630 results about "Yttrium(III) oxide" patented technology

The invention relates to the technical field of surface engineering, discloses a method and a system for preparing a yttrium fluoride composite ceramic coating through atmospheric plasma spraying, and aims to solve the problems that the yttrium fluoride coating generates a brittle aluminum fluoride layer on the surface of an aluminum substrate due to fluorine ion diffusion, so that the bonding strength is low, and the yttrium fluoride coating is easy to peel off and lose efficacy. The method comprises the following steps: sequentially carrying out mechanical polishing, ultrasonic cleaning and sand blasting roughening on an aluminum base material; preparing composite powder formed by mixing yttrium fluoride, yttrium oxide and nanometer aluminum oxide according to the mass ratio of 75: 20: 5; sequentially depositing a yttrium oxide transition layer, a composite barrier layer and a yttrium fluoride functional layer by adopting atmospheric plasma spraying; and finally carrying out vacuum post-heat treatment. According to the system, through the synergistic effect of the three layers of gradient structures, the transition layer forms an yttrium aluminate metallurgical bonding interface, the barrier layer inhibits fluorine ion diffusion through the dual mechanisms of nanometer aluminum oxide physical barrier and yttrium oxide chemical adsorption, and the functional layer guarantees the plasma erosion resistance. According to the method, the bonding strength of the coating is remarkably improved to 50 MPa or above, the porosity is lower than 3%, stripping is avoided under 500-hour high-energy plasma bombardment, the process cost is reduced by 40%, and the method is suitable for cavity protection of semiconductor etching equipment.

The invention discloses a preparation method of a toughening environmental barrier coating, and relates to a preparation method of a coating. The invention aims to solve the problem of poor fracture toughness of the existing environmental barrier coating. The method comprises the following steps: 1, pretreating a base material; 2, preparing a bonding layer; and 3, preparing the environmental barrier layer. The high-melting-point metal silicide prepared on the surface of the base material or the bonding layer compounded by the high-melting-point metal silicide and the rare earth silicate has excellent temperature resistance and good interface bonding strength, and due to the addition of the rare earth silicate, the expansion coefficient of the bonding layer is highly matched with that of the base material; according to the prepared yttrium oxide stabilized zirconia fiber, mullite fiber or silicon carbide fiber reinforced rare earth silicate environmental barrier layer, the fracture toughness of pure Yb2SiO5 is improved to 6.5 MPa.m < 1 / 2 >-8.0 MPa.m < 1 / 2 > from about 1.85 MPa.m < 1 / 2 >. The strengthening and toughening environmental barrier coating prepared by the invention has very important significance on development of thermal protection coatings of hot end parts of aircrafts with high thrust-weight ratios in China.

The invention discloses a silicon nitride ceramic-based composite material and a preparation method thereof, and relates to the technical field of silicon nitride ceramics. The silicon nitride ceramic-based composite material is prepared from silicon dioxide coated modified boron nitride and resin composite phase change microcapsules, Si3N4-C coated Al2O3 core-shell fiber aerogel, nano yttrium oxide and polyvinyl butyral, the silicon dioxide coated modified boron nitride and resin composite phase change microcapsules are stably attached to the surface of the Si3N4-C coated Al2O3 core-shell fiber aerogel in a chemical bonding and mechanical interlocking mode, the interface bonding strength is enhanced, the risk of phase separation is reduced, the combination effect of the silicon dioxide coated modified boron nitride and resin composite phase change microcapsules and the Si3N4-C coated Al2O3 core-shell fiber aerogel is better exerted, and the composite phase change effect of the silicon dioxide coated modified boron nitride and resin composite phase change microcapsules is improved. According to the present invention, the fracture toughness can be improved through fiber toughening, aerogel pore and microcapsule stress dispersion, the high temperature resistance can be improved through the low thermal conductivity of the aerogel and the heat absorption effect of the microcapsule, the mechanical property of the silicon nitride can be significantly improved through multiple ways and multiple modes, and the high temperature resistance can be effectively enhanced.

