A refining and mixing system adopted in a wet-process phosphoric acid refining process by a solvent extraction method is used for liquid-liquid mixing or liquid-powder mixing and comprises an A type mixing device, a transfer station and a B type mixing device which communicate with each other successively, wherein the A type mixing device has functions including that an external containing body can rotate, a heating body can be arranged and a rotating airflow can be generated, and a stirrer has three functions of body stirring, airflow stirring and enhanced stirring; the B type mixing device has functions including that an external containing body can generate a rotating airflow, a heating body can be arranged and a module can be replaced, and a stirrer has four functions of body stirring, airflow stirring, enhanced stirring, and midway addition of raw materials. The system can eliminate a fluid stagnation zone, can heat a mixed object, has the advantages of good mixing performance and high uniformity, can achieve rotation of an external container, strong lubrication effect, various stirring functions and midway addition, and has a wide range of application.