451 results about "Dimethacrylate ester" patented technology

A self-lubricating coating is provided which includes a mixture of a curable acrylate composition including a dipentaerythritol pentaacylate and a solid lubricant, such as polytetraflourethylenr. The curable acrylate composition may also include triethylene glycol dimethacrylate. An aramid pulp may also be added to the coating mixture. Also disclosed is a method of manufacturing the coating, and a self-lubricating bearing having the coating disposed on its surface.

The present invention provides materials that have high glucose and oxygen permeability, strength, water content, and resistance to protein adsorption. The materials include an interpenetrating polymer network (IPN) hydrogel that is coated with biomolecules. The IPN hydrogels include two interpenetrating polymer networks. The first polymer network is based on a hydrophilic telechelic macromonomer. The second polymer network is based on a hydrophilic monomer. The hydrophilic monomer is polymerized and cross-linked to form the second polymer network in the presence of the first polymer network. In a preferred embodiment, the hydrophilic telechelic macromonomer is PEG-diacrylate or PEG-dimethacrylate and the hydrophilic monomer is an acrylic-based monomer. Any biomolecules may be linked to the IPN hydrogels, but are preferably biomolecules that support the growth of cornea-derived cells. The material is designed to serve as a corneal prosthesis.

In one embodiment of the invention, iCVD is used to form linear thin films using a radical initiator and an alkene. In another embodiment, iCVD is used to form crosslinked thin films by the addition of a crosslinking agent (e.g., a diacrylate or a dimethyacrylate). The incorporation of a crosslinking agent into the thin films is shown to increase systematically with its partial pressure. In one embodiment, when the crosslinker is EDGA and the monomer is HEMA it results in crosslinked P(HEMA-co-EGDA) copolymer. In another embodiment, when the crosslinker is EDGA and the monomer is VP, it results in crosslinked P(VP-co-EGDA). Disclosed are the effects of crosslinker incorporation on the thermal and the wetting properties of the polymers. The unique swelling properties of these films are also described; certain films of the present invention are hydrogels when soaked in water.

Provided is a nanofiber sheet that sufficiently refined by fibrillation and has high crystallinity of cellulose fiber and can realize a fiber-reinforced composite material exhibiting high transparency, a high elastic modulus, a low coefficient of linear thermal expansion, and high heat resistance and being high in flatness and smoothness. This nanofiber sheet includes crystalline cellulose as the main component and a lignin in an amount of from 10 ppm to 10 wt %. When a fiber/resin composite material obtained by impregnating the nanofiber sheet with tricyclodecane dimethacrylate, subjecting the impregnated product to UV-curing at 20 J/cm², and heating the cured product in vacuum at 160° C. for two hours includes 60 wt % of the cured tricyclodecane dimethacrylate and 40 wt % of nanofiber, the following physical characteristics (i) to (iii) are satisfied: (i) the parallel light transmittance of light of a wavelength of 600 nm at a sheet thickness of 100 μm is 70% or more; (ii) the Young's modulus is 5.0 GPa or more; and (iii) the coefficient of linear thermal expansion is 20 ppm/K or less.

The present invention provides interpenetrating polymer network hydrogels that have high oxygen permeability, strength, water content, and resistance to protein adsorption. The hydrogels include two interpenetrating polymer networks. The first polymer network is based on a hydrophilic telechelic macromonomer. The second polymer network is based on a hydrophilic monomer. The hydrophilic monomer is polymerized and cross-linked to form the second polymer network in the presence of the first polymer network. The telechelic macromonomer preferably has a molecular weight of between about 575 Da and about 20,000 Da. Mixtures of molecular weights may also be used. In a preferred embodiment, the hydrophilic telechelic macromonomer is PEG-diacrylate or PEG-dimethacrylate and the hydrophilic monomer is an acrylic-based monomer. The material is designed to serve as a contact lens.

The invention discloses a temperature-sensitive magnetic sulfadimidine molecular imprinted adsorbent as well as a preparation method and application thereof, belonging to the technical field of preparation of environment functional materials. A gamma-Fe2O3/SiO2 magnetic composite material is prepared by using a sol-gel method and is subjected to vinyl modification by using 3-(methylacryloyloxy) trimethoxypropylsilane; with a vinyl-modified magnetic composite material (MPS (Modified Polystyrene)-gamma-Fe2O3/SiO2) as a substrate material, sulfadimidine as a template molecule, acrylamide as a functional monomer, N-isopropylacrylamide as a temperature-sensitive monomer, ethylene glycol-bis(methylacrylic acid) ester as a cross-linking agent and 2,2'-azobisisobutyronitrile as an initiator, a temperature-sensitive magnetic molecular imprinted polymer is prepared by using a free group polymerization process and is applied to selective recognition and separation of the sulfadimidine in an aqueous solution; and the obtained polymer has the advantages of remarkable heat and magnet stability, sensitive magnet and heat inducting effect, higher adsorption capacity, reversible adsorption/release function along with the temperature and remarkable recognition performance of a sulfadimidine molecule.

