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156results about How to "Improve surface stability" patented technology

Modified high nickel ternary positive electrode material and its preparation method and lithium ion battery

The invention discloses a modified high nickel ternary positive electrode material. The surface of a high nickel ternary positive electrode material is coated with a coating layer containing a fast ion conductor. The fast ion conductor has the chemical general formula of Li3x1La2/3-x1Ma1TiNz1O3, Li2+2x2Zn1-x2GeO4 or LiM'2(PO4)3, wherein M represents Ba<2+> and/or Sr<2+>, N represents Al<3+> and/orZr<4+>, x1 is greater than or equal to 0.04 and less than or equal to 0.167, a1 is greater than or equal to 0 and less than or equal to 1, z1 is greater than or equal to 0 and less than or equal to 1, x2 is greater than -0.3 and less than 0.8, and M' represents one or more of Zr, Ti, Ge and Hf. Compared with the existing positive electrode material, the modified high nickel ternary positive electrode material is provided with the coating layer containing the fast ion conductor and the coating layer can react with residual lithium on the surface of the material to reduce residual lithium on the surface of the material and inhibit side reactions of the residual lithium and the electrolyte so that material surface stability and cycle performances are improved. The modified high nickel ternary positive electrode material has good lithium ion deintercalation ability, improves the first discharge capacity of the material and first coulombic efficiency and has a good application prospect. The invention also discloses a preparation method of the modified high nickel ternary positive electrode material and a lithium ion battery.
Owner:CONTEMPORARY AMPEREX TECH CO

Synthetic method of nitrogen-enriched carbon coated lithium titanate composite material prepared by introduction of ionic liquid as carbon source

The invention discloses a synthetic method of a nitrogen-enriched carbon coated lithium titanate composite material prepared by the introduction of an ionic liquid as a carbon source. The synthetic method comprises the following steps of: 1) weighing lithium salt, titanium dioxide and the carbon source in proportion, adding alcohol, carrying out ball milling dispersion, and carrying out vacuum drying to prepare a precursor; 2) sintering the prepared precursor at the temperature of 750-950 DEG C under the protection of an inert atmosphere so as to preliminarily obtain lithium titanate with a carbon material coated on the surface; and 3) adding the ionic liquid and deionized water in proportion into the preliminarily obtained carbon-coated lithium titanate, carrying out ball milling, stirring and sintering. The lithium titanate composite material has a spherical morphology of nano-primary particle composed micrometer secondary particles, and the surface of the lithium titanate composite material is uniformly coated with a layer of nitrogen-enriched carbon material. Its electronic conductivity is not only effectively raised, but surface stability of the material is also enhanced. The obtained material has excellent rate capability and cycle performance. In addition, gas expansion problem of lithium titanate cells is effectively improved. The nitrogen-enriched carbon coated lithium titanate composite material has a wide application prospect in the field of lithium ion battery.
Owner:HEFEI GUOXUAN HIGH TECH POWER ENERGY

Method for enabling PTFE (Polytetrafluoroethylene) or FEP (Fluorinated Ethylene Propylene) surface to have super-hydrophobic and underwater high reflective properties simultaneously

A method for enabling a PTFE (Polytetrafluoroethylene) or FEP (Fluorinated Ethylene Propylene) surface to have super-hydrophobic and underwater high reflective properties simultaneously belongs to the laser machining field. According to the method, a 1064 nm picosecond laser micro-machining system is utilized to machine a one-dimensional or a dimensional trench array with a 25 mum seam width in PTFE and FEP surfaces so as to enable the surfaces to have super-hydrophobicity; if a prepared super-hydrophobic sample is completely immersed in water, a super-hydrophobic surface may take on a metallic luster high reflective surface. The method comprises the operating steps of: adjusting a picosecond laser light path, drawing a machining path by utilizing professional software, adjusting a picosecond laser output power based on a machining requirement, outputting picosecond pulse laser for machining when the laser power meets the requirement, achieving a super-hydrophobic requirement without subsequent cleaning after the machining is finished, and immersing the finished product in water to make a metal-like high reflective surface appear directly.
Owner:BEIJING UNIV OF TECH

Lithium ion battery cathode material with variable slope concentration gradient doping structure and preparation thereof