The invention relates to a preparation method of an etching-resistant and wear-resistant Y2O3-AlxOy composite coating. The preparation method comprises the following steps: carrying out ultrasonic cleaning on a corrosion-resistant matrix; performing plasma bombardment cleaning activation on the surface of the corrosion-resistant matrix; a Y2O3 coating and an AlxOy coating are alternately deposited on a corrosion-resistant base body in a double-target magnetron sputtering mode to form the Y2O3-AlxOy composite coating, the sputtering power of a Y target is larger than that of an Al target, and the ratio of x to y in the AlxOy coating is larger than 1. According to the method, the amorphous AlxOy coating dominated by the metal state is introduced into the Y2O3 coating, growth of Y2O3 columnar crystals is continuously broken, crystal grains are refined, formation of intergranular easy-to-etch point locations is inhibited, and an yttrium aluminum oxide composite strengthening phase is formed at an interface, so that plasma etching resistance is improved; the thickness of a single-layer coating in the composite coating is very thin; under the action of growth stress, the structure of the coating presents a wave-shaped microstructure and a soft and hard alternate mechanical structure, and the soft and hard alternate mechanical structure is beneficial to inhibiting generation of transverse cracks, guiding friction crack level expansion, prolonging the friction life of the coating and reducing the wear rate.

The invention discloses a preparation method of low-temperature rapid densification silicon nitride ceramic based on an aluminum oxide-yttrium oxide composite sintering aid, and aims to solve the problems of high temperature, high energy consumption, difficult densification and the like in the existing Si3N4 ceramic preparation. The preparation method comprises the following steps: 1, mixing alpha-Si3N4 powder, Y2O3 powder and Al2O3 powder, and carrying out ball milling dispersion to obtain mixed powder; 2, carrying out rotary evaporation drying on the mixed powder under a vacuum condition; 3, carrying out heat preservation treatment under the conditions of 1600-1700 DEG C and 40-60 MPa through a spark plasma sintering process; and 4, demolding after cooling. Under the action of the Al2O3-Y2O3 composite sintering aid, phase transformation from alpha-Si3N4 to beta-Si3N4 is remarkably promoted, the relative density of the ceramic reaches 97%-99%, the fracture toughness of the ceramic is 5.21 MPa.m < 1 / 2 >, and the bending strength of the ceramic is 924.99 MPa.

The cBN resin superhard grinding wheel is prepared from the following raw materials in percentage by mass: 30 to 45 percent of cBN grinding material, 1 to 3 percent of nano yttrium oxide, 2 to 3 percent of nano zirconium oxide, 2 to 4 percent of coupling agent, 1 to 3 percent of silicon dioxide compound and the balance of phenolic resin. The phenolic resin matrix is jointly modified by the nano yttrium oxide, the nano zirconium oxide and the specific silicon dioxide compound, and the prepared grinding wheel has good wear resistance, hardness and temperature resistance.

The invention belongs to the technical field of zirconite porous ceramics, and discloses a method for preparing high-strength zirconite porous ceramics by a foaming injection-coagulation method, which is characterized in that zirconite powder, yttrium oxide powder and manganese oxide powder are used as raw materials, and the foaming injection-coagulation method is adopted to prepare the zirconite porous ceramics. The zirconite porous ceramic is obtained through the steps of syrup solution preparation, ceramic powder premixing, ceramic slurry preparation, injection molding gelling, sintering treatment and the like. The foaming gel casting method is adopted, so that the porosity of the zirconite porous ceramic can be effectively increased, and the heat radiation transmission efficiency is reduced; saccharide is used as a solution medium instead of water, so that the sintering surface is increased and the strength of the porous ceramic is improved; the manganese oxide and the yttrium oxide are added, so that the merging and growing process among zirconite crystal grains is accelerated, the crystal form of zirconium oxide is stabilized at high temperature, cracks caused by crystal form transformation are avoided, the strength of the zirconite porous ceramic is further improved, and the prepared zirconite porous ceramic is stable in high-temperature performance, high in strength and low in heat conductivity coefficient.

