The invention relates to an offshore loading, unloading and mooring system for liquid bulk carriers as well as a mooring method, and the invention is characterized in that the mooring system consists of three sets of mooring device; the mooring device is formed by using connecting components to connect a buoy, a suspension bullback-weight, a chassis bullbacke weight and a anchoring base one by one; when in mooring, each set of mooring device connects the buoy and a carrier together by connecting components, wherein, two sets of mooring device are connected with the head of the liquid bulk carrier; another set of the mooring device is connected with the stern of the liquid bulk carrier; the three sets of mooring device are in Y-shaped arrangement; the mooring system can anchor the liquid bulk carrier in an off-shore sea area to load or unload materials; compared with the prior art, the invention has the advantages of small occupation sea area, low investment, short construction cycle, convenient operation, safety and reliability. Moreover, the invention does not take up shore-line resources, and is easy to be recovered and ruled, as well as especially suitable for the loading and unloading of the liquid bulk carriers.