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120results about How to "High fixed carbon content" patented technology

Method for biomass carbonization instead of pulverized coal injection in blast furnace

The invention provides a method for biomass carbonization instead of pulverized coal injection in a blast furnace. Dried straw and other biomass raw materials are extruded to obtain a machine-made rod, and the machine-made rod is carbonized by a carbonization furnace to obtain carbon powder at a temperature of 300 to 1000 DEG C. The carbon powder obtained by the furnace is mixed with pulverized coal and injected into the blast furnace to greatly reduce a coal ratio and flux usage amount and improve production efficiency; latent heat of flue gas is fully utilized to reduce emission of exhaust gas; the exhaust gas discharged from a combustion chamber is filtered and discharged into air through a microporous ceramic tube. Biomass resources and sensible heat of the flue gas, and oxygen and carbon monoxide in the flue gas are used in ironmaking production. In addition, the biomass resources can also be used as a substitute for the pulverized coal or coke powder used in iron ore sintering machines. The method comprehensively utilizes existing equipment to treat waste materials such as biomass raw materials and the flue gas, saves coking coal resources, fully exerts potential advantages of biomass energy, protects environment, and reduces costs.
Owner:UNIV OF SCI & TECH BEIJING

Combined carbonaceous reducing agent for smelting metal silicon and preparation method thereof

ActiveCN102976330AMeet physical and chemical performance requirementsPoor improvementSilicon compoundsPetroleumPetroleum coke
The invention discloses a combined carbonaceous reducing agent for smelting metal silicon and a preparation method thereof. The combined carbonaceous reducing agent comprises refined pulverized coal and petroleum coke powder, wherein the refined pulverized coal accounts for 70-80% of the total weight; the refined pulverized coal is prepared from the raw material soft coal by oil agglomeration selective flocculation de-ashing treatment; the refined pulverized coal contains 75-80% of fixed carbon, 3.5-4.5% of ash content and 16-21% of volatile content by weight; and 2-3% of binder is added into the mixture of the refined pulverized coal and the petroleum coke powder, and then a combined carbonaceous reducing agent pellet is prepared by cold press molding briquetting and drying treatment. According to the invention, the ash content and impurities in the soft coal are removed by a flotation method, the petroleum coke powder serves as supplement of the fixed carbon, and the two are combined to obtain a combined carbonaceous reducing agent with high content of fixed carbon, low ash content and low content of impurities. Through the invention, the problem that the reducing effect is unsatisfactory by using the soft coal only is solved, the smelting efficiency and the product quality are improved, and the added value of the soft coal is increased.
Owner:KUNMING METALLURGY INST

Carburant and preparation method thereof

The invention discloses a carburant and a preparation method thereof, and the technical problem to be solved is to improve the quality of the carburant. The carburant is composed of a graphite material and a bonding agent, wherein the graphite material is obtained by mixing micro-powder graphite and electrode powder, and the bonding agent is composed of an inorganic bonding agent and an organic bonding agent. The preparation method for the carburant comprises the following steps: uniformly mixing the micro-powder graphite with the electrode powder to obtain a mixture; carrying out thermal treatment on the mixture; mixing the inorganic bonding agent with the organic bonding agent; and adding the bonding agent into the graphite raw material to carry out pelletizing, thereby obtaining the carburant. Compared with the prior art, the fixed carbon content of the carburant is high, and the carburant is high in volumetric absorption capacity with iron parts and steel parts in a molten iron casting process, so that the quality of castings is improved, and the problems that the steel parts are easily cracked as a result of poor anti-impact toughness and low cracking energy absorption due to the fact that local stress concentration is caused by a great number of pores and crazes generated on the surfaces of the castings are overcome. The carburant prepared by the preparation method is high in pelletizing and molding ratio, and is low in production cost.
Owner:NINGXIA KOCEL ENERGY CO LTD

A process for preparing high-purity microcrystalline graphite with low energy consumption and in a large scale, and the high-purity microcrystalline graphite