This application relates to the field of metal surface treatment materials, specifically disclosing a silicon-integrated inorganic supercrystalline thermal energy powder and its preparation and application methods. The silicon-integrated inorganic supercrystalline thermal energy powder comprises raw material A and raw material B. Raw material A includes the following: magnesium oxide, sodium fluoroaluminate, sodium polyphosphate, zinc oxide, crystalline tin tetrachloride, silicon dioxide, and boric acid. Raw material B includes the following raw materials in parts by weight: spodumene, lithium carbonate, titanium dioxide, zinc silicate, sodium carbonate, antimony trioxide, albite, fluorite, boric acid, sodium hydroxide, and yttrium oxide. The inorganic supercrystalline thermal energy powder of this application has advantages such as corrosion resistance and oxidation resistance, good thermal stability, no damage from thermal cycling, high hardness, wear resistance and high temperature resistance, energy saving, water scale reduction, and the ability to replace organosilicon high-temperature resistant special coatings, baking paints, enamel paints, and ceramic floor glazes.

The invention relates to preparation of a ZTA composite ceramic material, and belongs to the field of inorganic nonmetal composite materials. The raw material composition formula comprises aluminum oxide, zirconium oxide, zirconium dioxide, yttrium oxide, magnesium oxide and titanium dioxide. The low-sodium microcrystalline alumina powder with the original grain size of 0.40 [mu] m is selected and ground to the original grain size in advance, so that zirconia can be more uniformly distributed between alumina grain boundaries, which is a precondition for obtaining more uniform ZTA. Zirconium dioxide is creatively introduced, and compared with a conventional method in which stable zirconium oxide is directly used, the cost of ZTA is greatly reduced. The pre-calcined granulation powder is adopted, so that a ZTA product which is uniformly mixed in the early stage is cured by adding a stabilizer, and then the uniform and stable ZTA ceramic can be obtained through later-stage forming and firing.

The invention belongs to the technical field of ceramic materials, and particularly discloses whisker toughened zirconium oxide-aluminum oxide composite ceramic and an additive manufacturing method thereof, the composite ceramic comprises the following components by mass: 94 parts of zirconium oxide toughened aluminum oxide ceramic and 5 parts of silicon carbide whisker; the zirconium oxide toughened aluminum oxide ceramic is prepared from the following components in parts by mass: 76 parts of aluminum oxide and 24 parts of zirconium oxide, and 3mol% of yttrium oxide is added into the zirconium oxide. According to the whisker toughened zirconium oxide-aluminum oxide composite ceramic and the additive manufacturing method thereof, the preparation method has unique design of components and process, and the preparation of a high-density and high-performance ceramic-based composite material part based on a fused deposition modeling technology is successfully realized. Further, the prepared silicon carbide whisker toughened zirconium oxide-aluminum oxide-based composite ceramic has relatively high density and excellent obdurability.

The invention relates to the technical field of high-temperature alloy materials, and provides an N10276 profiled bar and a forming method thereof.The surface of a blank is coated with a three-layer composite sheath, the blank is heated in a partitioned and gradient mode, the temperature of a side wing plate area is 50-100 DEG C higher than that of a web plate area, the metal fluidity of a side wing plate is improved, cogging rolling, four-roller reciprocating finish rolling, partitioned and gradient cooling and secondary solution treatment are conducted, and the N10276 profiled bar is obtained. A nitric acid and hydrofluoric acid mixed solution is used for pickling and stripping the composite sheath, an oxide layer is removed, intergranular corrosion is avoided, a triple sheath synergistic protection mechanism is adopted, oxygen is physically isolated by outer stainless steel, and heat loss is inhibited by a middle yttria-stabilized zirconia ceramic fiber layer.

The invention belongs to the technical field of ceramic slurry, and particularly relates to ceramic slurry and a preparation method and application thereof.The ceramic slurry comprises inorganic components and organic components, the inorganic components comprise inorganic additives and glass powder, the inorganic additives comprise Al2O3, ZrO2 and Y2O3, and the organic components comprise modified acrylic resin, organic solvent and auxiliaries. By controlling the relative content of carboxyl and ester groups in the modified acrylic resin and utilizing the polarity difference of functional groups, selective adsorption of inorganic powder is realized, so that the dispersion uniformity of the powder in the ceramic slurry is remarkably improved, segregation of yttrium oxide is effectively inhibited, and the service life of the ceramic slurry is prolonged. Therefore, monoclinic-phase zirconium oxide, tetragonal-phase zirconium oxide and cubic-phase zirconium oxide with a proper proportion can be formed in the sintered ceramic substrate, further the bending strength of the ceramic substrate is remarkably improved, and the ceramic substrate is particularly suitable for manufacturing miniaturized and thin electronic components.

