The invention relates to a non-phosphate film agent, comprising the following components by weight percent: 2.5-4.5% of succinic acid, 0.8-2% of sodium molybdate, 0-3% of sodium nitrate, 0-5% of citric acid, 0-0.5% of sodium fluoride, 0-0.8% of tannin, 0-1.5% of oxalic acid, 0-0.05% of sodium dodecyl sulfate, the balance of water. The invention has the advantages that: the non-phosphate film agent contains no phosphor, thus being really environmentally friendly; antirust performance is good; combining power with molding powder and paint and adhesive force are all excellent, thus meeting ROHS standard; when in use, aluminum alloy work piece, galvanized work piece and steel work piece can be placed in the same bath solution for coating, thus greatly simplifying the production technology andreducing equipment investment; and suspended matter produced when being continuously used for three months is only 10-20 kilograms, thus solving the difficult problem that one day is stopped in production per week for clearing phosphated slag when using phosphoric film agent.