InactiveCN108649205AThe rate of change of concentration increasesGood element doping distributionElectrode thermal treatmentSecondary cellsSurface layerSynthesis methods
The invention discloses a lithium ion battery cathode material with a variable slope concentration gradient doping structure and a synthesis method thereof. For solving the problems of capacity fadingand rate performance degradation which are brought by the conventional doping method, an element with a variable slope concentration gradient structure is doped, thereby obtaining the lithium ion battery cathode material with the concentration of a doping element continuously changed from the center of a material particle to the surface of the material particle; and change rate is gradually increased from inside to outside, so that the concentration of the doped element inside the material is slowly changed, the concentration of the doped element on the surface of the material is rapidly changed, and change of the concentration of the doped element is mainly concentrated on a surface layer. The method improves stability of the internal structure and the surface of the material while sideeffect is not introduced, the problems such as phase change of the material, volume change and dissolution of transition metal elements in a charge-discharge cycle process are reduced, cycle life of the material is greatly prolonged, and safety performance of the material is greatly improved.
Owner:HARBIN INST OF TECH

High strength and completely antioxidative third generation monocrystalline high temperature alloy and preparation method thereof

The invention relates to the field of high strength monocrystalline high temperature alloy and especially provides a high strength and completely antioxidative third generation monocrystalline high temperature alloy with low cost, and is mainly suitable for blade material of an aircraft engine used at a temperature higher than 1100 DEG C. The alloy comprises chemical components (wt%) of 3-5% of Cr, 5-12% of Co, 6-8% of W, 0.1-2% of Mo, 4.5-5.5% of Re, 5.5-7% of Al, 6-10% of Ta and the balance of Ni. The preparation method is as below: a monocrystalline blade or a testing rod is prepared at a monocrystalline growth furnace temperature gradient of 40K/cm-80K/cm, a cast temperature of 1480-1550 DEG C, with a shuttering temperature and a cast temperature kept at the same and a growth rate of 4-8mm/min; then, the alloy is treated with solid solution homogenizing treatment, high temperature aging treatment and low temperature aging treatment to gain high lasting intensity and creep limit. The alloy has a life no less than 200 h under a lasting condition of 1100 DEG C / 140 MPa and a lasting intensity similar to CMSX-10 and good high temperature antioxidative property, which is good surface stability Besides, a heat treatment window is wide, and the solid solution treatment is easy to control.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

HDI board fabrication method and HDI board

The invention discloses an HDI board fabrication method and an HDI board. The HDI board fabrication method comprises the steps of processing a core board by a core board processing step, performing browning, prepreg pasting and protection film on the processed core board, drilling a position corresponding to a micropore of the core board, filling the hole with conductive paste to obtain an interconnection unit, and finally, laminating a plurality of interconnection units in one time to achieve interconnection of an arbitrary layer so as to obtain the HDI board. Through hole filling by the conductive paste, the hole filling efficiency is high; moreover, the core board coated with the conductive paste and a prepreg is used as the interconnection unit, the plurality of interconnection units are laminated in one time to fabricate the HDI board, the board is not needed to fabricated by lamination layer by layer, the fabrication efficiency of the HDI board is effectively improved, and the technical problem that the a conventional lamination method for fabricating HDI board in the prior art is extremely long in process flow to cause extremely low fabrication efficiency of the HDI board issolved.
Owner:深圳明阳电路科技股份有限公司

High endurance strength and excellent oxidation resistance third generation single crystal high-temperature alloy and preparation thereof

The invention provides a low cost, high strength and fully oxidation resistance third generation single crystal high-temperature alloy. The high-temperature alloy is mainly suitable for aircraft engine blade materials used at the temperature of 1100 DEG C or above. The alloy is prepared from the chemical components in percentage by weight: 3-5% of Cr, 5-12% of Co, 6-8% of W, 0.1-2% of Mo, 4.5-5.5%of Re, 5.5-6.5% of Al, 6-10% of Ta, 0-0.6% of Nb, 0-0.2% of Hf, 0-0.05% of Y, 0-0.04% of C, and the balance of Ni. A preparation method comprises the steps that single crystal blades or test rods areprepared within a temperature gradient range of a single crystal growth furnace being 40 K/cm-80 K/cm, at a casting temperature of 1500-1550 DEG C, under the condition that a mould shell temperatureis consistent with the casting temperature, and within the growth rate range of 4-8 mm/min. Then after solid solution homogenization treatment, high temperature aging treatment, and low temperature aging treatment, the alloy has high endurance strength and creep limit. The service life is greater than or equal to 200 h at the endurance condition of 1100 DEG C/140 MPa, and the endurance strength ofthe alloy is comparable to that of CMSX-10; and the performance of high temperature oxidation resistance is good, specifically, surface stability is good. A heat treatment window is wide, and solid solution treatment is easy to control.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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