The invention provides a preparation method and application of ceramic slurry for high-temperature bonding of aluminum nitride ceramics, and relates to the technical field of high-temperature ceramic materials.The preparation method comprises the following steps that firstly, an organic carrier is prepared, a polymer binder, an organic solvent, a plasticizer and a dispersing agent are weighed according to the weight ratio and stirred at the temperature of 60-70 DEG C till complete dissolution and clarification are achieved for use; 2, an inorganic functional phase is prepared, aluminum nitride powder, yttrium oxide powder and alkaline earth metal oxide powder are weighed according to the weight proportion and placed in a ball milling tank to be evenly mixed, the obtained ceramic slurry serves as a bonding layer, the tolerable temperature can reach 1000 DEG C or above and is far higher than that of metal brazing filler metal, and the ceramic slurry is suitable for severe environments such as aerospace and high-temperature sensors. The main components of the bonding layer are consistent with the base material, and the thermal expansion coefficient is highly matched, so that the thermal stress can be greatly relieved, and the failure of the device caused by thermal fatigue in the temperature cycle is avoided.

The invention relates to the technical field of alloy powder preparation, and particularly discloses alloy powder for laser surfacing and a preparation method thereof, and the alloy powder for laser surfacing comprises 8-12% of nickel (Ni), 4-6% of chromium (Cr), 2-3% of molybdenum (Mo), 1-2% of boron (B), 10-15% of titanium carbide (TiC), 0.5-1% of yttrium oxide (Y2O3), 0.5-1% of silicon (Si), 0.1-0.3% of carbon (C) and the balance of iron (Fe). Fe is used as a matrix, corrosion-resistant and solution strengthening elements such as Ni, Cr and Mo are accurately matched, a low-content Y2O3 rare earth element and a TiC nano strengthening phase are introduced, Y2O3 effectively inhibits grain coarsening in the surfacing process, the brittleness problem caused by the traditional high rare earth content is avoided, TiC nano particles are evenly dispersed in the matrix and form a composite strengthening structure with a Cr7C3 hard phase, the hardness of a surfacing layer is improved, and the hardness of the surfacing layer is improved. The wear-resistant life is prolonged.

The invention relates to the field of suspension plasma spraying, in particular to a long-service-life suspension plasma spraying thermal barrier coating based on a platinum-aluminum coating and a preparation method of the long-service-life suspension plasma spraying thermal barrier coating. The preparation method comprises the following steps: preparing a vertical crack or columnar-like structure ceramic layer on the surface of a platinum modified aluminide bonding layer with lower roughness by using suspension slurry prepared from fully-stable tetragonal phase yttrium oxide stabilized zirconium oxide powder and adopting suspension plasma spraying suspension, so as to obtain a thermal barrier coating system with long service life. The problems that in the prior art, due to stress existing between a ceramic layer prepared through plasma spraying and a low-roughness platinum modified aluminide bonding layer, cracks are continuously formed and expanded at an interface, and the service life of a thermal barrier coating system is short are solved. The long-life thermal barrier coating system can be prepared on the platinum modified aluminide bonding layer through suspension plasma spraying.

The invention discloses a high-corrosion-resistance yttrium oxide coating for semiconductor equipment and a preparation method of the high-corrosion-resistance yttrium oxide coating, and belongs to the technical field of coatings. According to the high-corrosion-resistance yttrium oxide coating for the semiconductor equipment and the preparation method of the high-corrosion-resistance yttrium oxide coating, a SiC transition layer is formed on the surface of a carbon-containing matrix; and an yttrium oxide ceramic coating is deposited on the SiC transition layer in an SPPS plasma spraying mode. The SiC transition layer is firstly formed on the carbon-containing substrate, then the Y2O3 coating is deposited through solution precursor plasma spraying, and a structure with both interface stability and surface protection is formed. SiC is thermally compatible with a substrate, so that undercut, warping and stripping can be inhibited; the dense Y2O3 layer can form a non-volatile protective phase in fluorine-containing / chlorine-containing plasma, thereby reducing the material removal rate and reducing particle release.

