an active diluting agent, 1-6% of toughening resin, 1-3% of a curing agent, 0-1% of a curing promoter and 0.5-2% of a coupling agent. The sheet/branch silver-coated copper powder is high in silver coating rate on the surface of Cu and excellent in electrically conductive performance, so that the electrically conductive adhesive prepared from the sheet/branch silver-coated copper powder is excellent in performance, low in cost and good in intrinsic conductivity.
Owner:重庆邦锐特新材料有限公司

Heat-cured high-intensity flaky adhesive for automobile and preparation method thereof

The invention provides a heat-cured high-intensity flaky adhesive for an automobile and a preparation method thereof. The heat-cured high-intensity flaky adhesive for the automobile comprises three layers, wherein the upper layer is made of glass fiber cloth, the middle layer is made of a high-intensity adhesive, and the bottom layer is made of barrier paper. The high-intensity adhesive is prepared from synthetic rubber, a plasticizer, epoxy resin, thermoplastic resin, tackifying resin, a curing agent, a vulcanizing agent, an accelerating agent, an anti-aging agent and calcium carbonate. Due to the adoption of the flaky adhesive, the rigidity of a metal sheet can be increased greatly in the automobile manufacturing process, the running noise of the automobile can be reduced, and the comfort and the safety of the automobile are ensured. The heat-cured high-intensity flaky adhesive has high adhesion to an oil surface metal material, can be operated manually and directly in the construction process, is non-sticky, nontoxic and tasteless, has high manufacturability, is prevented from moving, and is convenient to use. The flaky adhesive can be cut according to different requirements onpositions, sizes and shapes and can be stored for over 3 months at the temperature of 25 DEG C.
Owner:三友(天津)高分子技术有限公司

Method for preparing flexible heat conducting insulating adhesive film used in LED heat radiation substrate

A method for preparing flexible heat conducting insulating adhesive film used in an LED heat radiation substrate comprises the preparation of a flexible heat conducting insulating adhesive and that of the flexible heat conducting insulating adhesive film, wherein the flexible heat conducting insulating adhesive comprises liquid epoxy resin, solid epoxy resin, flexibilizer, curing agent, high-heat conductivity inorganic packing, organic solvent, coupling agent, dispersing agent and flatting agent. The method for preparing the flexible heat conducting insulating adhesive film comprises the following steps: coating the flexible heat conducting insulating adhesive on a release film through a coating machine; baking through a temperature control baking channel to obtain an flexible heat conducting insulating adhesive layer used in the LED heat radiation substrate; coating the release film on the adhesive surface in a compounding manner; and rolling and forming to obtain the flexible heat conducting insulating adhesive film used in the LED heat radiation substrate. The adhesive film used in the LED heat radiation substrate has the characteristics of high heat dissipation, insulation, heat resistance and peel strength, flexibility and the like.
Owner:HAISO TECH

Bio-based epoxy resin composition and application thereof in preparing epoxy resin film

The invention discloses a bio-based epoxy resin composition. The bio-based epoxy resin composition comprises the following raw materials: 100 parts of bio-based epoxy resin and 5 to 50 parts of a curing agent; and the structural general formula of the bio-based epoxy resin is shown in the following formula. In the formula, x is an integer selected from 1 to 5, R1 to R4 are independently selected from a phenyl, a vinyl group, and an alkyl group having 1 to 10 carbon numbers. The bio-based epoxy resin is siloxane chain segment-containing eugenol bio-based epoxy resin, and main reaction functional groups are eugenol epoxy groups, and siloxane chain segments are introduced in a molecular skeleton, thereby being capable of greatly reducing the viscosity of the system and improving the processing fluidity, siloxane in macromolecular volume can further greatly improve dielectric properties and reduce dielectric constants, and has intrinsic flame retardant properties. The epoxy resin composition taking siloxane as a substrate can realize intrinsic flame retardation without adding a flame retardant, and the epoxy resin film prepared by using the composition has outstanding flame retardancy,adhesive properties and bending strength, and further is high in dielectric strength.
Owner:江苏和和新材料股份有限公司
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