The invention discloses a concrete of strength grade C55 for a profile steel reinforced concrete structure. The concrete contains the ingredients: cement, fine aggregates, coarse aggregates, water, an efficient water reducing agent, an antifoamer, silica fume, fly ash and a composite excitant, wherein the ratio (kg/m<3>) of the cement to the fine aggregates to the coarse aggregates to the water to the efficient water reducing agent to the antifoamer to the silica fume to the fly ash to the composite excitant is 330: 713: 1186: 160: 6: 1: 30: 80: 2.5. A preparation method of the concrete comprises the steps of firstly, uniformly mixing the polycarboxylic acid efficient water reducing agent and the composite excitant with the weighed water so as to obtain a mixture, sequentially adding the fine aggregates and 1/3 the total weight of the mixture into a stirrer according to a weight ratio, carrying out stirring, adding the coarse aggregates and 1/3 the total weight of the mixture into the stirrer, carrying out stirring, adding the cement, the silica fume and the fly ash into the stirrer, carrying out stirring, adding the antifoamer and the remaining mixture into the stirrer, carrying out stirring, and carrying out discharging. The concrete can be used for remarkably improving the bonding property between profile steel and the concrete in a state of nature, and respective mechanical properties and mutual cooperated working performance of two kinds of materials, i.e., the steel and the concrete are effectively exerted, so that the bearing capacity and use performance of structural elements are substantially improved, and the durability of structures is improved.