The invention discloses a PTC ceramic material and a preparation method thereof, and relates to the technical field of PTC, and the PTC ceramic material is prepared from the following components: 50-65 parts of barium titanate, 12-16 parts of lead tetraoxide, 0.1-0.3 part of yttrium oxide, 0.1-0.3 part of lanthanum oxide, 6-15 parts of modified silicon boride, 4-10 parts of aluminum oxide, 1-3 parts of ammonium polyacrylate, and 3-6 parts of polyvinyl alcohol. Through synergistic cooperation of a barium titanate main body and functional fillers such as modified silicon boride, leap-type improvement of the comprehensive performance of the PTC ceramic material is realized, on the basis of maintaining excellent PTC characteristics, the heat conductivity coefficient and the breaking strength of the material are effectively improved, the thermal shock resistance and the mechanical reliability are remarkably enhanced, and the PTC ceramic material has good application prospects. The method is especially suitable for the high-end application fields of automotive electronics, industrial control, high-power LED driving and the like.

The invention relates to the technical field of titanium alloy pipes, in particular to a titanium alloy pipe preparation method which comprises the following steps: S1, base material preparation, S2, base material pretreatment, S3, cladding material preparation, S4, cladding treatment and S5, post-treatment. According to the method, after the cladding layer is formed on the surface of the titanium alloy pipe by matching the basic powder, the reinforced phase powder and the additive with the cladding treatment process, the basic powder forms a tough metal collective to provide stable support for the reinforced phase, and the reinforced phase powder treated by the silane coupling agent forms a multi-scale reinforced network in a matrix; boron carbide serves as a superhard phase to directly resist abrasion, nano yttrium oxide refines grains through a pinning effect, crack propagation is prevented, the abrasion-resistant life of the pipe is remarkably prolonged, and the service reliability of the pipe is remarkably improved.

The invention relates to the technical field of synthesis and processing of ceramic materials, and discloses a multiphase composite coated high-dielectric-constant ceramic material and a preparation method of the multiphase composite coated high-dielectric-constant ceramic material. 11%-13% of strontium titanate; 5%-7% of holmium oxide; 5%-6% of lead magnesium niobate; 6%-7% of titanium dioxide; 2%-3% of yttrium oxide; 3%-4% of magnesium oxide; 3%-4% of bismuth oxide; 2%-3% of lithium carbonate; 4%-5.5% of silicon dioxide; 1%-2% of zinc oxide; 2.5%-3.5% of manganese dioxide; 6%-7% of copper oxide; 3%-4% of glass powder; 0.05% to 0.08% of lanthanide series elements; through the steps of component pretreatment, ball milling and mixing, drying and sieving, forming, sintering and post-treatment, the component activity is improved through high-temperature calcination pretreatment, and directional growth of crystal grains in the components can be promoted by precisely controlled sintering temperature; the prepared ceramic material has the advantages of high dielectric constant, low dielectric loss, excellent densification effect and good mechanical property.

The invention discloses an Nb-Si-Ti-Cr-Al-Hf alloy turbine ultrahigh-temperature investment casting method. The method comprises the following steps: preparing an alloy turbine ultrahigh-temperature investment casting shell; performing ultrahigh-temperature investment casting on the alloy turbine; and post-processing the alloy turbine casting. The microstructure and the mechanical property of the Nb-Si-based alloy are improved through alloying, the solidification path of the alloy is changed, the eutectoid reaction of metastable-phase Nb3Si is promoted, and the comprehensive performance is improved. Through the rare earth yttrium oxide shell, the problem that the alloy reacts with the shell is solved; high surface quality, strength and thermal shock resistance of the alloy turbine are ensured by regulating and controlling the powder-liquid mass ratio of the slurry and the number of shell layers; and a casting of which the tail end of the blade can be completely filled and has no metallurgical defect is cast through an induction suspension smelting technology, so that the alloy turbine cast by the ultra-high-temperature investment casting can meet the actual application requirement.

A solid oxide fuel cell is disclosed. The solid oxide fuel cell includes: an anode support electrode; a solid oxide electrolyte disposed on the anode support electrode; and a cathode electrode disposed on the solid oxide electrolyte. The anode support electrode includes: a first support layer having a porous structure and including a cermet of nickel and first yttria-stabilized zirconia containing yttria in a proportion of 1 mol% to 5 mol%; a second support layer which has a porous structure, is provided on the first support layer, and is formed from metal ceramic of nickel, second yttria-stabilized zirconia having a higher yttria content than the first yttria-stabilized zirconia, and alumina; and an anode functional layer which is provided on the second support layer so as to be in contact with the solid oxide electrolyte, and which is formed from a cermet of yttria-stabilized zirconia and nickel.