The invention disclosed is a hydrogel composition for use as dural substitute, for wound closure of cleft palate and regeneration, and as substrate for cell delivery to the eye. The hydrogel is made of a copolymer of (a) an N-substituted (meth)acrylamide, and (b) a hydroxyalkyl (meth)acrylate, which is covalently crosslinked with dimethacrylate monomers. The swollen, gel is in the form of a sheet or membrane that is readily sterilisable, being homogeneous or heterogeneous, non-degradable, non resorbable, elastically deformable, and has an equilibrium water content of at least 50%.

The invention discloses an anisotropic conductive film composition comprising a binding agent containing at least one of polyester type polyurethane resin, polyurethane acrylate resin, and carbamic acid ester resin; ethylene-acetic acid vinyl ester copolymer; materials capable of free radical polymerization containing tricyclodecane dimethanol diacrylate or tricyclodecane dimethanol dimethyl methacrylate; and organic particles. To be specific, the invention relates to a resin composition used for connection of the circuit and a film, which is provided with an extension rate in a range from 10 to 100% after the solidification and has no obvious retraction and expansion in the connection structure. The reliability of the electric connection under the high temperature and high humidity condition can be reduced. The invention also provides a semiconductor device containing the above mentioned anisotropic conductive film.

The invention concerns a photocurable adhesive composition comprising, based on total weight of photopolymerizable monomers and/or oligomers of the composition: (A1) 20 to 80 wt % of at least one diacrylate monomer or oligomer thereof (A1); (A2) 80 to 20 wt % of at least one dimethacrylate monomer or oligomer thereof; (B) 0 to 50 wt %, of at least one copolymerizable monomer different from components (A1) and (A2);

with the proviso that the composition is free from any thio(meth)acrylate (—SCOCR′=CH₂, with R′=H or CH₃) monomer or oligomer thereof.

The invention discloses a cross-linked polymer gel electrolyte membrane supported by a hydrophilic polytetrafluoroethylene microporous membrane. When the cross-linked polymer gel electrolyte membrane is prepared, firstly, methoxypolythylene glycol with double bonds and methyl acrylic glycidyl ester segmented copolymer are combined, ethylene glycol dimethacrylate, a thermal initiator and organic electrolyte containing lithium salt are added, stirring is conducted to form an even polymeric precursor solution; the hydrophilic polytetrafluoroethylene microporous membrane is immersed in the polymeric precursor solution and fully absorbs the polymeric precursor solution and is taken out, and the cross-linked polymer gel electrolyte membrane is obtained after cross-linked gelatinization is conducted. According to the cross-linked polymer gel electrolyte membrane, the preparation technology is simple, the electrolyte membrane is suitable for industrial production, a prepared cross-linked polymer gel electrolyte membrane system not only has a good mechanical property, but also has a good electrochemical property, an ionic conductivity at room temperature reaches up to 1.30*10-3 S cm-1, and an electrochemical stability window value can reach 4.5V. Lithium iron phosphate/lithium metal batteries assembled by the cross-linked polymer gel electrolyte membrane have good cycle performance under 25 DEG C and 70 DGE C.

The present invention provides polymerizable dental compositions comprising a dimer acid-derived monomer such as a dimer acid-derived di(meth)acrylate monomer. In one embodiment, the dimer acid-derived monomer is of the formula (I): wherein R₁, R₂, R₃, R₄, R₅ and R₆ are independently selected from H and optionally substituted C₁-C₂₅ straight-chained or branched aliphatic, optionally containing 1 or more double or triple bonds, wherein one or more carbons are optionally replaced by R* wherein R* is —C(O)—, —C(O)C(O)—, —C(O)NR⁷—, —C(O)NR⁷NR⁸—, —C(O)O—, —OC(O)—, —NR⁷CO₂—, —O—, —NR⁷C(O)NR⁸—, —OC(O)NR⁷—, —NR⁷NR⁸—, —NR⁷C(O)—, —NR⁷C(O)O—, —S—, —SO—, —SO₂—, —NR⁷—, —SO₂NR⁷— or —NR⁷SO₂—, where R⁷ and R⁸ are independently selected from H and optionally substituted aliphatic, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; provided that at least two of R₁, R₂, R₃, R₄, R₅ and R₆ are substituted C_1-25 straight-chained or branched aliphatic wherein at least one carbon is replaced by R* and at least one of the substituents is an alkenyl group.

