The invention provides a preparation method of a water-based chlorinated polyvinyl chloride anti-corrosive paint. The water-based chlorinated polyvinyl chloride anti-corrosive paint is prepared from the following raw materials: water-based epoxy resin, chlorinated polyvinyl chloride, dispersant, stabilizer, bactericide, defoaming agent, carbon black, zinc phosphate, barium sulfate, corrosion inhibitor, leveling agent, drying agent and thickening agent. The preparation method comprises the following steps: evenly stirring related raw materials according to the formula, and grinding with a sand mill until the fineness is 30-60 mu m; and while stirring, adding the residual chlorinated polyvinyl chloride, stabilizer, binder, bactericide, leveling agent, drying agent and thickening agent, homogenizing, and filtering.