The invention belongs to the technical field of
chloroprene rubber preparation, and provides a preparation method of a
sulfur-modified
chloroprene rubber with a high latex
Mooney viscosity stability in order to solve the problems that the final chain-broken products of conventional
sulfur-modified
chloroprene rubber are not stable, the
Mooney viscosity of latex changes after being stored for a while, the storage stability of
raw rubber is bad, the rubber will become hard and the rubber
plasticity is reduced after long-term storage, the
processing performance turns worse, and the performance of sulfurized rubber degrades. The preparation method comprises the following steps: dissolving
sulfur, tetrabutyl
thiuram disulfide, and 2-
mercaptobenzothiazole into chloroprene monomers to prepare an
oil phase; mixing the
oil phase with a prepared water phase to carry out emulsification, adding an initiator to carry out reactions; stopping the reactions when the
specific weight of the
system reaches 1.075 to 1.077, allowing the
system to stand still for a while, then adjusting the pH value, cooling on the drum to carry out gelation, and cleaning and
drying the gel so as to obtain the target product. The
polymerization can be easily controlled, the formula and the technology are simple and convenient, the chain breaking technology is omitted, the molecular weight can be adjusted to a proper value in a short time, the
Mooney viscosity of the obtain latex is stable; and the problems that the latex
viscosity is hard to control and the storage stability of the latex is bad are solved.