To provide a photopolymerizable inkjet ink, which contains photopolymerizable monomers containing at least one selected from the following compound group (A) compounds of which are negative for skin sensitization, and at least one selected from the following compound group (B) compounds of which are negative for skin sensitization, wherein the compound group (A) is a compound group consisting of caprolactone-modified dipentaerythritol hexaacrylate, polyethoxylated tetramethylol methane tetraacrylate, ethylene oxide-modified bisphenol A diacrylate, caprolactone-modified hydroxy pivalic acid neopentyl glycol diacrylate, polypropylene glycol diacrylate [CH₂═CH—CO—(OC₃H₆)n-OCOCH═CH₂ (n≈12)], hydroxyethyl acryl amide, trimethylol propane trimethacrylate, and tricyclodecane dimethanol dimethacrylate, and the compound group (B) is a compound group consisting of ethylene oxide-modified phenolacrylate, isostearyl acrylate, ethylene oxide-modified trimethylol propane trimethacrylate, stearyl methacrylate, and glycerin dimethacrylate.

A radically curable polyurethane composite for dental restorations, including provisional restorations, includes polyurethane dimethacrylate prepolymers that have at least one flexible unit within a polyurethane dimethacrylate backbone, and one or more dimethacrylate monomers. Composite materials made with polyurethane dimethacrylate prepolymers of the invention exhibit superior and optimal properties of flexural strength and deflection-at-break relative to conventional dental resin composites. Composite materials of the invention also provide improved melt-resistance in response to the heat of grinding or finishing, thereby improving the fit of restorations made from the composite and preserving the finishing instruments. Methods of treating a tooth using the radically curable polyurethane composite and methods of making the polyurethane dimethacrylate prepolymers with flexible units is also provided. A kit including the radically curable polyurethane composite is also described.

A transparent laminate including a transparent substrate and structure layer, wherein the structure layer contains protrusion portions, depression portions, or both on a surface thereof, and an average distance between the adjacent protrusion portions or between the adjacent depression portions is equal to or less than a visible light wavelength, the structure layer includes a polymerized product of an active energy ray curable resin composition, the resin composition includes a composition of a (meth)acryloyl group-containing polymerizable compound, the compound composition includes one or more from each of (A), (B), and (C):

• • (A) a monofunctional (meth)acryloyl group-containing polymerizable compound;
  • (B) alkylene glycol di(meth)acrylate; and
  • (C) trifunctional or higher (meth)acrylate,

the (A) satisfies certain conditions specifying a type and amount of a compound, and a ratio (E′₁₅₀/E′₅₀) of storage elastic modulus E′₁₅₀ of the structure layer at 150° C. to storage elastic modulus E′₅₀ thereof at 50° C. is 0.5 or less.

The invention discloses a method for determining vanillin by virtue of photonic-crystal molecular imprinting hydrogel. The method comprises the steps of firstly, preparing a silicon dioxide photonic crystal on a common glass sheet, and dissolving vanillin, methylpropenoic acid, ethylene glycol dimethacrylate and azodiisobutyronitrile in methyl alcohol to form a molecular imprinting precursor; permeating the precursor between organic glass and the photonic crystal, and performing ultraviolet polymerization; removing silicon dioxide by hydrofluoric acid, and soaking with methyl alcohol to remove vanillin; and forming the photonic-crystal molecular imprinting hydrogel on the organic glass. The photonic-crystal molecular imprinting hydrogel disclosed by the invention has the advantages of high response speed, high selectivity, high sensitivity, high anti-interference capacity and the like when being used for determining trace vanillin. The preparation method is simple, is low in cost and good in reproducibility, can be used for detecting vanillin in foods, and provides a technical support for detecting a food additive.

The invention provides a preparing method of Tetracycline molecular imprinting column. The invention includes the following steps: dissolving template molecular Tetracycline (TC) with ultrasound in methanol, adding functional monomer and pore-forming agent (cyclohexanol and lauryl alcohol), oscillating for 6 hours, adding crosslinking agent (ethylene glycol dimethacrylate) and initiator (azobisisobutyronitrile), after ultrasonic degassing, adding nitrogen for 20 minutes, deoxidizing, pouring the solution into 10cm stainless column with bottom sealed, sealing the top end, putting the column into 60 DEG C water for water bath, after 12 hours, obtaining the molecular imprinting column by heat initiation reaction. Connecting the column to the high-pressure pump for washing away the pore-forming agent and template molecular, in the end the molecular imprinting column with good separation effect is obtained. Compared with traditional bulk polymerization method, the invention has the characteristics of simple preparation for avoiding process of lapping, good molecular recognition ability and so on. The molecular imprinting column provided by the invention is used as a liquid chromatogram filling, and can realize separation, enrichment and purification of Tetracycline antibiotics.