Disclosed is a chamber component of a processing chamber, the chamber component comprising a body and a coating on at least one surface of the body. The coating comprises about 89 mol % to about 93 mol % Y2O3 and about 7 mol % to about 11 mol % ZrO2. The coating has a hardness of about 1-50 GPa.

The invention relates to the technical field of surface modification, in particular to a preparation method of silicon carbide modified powder. The ceramic material is characterized by comprising the following raw materials in parts by weight: 76-82 parts of silicon carbide powder, 8-12 parts of carbonyl nickel powder, 2-4 parts of aluminum powder, 0.5-1.2 parts of nano yttrium oxide, 2-4 parts of yttrium oxide stabilized zirconium oxide, 1-2 parts of a first additive, 1-2.5 parts of a second additive and 1-2.5 parts of a modified adhesive. Silicon dioxide generated by reaction of silicon hydroxyl on the surface of silicon carbide and oxygen is promoted by the first additive to uniformly deposit in particle gaps to form a continuous and compact initial oxide film, and meanwhile, the thermal expansion coefficient is between that of silicon dioxide and that of silicon carbide, so that the thermal stress difference between the silicon dioxide oxide film and a silicon carbide substrate is effectively buffered; the risk of film cracking caused by thermal expansion mismatch is reduced, and the oxidation resistance of the material is improved.

The invention discloses a high-temperature-resistant passive strain gauge for gas turbine blade monitoring and a preparation method and application thereof, and belongs to the technical field of gas turbine health monitoring. The high-temperature-resistant passive strain gauge comprises a strain gauge substrate, an insulating layer, a snakelike sensitive grid, a fiber bragg grating (FBG) and a yttria-stabilized zirconia (YSZ) protective layer. The strain gauge has the beneficial effects that aiming at the limitation of a traditional sensor in a high-temperature (greater than or equal to 1200 DEG C), high-frequency vibration and corrosion environment, the strain gauge adopts the high-temperature-resistant platinum-tungsten alloy snakelike sensitive grid, the single crystal aluminum oxide ceramic substrate and the sapphire fiber bragg grating to transmit a strain signal through wavelength shift, and an external power supply is not needed; and the Ir-Re alloy is brazed and fixed to the microgroove in the surface of the blade, the shearing strength is high, and the service life is long. The method overcomes the technical bottleneck of strain measurement in a high-temperature environment, is suitable for scenes of aero-engines, gas turbine blades and the like, and remarkably reduces the maintenance cost and improves the monitoring reliability.

The invention provides a dielectric filler-doped solid electrolyte, a lithium metal battery and a preparation method, the dielectric filler-doped solid electrolyte comprises a polyether matrix, and the polyether matrix is formed by dispersing a lithium salt and a dielectric filler, the dielectric filler is two or more of barium titanate (BaTiO3), strontium titanate (SrTiO3), zirconium oxide (ZrO2), hafnium oxide (HfO2), titanium oxide (TiO2), cerium oxide (CeO2), zinc oxide (ZnO), lanthanum oxide (La2O3), aluminum oxide (Al2O3), tantalum oxide (Ta2O5) and yttrium oxide (Y2O3).

The invention discloses a method for preparing YAG transparent ceramic by two-step sintering, which comprises the following steps: 1) weighing yttrium oxide powder and aluminum oxide powder according to a stoichiometric ratio, mixing, and carrying out solid-phase reaction to synthesize YAG powder; 2) performing dry grinding and wet grinding on the obtained YAG powder to obtain mixed slurry; 3) drying the obtained mixed slurry to obtain powder, and performing compression molding and cold isostatic pressing to obtain a ceramic biscuit; and 4) pre-sintering the obtained ceramic biscuit in an oxygen-containing atmosphere, embedding the pre-sintered ceramic with oxide particles, and carrying out hot isostatic pressing sintering to prepare the YAG transparent ceramic. On the basis of obtaining the YAG transparent ceramic with high optical quality, a microstructure with a fine grain size can be obtained, and good mechanical properties are considered; the preparation method is simple, the equipment cost and energy consumption are low, the traditional annealing step can be omitted, and a new thought can be provided for preparation of the high-performance YAG transparent ceramic.

