The invention discloses a polyvinylidene fluoride/polyalkenes sulfonate cation exchange alloy membrane preparation method, which uses polyvinylidene fluoride as a matrix material of the sulfonic acid type cation exchange membrane, and comprises the following methods: completely dissolving polyvinylidene fluoride and alkene sulfonate by organic solvent and water, dissolving a cross-linking agent and an initiator into, and obtaining a homogeneous high-molecular composite solution; and then heating and copolymerizing the composite solution for forming a jelly with an interpenetrating network structure, extruding, solidifying, pelleting, drying, crushing or the like, thereby obtaining a cation exchange alloy powder; finally using a hot pressing moulding method, adding auxiliary material, banburying, milling, pulling sheet, hot pressing, cooling and obtaining polyvinylidene fluoride/polyalkenes sulfonate cation exchange alloy membrane. The cation exchange alloy membrane manufactured by the invention has a high-molecular interpenetrating network structure and a low membrane surface resistor, thereby avoiding a sulfonation reaction step with violent condition, and easily realizing a large scale industrial production.