The invention relates to the technical field of microcrystalline graphite purification, and discloses a process for preparing high-purity microcrystalline graphite with low energy consumption and in alarge scale, and the high-purity microcrystalline graphite. According to the process, microcrystalline graphite raw ore is firstly crushed and ground, and flotation including one time of roughing, four times of cleaning and one time of scavenging is performed in match to increase the purity of the raw ore to the utmost through a physical method; an improved acid leaching purification method is adopted, the alkali leaching efficiency is increased, energy consumption is reduced, and the graphite recovery yield is increased; and finally a high-temperature purification method adopting a step-by-step heating manner is utilized to further reduce energy consumption for graphite purification, and the high-purity microcrystalline graphite the fixed carbon content of which is 99.993% or above can be finally obtained. The process overcomes a problem that microcrystalline graphite in the prior art is not high in purity, high in energy consumption and high in cost. Through improvements on the prior art, the process achieves an objective of reducing energy consumption and the cost, and achieves industrial production.
Owner:HUNAN GUOSHENG GRAPHITE TECH CO LTD

Microcrystalline graphite high temperature pretreatment-alkaline acid method purification method

The invention belongs to the technical field of microcrystalline graphite purification, and more specifically relates to a microcrystalline graphite high temperature pretreatment-alkaline acid methodpurification method. The microcrystalline graphite high temperature pretreatment-alkaline acid method purification method comprises following steps: microcrystalline graphite ore is subjected to smashing and grinding to a certain particle size; high temperature heat treatment is adopted; after heat treatment, the obtained microcrystalline graphite is subjected to pressurization alkaline leaching and normal pressure acid leaching so as to obtain microcrystalline graphite finished products. According to the microcrystalline graphite high temperature pretreatment-alkaline acid method purificationmethod, pressurization alkaline leaching is adopted to replace high temperature calcining, after heat treatment, alkaline leaching temperature in alkaline acid method purification process of microcrystalline graphite can be reduced, alkaline leaching efficiency is increased, energy consumption is reduced, and graphite recovery rate is increased. The microcrystalline graphite high temperature pretreatment-alkaline acid method purification method is capable of increasing microcrystalline graphite fixed carbon content to be 98% or higher.
Owner:HUNAN GUOSHENG GRAPHITE TECH CO LTD

Biomass gasification residue formed activated carbon and preparation method thereof

The invention discloses biomass gasification residue formed activated carbon and a preparation method thereof. The preparation method comprises the following steps: uniformly mixing a raw material with a high-temperature adhesive, activation aids and a normal-temperature adhesive, carrying out extrusion molding in a molding machine, carrying out drying hardening, and carbonizing and activating ina high-temperature furnace, thereby obtaining a finished product of activation carbon, wherein biomass gasification residue carbon powder is used as the raw material. After the normal-temperature adhesive is mixed with the carbon powder and the high-temperature adhesive, a molding function is achieved, and convenience can be brought to extrusion molding or shaping of the raw material; in the high-temperature carbonization and activation process, the normal-temperature adhesive is burnt to generate pores, and the high-temperature adhesive is heated and molten to achieve an adhesion effect at the moment; due to addition of the activation aids, the reaction activity of gasification residues can be improved; the strength of the activated carbon is up to 99%, the iodine sorption value of the activated carbon is up to 900 mg / g, and the methylene blue adsorption value of the activated carbon is up to 180 mg / g.
Owner:INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY

Preparation method of biomass charcoal composite fuel for blast furnace injection

The invention provides a preparation method of a biomass charcoal composite fuel for blast furnace injection, which comprises the following steps: mixing crushed biomass raw materials and low metamorphic coal, carrying out hydrothermal carbonization treatment, then mixing with preheated high metamorphic coal, carrying out heat preservation, and finally carrying out hot pressing treatment. According to the method, the yield of biomass hydrothermal carbonization is increased by utilizing mineral substances in the low-rank coal, and meanwhile, ash, volatile components and water in the low-rank coal can be partially removed, so that the caking property is improved. And then the mixture is mixed with the preheated high-metamorphic coal, so that the ignition point of the mixture can be improved, the explosiveness of the mixture is reduced, and the ash fusion point of the composite fuel can be further improved by utilizing the characteristic of high ash fusion point of the high-metamorphic coal. The biomass charcoal composite fuel can completely replace fossil fuel to be used for blast furnace injection, the emission amount of carbon dioxide and pollutants in the ironmaking production process is reduced, and in addition, the fuel formed through hot pressing has the advantages of being large in volume density and high in compressive strength and is suitable for long-distance transportation and long-term storage.
Owner:BAOSHAN IRON & STEEL CO LTD +1

