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44results about How to "The preparation process is economical and practical" patented technology

Supported nickel-based alloy catalyst as well as preparation method and application thereof

The invention discloses a supported nickel-based alloy catalyst as well as a preparation method and application thereof. The supported nickel-based alloy catalyst comprises a carrier and a nickel-based alloy supported by the carrier. The nickel-based alloy is a NixMyCz alloy, wherein x is greater than or equal to 1 and less than or equal to 10, y is greater than or equal to 1 and less than or equal to 10, and z is greater than or equal to 0 and less than or equal to 5; M is selected from at least one of iron, copper, cobalt, zinc, molybdenum, palladium, silver, gallium, indium, tin, germanium,bismuth and lead; in addition, when z is greater than 0, M is not indium, the total mass of the nickel-based alloy is 1 to 50 percent, and the balance is a carrier. The catalyst provided by the invention has the advantages of stable structure, good thermal conductivity, high permeability, high conversion rate, high selectivity, high activity, high mechanical strength, easiness in forming and filling, high throughput, low pressure drop and the like. The supported nickel-based alloy catalyst is a good catalyst for reactions for preparing methyl glycollate, ethylene glycol and ethanol by hydrogenation of dimethyl oxalate.
Owner:EAST CHINA NORMAL UNIV

Cellulose solvent, and preparation method and application thereof

ActiveCN110256698AShorten the range of speciesShorten the scope of useBulk chemical productionCelluloseSolubility
The invention relates to a cellulose solvent, and a preparation method and application thereof. The preparation method for the cellulose solvent comprises the following steps of: mixing an organic base having a heterobicycle in its chemical structure with an organic solvent, placing the formed mixture in a three-necked flask, introducing nitrogen, dropwise adding an acidic reagent to a reaction system under magnetic stirring, and allowing a temperature to be kept at 30 DEG C or below in the whole reaction process so as to obtain a transparent mixture; continuing stirring the mixture at room temperature to realize full reaction of the mixture, allowing non-imidazole ionic liquid to be precipitated from an organic phase, and carrying out separation to obtain the non-imidazole ionic liquid; and heating the non-imidazole ionic liquid under the protection of an inert gas so as to obtain the dried cellulose solvent. According to the invention, the dissolution effect of cellulose in the relatively-inexpensive non-imidazole ionic liquid is improved through the preparation and utilization of the non-imidazole ionic liquid cellulose solvent; and in particular, the maximum solubility of cellulose is increased, the dissolution time of cellulose is shortened, and the degradation rate of cellulose is remarkablely reduced.
Owner:BEIJING FORESTRY UNIVERSITY

Composite separation membrane based on fluorine-containing copolymer and having in-situ grown organic framework structure and preparation method and application of composite separation membrane

The invention discloses a composite separation membrane based on a fluorine-containing copolymer and having an in-situ grown organic framework and a preparation method and application of the composite separation membrane. The preparation method comprises the following steps: randomly copolymerizing perfluoro-2,2-dimethyl-1,3-dioxole (PDD), tetrafluoroethylene (TFE) and amine-terminated olefin according to a certain ratio to prepare a fluorine-containing copolymer which can be further subjected to reaction modification; mixing the fluorine-containing copolymer with a PDD-co-TFE binary copolymer according to different ratios to prepare a membrane; and performing Schiff base reaction to grow a covalent organic frame structure sheet layer in situ on the surface of a membrane matrix and introducing a functional group into a frame structure to form a coordination structure so as to obtain the fluorine-containing copolymer composite separation membrane. According to the composite separation membrane prepared by the method disclosed by the invention, binding force between a fluorine-containing copolymer layer and an organic framework structure layer is remarkably enhanced through amino bridging, and the adjustability of an internal pore size is realized through the modification of the internal structure of the pore channel of the organic framework structure layer, so organic gas and inorganic gas (oxygen, carbon dioxide and the like) can be efficiently and selectively separated; and the method has extremely high practical value.
Owner:ZHEJIANG UNIV +1

Modified diatomite/chlorinated butyl rubber damping composite and preparation method thereof

ActiveCN106810776AImproved damping propertiesImprove composite performanceNano zinc oxideStearic acid
The invention discloses modified diatomite / chlorinated butyl rubber damping composite and a preparation method thereof; the modified diatomite / chlorinated butyl rubber damping composite is prepared by mixing, by weight, 100 parts of chlorinated butyl rubber, 1-3 parts of a vulcanizing agent, 1-3 parts of an accelerator, 2-4 parts of stearic acid, 1-2 parts of nano zinc oxide, 2-4 parts of an antiaging agent, 1-3 parts of light weight magnesia, and 2.5-10 parts of modified diatomite; the modified diatomite is prepared by modifying sintered diatomite with hindered phenol. The modified diatomite is prepared by modifying diatomite with hindered phenol and is added to chlorinated butyl rubber, and the damping property, mechanical properties and heat conductivity of the chlorinated butyl rubber can be improved significantly; the modified diatomite / chlorinated butyl rubber damping composite has high practical value.
Owner:SHANGHAI UNIV OF ENG SCI

Hot vulcanization type flame-retardant silicon rubber composite material and preparation method of hot vulcanization type flame-retardant silicon rubber composite material

The invention discloses a hot vulcanization type flame-retardant silicon rubber composite material and a preparation method of the composite material. The composite material is obtained from hot vulcanization type silicon rubber raw rubber and hydrotalcite-like compounds containing zinc, boron and iron through mixed smelting and vulcanization. The preparation method of the material comprises the following preparation steps that firstly, the hot vulcanization type silicon rubber raw rubber and the hydrotalcite-like compounds containing zinc, boron and iron in the proportioning quantity are subjected to uniform mixed smelting; then, vulcanizing agents are added, and sheet discharge is carried out after the uniform mixed smelting; and finally, the vulcanization is carried out. The hot vulcanization type flame-retardant silicon rubber composite material provided by the invention has obvious flame-retardant and smoke suppression performances, and in addition, the physical mechanical performance is excellent. In addition, the preparation process of the composite material is economic and practical, the controllability is high, the cost is low, the large-scale production is easily realized, and the practicability is realized.
Owner:浙江沪天胶带有限公司

Composite separation membrane based on in situ growth organic framework structure of fluorine-containing copolymer and its preparation method and application

The invention discloses a composite separation membrane based on an in-situ grown organic framework structure of a fluorine-containing copolymer, a preparation method and an application thereof. Random copolymerization of a certain proportion of perfluoro-2,2-dimethyl-1,3-dioxole (PDD), tetrafluoroethylene (TFE) and amino-terminated olefins can be further modified by reaction fluorine-containing copolymers, mixed with PDD-co-TFE binary copolymers in different proportions, and formed into membranes, through the Schiff base reaction, the covalent organic framework structure sheets are grown in situ on the surface of the membrane substrate, and the functional The group is introduced into the framework structure to form a coordination structure, and a fluorine-containing copolymer composite separation membrane is obtained. The composite separation membrane prepared by the method of the present invention significantly enhances the binding force between the fluorine-containing copolymer layer and the organic framework structure layer through amine bridging, and realizes the adjustable internal pore size through the internal structure modification of the pores of the organic framework structure layer , can efficiently and selectively separate organic gases and inorganic gases (oxygen, carbon dioxide, etc.), and has extremely high practical value.
Owner:ZHEJIANG UNIV +1
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