The invention discloses a two-dimensional lead-free perovskite material and a design method. The structural formula of the two-dimensional lead-free perovskite material is expressed as: AxByXz, wherein x = 1, 2, 3; y = 1, 2 ; Z = 4, 7, 8, 9; A is one element of Cs, Ba, Sr, and Ca; B is one element of Sb, Bi, Ga, In, Au, Sn, Hf, Zr, amd Ti; X is one element of F, Cl, Bre, I, S, Se, and Te. A firstprinciple method that is widely used, accurate in computation, and low in cost is used to systematically compute the excellent properties of such structure, and two types of perovskite materials, including transcending solar photovoltaic star material MAPbI3 and a graphene-like semiconductor with graphene linear electronic dispersion and an intrinsic quasi-particle bandgap of about 0.1 to 1 eV, are found out.