Uniform ultra-microporous activated carbon for gas separation and preparation method of uniform ultra-microporous activated carbon

The invention relates to uniform ultra-microporous activated carbon for gas separation and a preparation method of the uniform ultra-microporous activated carbon. According to the technical scheme of the preparation method, mixing semi-coke with KOH in a mass ratio being 1: (0.01-0.2), adding water and an activating aid to impregnate the mixture for 1-36 h; increasing the temperature to 800-950 DEG C in a programmed manner under N2 protection, controlling thermal decomposition, and introducing water for activation of part of steam for 0.5h-1.5h; finally, washing the mixture with acid and water until the mixture is neutral to obtain the uniform ultra-microporous activated carbon. The pore size is distributed centrally between 0.45 and 0.55 nm, the pores belong to ultra-micropores and have microporosity of 70% or more, and the adsorption capacity of hydrogen is 77cm<3>/g or higher. The semi-coke is taken as a raw material, low in price and low in energy consumption and needs not to be carbonized; an activation method integrates KOH impregnation pretreatment and activation of part of steam, little KOH is consumed, and the activation method has the characteristics of being low in cost and pollution, helpful for reducing corrosion of equipment and the like. The activated carbon prepared with the method has the characteristics of uniform pore size distribution, extremely rich ultra-microporous structure and the like, and can be used in gas separation fields such as pressure swing adsorption hydrogen making or hydrogen storage and the like.
Owner:WUHAN UNIV OF SCI & TECH

Method and device for preparing hydrogen-enriched fuel gas through sawdust charcoal gasification by high-temperature water vapor

The invention discloses a method and a device for preparing hydrogen-enriched fuel gas through sawdust charcoal gasification by high-temperature water vapor. Sawdust charcoal is used as a raw material, and water vapor is used as a gasification medium, so as to prepare the hydrogen-enriched fuel gas. The method mainly comprises the following steps: helical feeding of sawdust charcoal, generation of water vapor, gasification of sawdust charcoal and cooling of hydrogen-enriched fuel gas. The water vapor is supplied by a water vapor generator in the early stage; after the system is stabilized, the water vapor is supplied by a waste heat recycling device; the temperature of a reactor is 800 to 950 DEG C; and the hydrogen-enriched fuel gas is prepared under technological conditions of proper reaction temperature, flow of the water vapor, particle size of the raw material, reaction time and the like. According to the method, the hydrogen-enriched fuel gas with the hydrogen volume percentage of 61.2 to 65.8 percent and the maximum hydrogen yield of 113.5 mmol/g can be prepared. The method has the advantages that the hydrogen volume percentage of the fuel gas is high, no tar is generated, and the gasification device is simple in structure; and the hydrogen-enriched fuel gas can be applied to preparation of high-purity hydrogen, synthesized natural gas, liquid fuel including methyl alcohol and dimethyl ether, and the like.
Owner:INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY

Method for preparing coking raw material through biomass hydrothermal carbonization treatment and application of coking raw material prepared by method to coking production

PendingCN111978970AAddressing Distribution Inconsistency BiasDistribution inconsistency deviation is smallBiofuelsSpecial form destructive distillationPollutant emissionsCoke
The invention provides a method for preparing a coking raw material through biomass hydrothermal carbonization treatment and application of the coking raw material prepared by the method to coking production. According to the method, firstly, crushed biomass is subjected to hydrothermal carbonization treatment; by controlling the hydrothermal carbonization temperature and time, high-quality biomass hydrothermal carbon with the low ash content, the low alkali metal content, the high fixed carbon content and the proper water content is obtained, so that the performance of the biomass hydrothermal carbon meets the quality requirement of coking production; then, the biomass hydrothermal carbon and base coal are mixed, a proper amount of water is added for uniform mixing, and the coking raw material is obtained; and the water content in the coking raw material is regulated and controlled to be 6 to 12 percent, and the coking production is performed. On the premise that the mechanical strength and the reaction performance of the produced coke are enabled to meet the blast furnace ironmaking requirement, the goals of realizing resource utilization of the biomass, reducing the coking cost,saving coking coal resources and reducing CO2 and pollutant emission are also achieved; and good environmental and economic benefits are achieved.
Owner:UNIV OF SCI & TECH BEIJING

