The invention discloses a novel method for producing a fluorine-free chromium-based composite ceramic material coating. The coating comprises components of: 150-350g / l of chromic anhydride, 1.5-3.5g / l of sulfuric acid, 3-8ml / l of an FHD additive, and 2-10g / l of trivalent chromium. The production method comprises steps that: a chromium layer is pre-deposited for 10-40min on the surface of a workpiece; an electrode is switched, such that the mesh of the chromium layer is deepened and thickened; ceramic powder is filled in the mesh slits; the electrode is switched again, chromium is electrically deposited on the surface of the workpiece, such that the mesh is sealed, and the ceramic powder is fixed, until the thickness of the coating satisfies the technological requirements of products. Finally, a chromium-based composite ceramic coating with a ceramic powder content of 1-6Wt%, and properties such as excellent oil retention property, excellent lubricity, excellent wear resistance, excellent corrosion resistance, excellent oxidation resistance, and excellent thermal shock resistance can be obtained. The composite ceramic coating can be widely applied in industries such as automobiles, national defense, aeronautics, astronautics, vehicles, ships, engineering machineries, steel, and the like.