A process for the production of polyurethane di(meth)acrylates in which 1,6-hexane diisocyanate is reacted, without solvent and without subsequent purification operations, with a diol component and hydroxy-C2-C4-alkyl (meth)acrylate in the molar ratio x:(x−1):2, wherein x means any desired value from 2 to 5 and the diol component is a combination of two to four (cyclo)aliphatic diols with molar masses of 62 to 600 and wherein each of the diols constitutes at least 10 mol % of the diols of the diol component and powder coating compositions having the polyurethane di(meth)acrylates as a binder.

A UV-curable ink-jet ink is provided, which has a high sensitivity and allows soft and highly fine patterns to be formed. The UV-curable ink-jet ink includes a mono-functional polymerizable monomer (A) having a hydroxyl group, a di(meth)acrylate ester (B) and a photo-polymerization initiator (C).

The invention relates to a bisphenol A dummy template molecularly imprinted stir bar and a preparation method thereof. The stir bar is a glass bar containing an iron core, wherein the glass bar is coated by a polymer coating; the polymer coating is a bisphenol A dummy template molecularly imprinted polymer; modified silica microspheres with grain size being 400nm are taken as the carriers for synthesizing the imprinted polymer; and biphenyl diphenol is taken as a dummy template molecule. The bisphenol A dummy template molecularly imprinted polymer is prepared by carrying out surface grafting on the surfaces of silica microspheres with grain size being 400nm with vinyltrimethoxysilane to obtain the modified silica microspheres, then subjecting the modified silica microspheres to react withbiphenyl diphenol, 4-vinyl pyridine, ethylene glycol dimethacrylate and azodiisobutyronitrile and using a methanol-glacial acetic acid mixed solution to wash off the template molecule. The stir bar and the preparation method have the following beneficial effect that: SiO2 is taken as the carrier for synthesizing the imprinted polymer, thus greatly adding the number of the effective binding sites and improving the sensitivity.

A macromonomer of the present invention comprises at least functional group and a plurality of hydrophilic moieties. Such a functional group can be an ethylenically unsaturated group that comprises acrylate, methacrylate, sinapate (or 3,5-dimethoxy-4-hydroxycinnamate), cinnamate (or 3-phenylacrylate), senecioate (or 3,3-dimethylacrylate), crotonate, maleate, fumarate, itaconate, vinyl, allyl, or styryl group. Polymeric materials comprise such a macromonomer are used advantageously to provide a hydrophilic or lubricious (or both) coating on polymeric articles, such as medical devices. Such polymeric materials can comprise units of other hydrophilic monomers.

An ultraviolet-curing resin composition of (a) 5 to 35 parts by mass of a chlorinated polyolefin with a chlorine content of 15 to 40 mass %, (b) 15 to 60 parts by mass of an alicyclic hydrocarbon mono(meth)acrylate, and (c) 5 to 80 parts by mass of a polypropylene glycol di(meth)acrylate; and, per 100 parts by mass of the total amount of components (a), (b) and (c), (d) 0 to 1100 parts by mass of an aliphatic hydrocarbon di(meth)acrylate and (e) 0 to 600 parts by mass of a polyfunctional monomer having 3 to 6 (meth)acryloyl groups in its molecule; and, per 100 parts by mass of the total amount of components (b), (c), (d) and (e), (f) 1 to 15 parts by mass of a photoinitiator; and the composition as an active ingredient in paints, inks, adhesives, sealing agents and primers.

The invention relates to a method for preparing a molecularly imprinted polymer for fluorescence detection of cyhalothrin. By adopting the method, a spherical fluorescent molecularly imprinted polymer (F-MIP) of taking pyrethroid cyhalothrin as a template molecule, acrylamide (AM) as a functional monomer, allyl fluorescein as fluorochrome, ethylene glycol bi(methacrylic acid) ester (EGDMA) as a crosslinking agent and 2,2'-azobisisobutyronitrile (AIBN) as an initiator is synthesized by adopting a precipitation polymerization method. The prepared fluorescent imprinted polymer has high sensitivity and low detection limit, has strong selective recognition ability on cyhalothrin, and can be applied to quantitative detection analysis of ultratrace cyhalothrin.

The invention provides a dibutyl phthalate molecularly imprinted polymer (DBP-MIP) and a preparation method thereof, belonging to the technical field of analytical chemistry. The DBP-MIP is prepared by dissolving a template molecule DBP, a functional monomer methacrylic acid and a crosslinking agent ethylene glycol dimethacrylate into a porogen chloroform or acetonitrile, adding an initiator azobisisobutyronitrile, filling nitrogen to remove oxygen, carrying out initiated polymerization at 55-75 DEG C, and grinding, sieving and washing a polymer after completing reaction. An MIP solid phase extraction column can highly selectively separate and enrich DBP in samples such as environment, food, chemical products and the like and effectively remove matrix interference.