The invention discloses a method for editing and regulating
aromaticity and
surface reaction activity of a
nickel (II) norcorrole derivative through an
oxygen bridging skeleton, a product of the method and application of the product, and belongs to the technical field of surface molecular science and molecular
nanotechnology. In a
solution phase pre-synthesis stage, a predetermined number of
oxygen atoms are introduced into a
pyrrole-
pyrrole connecting bond of a
nickel (II) norcorrole molecule, a determined number of C-O-C bridging structures are constructed and formed, and a precursor molecule with a programmable structure is obtained. The precursor is deposited on the surface of a
metal single crystal and is subjected to a surface-assisted dehydrocyclization reaction after thermal annealing treatment, and
oxygen atoms are retained and integrated into a final macrocyclic skeleton. The introduction of the
oxygen bridge systematically regulates and controls the
electronic structure and
aromaticity distribution of the product, and further reconstructs the front line
orbit space distribution. In the surface covalent
coupling reaction, products not doped with oxygen are subjected to multi-path
coupling to form products with different structures, and oxygen bridging products selectively form a single beta-beta site
coupling structure.