The invention belongs to the technical field of refractory materials for hydrogen metallurgy, and discloses a high-strength heat-insulating castable for hydrogen metallurgy as well as a preparation method and application of the high-strength heat-insulating castable. The invention discloses a high-strength heat-insulating castable which comprises the following raw materials in percentage by mass: 15-25% of modified aluminum oxide hollow spheres with the particle size of 5-3mm, 7-13% of modified aluminum oxide hollow spheres with the particle size of 3-2mm, 2-4% of modified aluminum oxide hollow spheres with the particle size of 2-1mm, 7-11% of modified perlite with the particle size of 3-0.074 mm, 18-28% of quartz powder, 4-6% of silicon dioxide powder, 25-35% of pure calcium aluminate cement and 0.5-2% of yttrium oxide powder. A water reducing agent accounting for 0.05-0.15% of the total mass of the raw materials, a pore forming agent accounting for 0.03-0.07% of the total mass of the raw materials and water accounting for 17-21% of the total mass of the raw materials are added. The castable disclosed by the invention has the comprehensive properties of high strength, low heat conductivity, high volume stability and excellent H2 / CO erosion resistance, and meets the comprehensive harsh requirements of hydrogen metallurgy application scenarios.

The invention discloses lithium-free high-heat-resistance ceramic pug and a preparation method thereof, and relates to the technical field of ceramic materials. When the lithium-free high-heat-resistance ceramic pug is prepared, aluminum oxide reacts with 3-(2, 3-epoxypropoxy) propyltrimethoxysilane to prepare pre-modified aluminum oxide; reacting the pre-modified aluminum oxide with starch to obtain modified aluminum oxide; mixing ethyl acetoacetate, isopropanol, zirconium oxychloride, aluminum sec-butoxide, polyvinylpyrrolidone and N-N dimethylformamide to prepare a spinning solution, performing electrostatic spinning, and then immersing the spinning solution into the yttrium oxide sol to prepare aluminum oxide-zirconium oxide-yttrium oxide composite fibers; stirring and mixing the modified aluminum oxide, talc, aluminum oxide-zirconium oxide-yttrium oxide fibers, hydroxypropyl methyl cellulose, glycerol, oleic acid, polyethylene glycol and water, and performing vacuum pugging to obtain the lithium-free high-heat-resistance ceramic pug. The lithium-free high-heat-resistance ceramic pug prepared by the invention has good thermal shock resistance and bending strength after being sintered.

The invention discloses a method for wrapping high-refractive-index ceramic powder with a low-refractive-index product layer and a ceramic material, and relates to the technical field of ceramic additive manufacturing. The method comprises the following steps: forming a low-refractive-index product layer on the surface of ceramic powder through a physical vapor deposition method, a chemical vapor deposition method or a hydrothermal method; the material of the low-refractive-index product layer comprises at least one of silicon dioxide, aluminum oxide, yttrium oxide or yttrium aluminum garnet; the ceramic powder is high-refractive-index ceramic powder and comprises at least one of silicon carbide, silicon nitride or aluminum nitride. According to the method, on the premise that the powder body is prevented from being damaged and impurities are prevented from being introduced, a coating layer which is uniform, compact and good in refractive index matching is formed, and therefore the curing depth and printing reliability of the high-refractive-index ceramic powder in photocuring forming are effectively improved.

The application provides a ceria / yttria composite stabilized zirconia grinding medium and a preparation method. The method comprises the following steps: step one, mixing zirconia, ceria, yttria and kaolin, and then adding an appropriate amount of dispersant and water to obtain a slurry; step two, performing centrifugal spray drying on the slurry to obtain ceria / yttria composite stabilized zirconia powder; step three, adding the ceria / yttria composite stabilized zirconia powder into a binder, and then rolling to form a green body of spherical grinding medium; and step four, sintering and polishing the green body of spherical grinding medium to obtain the ceria / yttria composite stabilized zirconia grinding medium. The method can obtain low particle size and high specific surface area through high-temperature ball milling, and can also promote the solid solution of the stabilizer into the zirconia crystal lattice through heat treatment, so as to improve sintering activity, reduce sintering temperature and reduce production cost.