Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings comprises A compositions, B compositions and a C composition, wherein the A compositions comprise the following substances in parts by weight: 25-35 parts of polyaspartic acid ester resin, 20 parts of an aromatics mixed solvent, 8-10 parts of nano-scale ceramic powder, 2-4 parts of mica powder, 10-18 parts of diacetone alcohol, 3-8 parts of ethylene glycol monobutyl ether, 7-11 parts of a cellulose thickener solution with the mass percent of 2%, 1.0-1.4 parts of a polyphosphate dispersing agent solution with the mass percent of 10%, 1-3 parts of an emulgator, 0.1-0.3 part of sodium hydroxide, 30-50 parts of ethyl alcohol, 70-100 parts of deionized water, 140-180 parts of titanium dioxide; the B compositions comprise the following substances in parts by weight: 3-5 parts of a paint curing agent, 0.02-1 part of an initiator, 1 part of a dispersing agent, 0.6 part of a flatting agent, 0.3 part of an antifoaming agent, 0.3 part of a defoaming agent, 25 parts of a modified ammonia curing agent, 2-4 parts of tetrachloroisophthalonitrile, 3-5 parts of a dry film antiseptic; the C composition is an environment-friendly color mixed-phase inorganic pigment.