The invention discloses a hydrogenation catalyst modified by a solid-phase modifier and its application. The hydrogenation catalyst is a mixture of a supported palladium catalyst and a solid-phase modifier, or is supported by a solid-phase modifier. metal palladium material; when the hydrogenation catalyst is a mixture of a supported palladium catalyst and a solid phase modifier, the mass ratio of the solid phase modifier to the loaded palladium catalyst is 0.1 to 500:1; when the hydrogenation catalyst is a mixture of When the solid-phase modifier is a metal palladium material loaded on a carrier, the loading amount of metal palladium is 0.1-20wt%; the solid-phase modifier is polyphenylene sulfide or metal sulfide, and the metal sulfide is silver sulfide, barium sulfide, At least one of cadmium sulfide, cerium sulfide, ferrous sulfide, ferrous disulfide, lithium sulfide, sodium sulfide, nickel sulfide, manganese sulfide, molybdenum sulfide, selenium sulfide, tungsten sulfide, zinc sulfide, copper sulfide, titanium sulfide. The hydrogenation catalyst of the present invention has high catalytic activity in the selective hydrogenation reaction of alkynes, and can effectively improve the catalytic selectivity of target olefin products.