Formed coke clean production method and equipment

The invention discloses a preparation method for formed coke and a piece of equipment, in particular to a method of using coke powder or anthracite, mill coal as primary material, adding powder normal temperature adhesive and coal tar powder, fully mixing, cold molding and performing, putting the coke adobe into a tunnel carbonization stove, giving a low temperature oxidation treatment to the coke adobe, to produce formed coke with a high quality. The forming equipment is over 24 times more efficient than the existing equipment by using multicavity composite mold and automatic feeding-ejection apparatus; the material needs no processing of drying and heat plasticizing; the elementary composition of the body can be adjusted freely; the formed coke has low sulfur content, low ash content, high fixed carbon content, no smoke in the combustion, high iron-coke ratio and good watertightness in the long time preservation. The investment scale with the same production capacity is only one twentieth of the heat seal - carbonization method; the working procedures of material drying, heat kneading, high temperature carbonization are saved, not only the production control becomes easy, but also the production process is more energy-saving; the tunnel type oxidation (or carbonization) stove realizes a continuous operation, has a large yield, and improves the productivity.
Owner:陈善堂

Method for preparing blast furnace blowing semicoke from low-rank coal based on high-pressure hydrothermal reaction

The invention relates to a treatment method for dehydrating and upgrading high-moisture and high-volatile low-rank coal, and discloses a method for preparing blast furnace blowing semicoke by upgrading low-rank coal based on a high-pressure hydrothermal reaction, wherein the method comprises four steps of low-rank coal pretreatment, high-pressure hydrothermal upgrading, waste heat recycling and upgraded semicoke dehydration and drying. According to the method, low-heat-value low-rank coal is converted into high-quality blast furnace blowing upgrading semicoke by utilizing a high-pressure hydrothermal reaction upgrading technology, wherein the moisture content of the semicoke air drying base is less than 6%, the volatile component content is less than 25%, the Hardgrove grind ability indexis greater than 60, the high-order heat generation value is greater than 24000 kJ/kg, soluble potassium salt, sodium salt and sulfate components in ash are dissolved out, the organic sulfur in coal iseffectively separated out, and the upgraded semicoke can meet the performance index requirements of coal for blast furnace blowing; and the method provided by the invention effectively solves the problems of high water content, high volatile component content, low heat value and high harmful element content of blast furnace blowing of low-rank coal, and provides a clean, efficient, low-energy-consumption and high-added-value low-rank coal upgrading utilization method.
Owner:UNIV OF SCI & TECH BEIJING

Method for preparing activated carbon through sludge fermentation residues

The invention relates to a method for preparing activated carbon through sludge fermentation residues. The method comprises the following steps of 1, mixed strong base pretreatment on sludge, whereinthe remaining sludge is taken, the moisture content of the sludge is adjusted to be 95-98%, a mixed solution of potassium hydroxide and sodium hydroxide is added, and the sludge is subjected to mixedstrong base pretreatment after being heated to 90-95 DEG C; 2, sludge and water separation for a fermentation mixture, wherein the remaining sludge after strong base pretreatment in step 1 is subjected to anaerobic fermentation, and when fermentation is finished, agricultural and forest waste is put in the fermentation mixture to serve as a filter aid; 3, preparation of the activated carbon through the fermentation residues, wherein the fermentation residues after sludge and water separation in step 2 are slowly dried under a low-temperature condition, the dried residues are sent into a carbonizing furnace for high-temperature carbonizing, the carbonized residues are sent to an activator for pelleting activation, the activated residues are sent to an oven for drying, and after drying is finished, the sludge-based activated carbon is obtained. By means of the method, the situation that the agricultural and forest waste is left unused and wasted is reduced, and the problem that it is hard to dispose anaerobic fermentation sludge is solved.
Owner:南京河海环境研究院有限公司
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