The invention provides a composite
lithium supplement diaphragm and a secondary battery thereof, the composite
lithium supplement diaphragm comprises a porous base membrane, a
lithium-containing layer is arranged on one side of the porous base membrane, the lithium-containing layer comprises lithium sources, inorganic
ceramic powder and a binder, the lithium sources are in gradient distribution in the thickness direction of the lithium-containing layer, and the
mass ratio of the lithium source close to one side of the surface of the porous base membrane is relatively low. According to the invention, the irreversible active lithium loss in the first charging process can be effectively compensated without additionally supplementing lithium on the surface of the positive
pole piece or the negative
pole piece, so that the
energy density and the cycle life of the lithium
ion secondary battery can be remarkably improved. The lithium source in the lithium-containing layer of the composite diaphragm is in gradient distribution, and the active lithium content is relatively low on one side close to the surface of the base membrane, so that the contact area of
metal lithium
powder or a lithium-containing compound and the like with the base membrane can be effectively reduced, the risk that micropores of the base membrane are possibly blocked is reduced, and the performance of a
battery cell is further improved.