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54results about How to "Low membrane resistance" patented technology

Preparation method for polystyrene/polyvinylidene fluoride cation exchange membrane

The invention discloses a preparation method for a polystyrene/polyvinylidene fluoride cation exchange membrane. According to the method, polyvinylidene fluoride is used as a matrix material for the membrane. The method comprises the following steps: dissolving polyvinylidene fluoride and then fully mixing dissolved polyvinylidene fluoride with styrene and a cross-linking agent so as to obtain a homogeneous polymer solution; carrying out heat-initiated crosslinking copolymerization so as to obtain gelatinoid with an interpenetrating network structure; subjecting the gelatinoid to polymer physical processing so as to obtain polystyrene/polyvinylidene composite powder; then preparing cation exchange powder by using a sulfonation method for a storng-acid cation exchange resin as reference; and finally preparing the cation exchange membrane by using a hot pressing molding method for a heterogeneous cation exchange membrane. The polystyrene/polyvinylidene fluoride cation exchange composite high polymer membrane prepared in the invention has the interpenetrating network structure, so the structural defect of incompatibility between cation exchange resin powder and a high polymer binder in conventional heterogeneous cation exchange membranes is eradicated, membrane resistance is substantially reduced, and comprehensive properties of the polystyrene/polyvinylidene fluoride cation exchange membrane in the invention are closer to comprehensive properties of cation exchange membranes.
Owner:辽宁易辰膜科技有限公司

Method for preparing carbon nano tube modified bipolar membrane with anion groups

The invention relates to a method for preparing a carbon nano tube modified bipolar membrane with anion groups. The method comprises the following steps of: preparing a sodium carboxymethylcellulose (CMC) aqueous solution or a sodium alginate (SA) aqueous solution by using sodium carboxymethylcellulose or sodium alginate, adding a carbon nano tube with the anion groups, stirring and defoaming under reduced pressure to obtain viscous membrane liquid; casting the viscous membrane liquid in a smooth culture dish to prepare a cation exchange membrane; stirring and dissolving chitosan in 1 to 10 mass percent of acetic acid aqueous solution to prepare 1 to 10 mass percent of chitosan acetic acid aqueous solution, dripping 2.5 volume percent of glutaraldehyde solution slowly with stirring, and defoaming under the reduced pressure to obtain a chitosan (CS) anion membrane liquid; and forming a membrane of the CS anion membrane liquid, fixing the membrane to a prepared cation membrane layer, and airing at room temperature to obtain the bipolar membrane. Due to the adoption of the carbon nano tube modified cation membrane layer with the anion groups, the bipolar membrane has the characteristics of high water dissociation efficiency, small membrane impedance, low tank voltage, high compatibility of two membrane layers and the like.
Owner:FUJIAN NORMAL UNIV

Closed type reverse electrodialysis generation method based on asymmetric ion exchange membranes and device thereof

The invention provides a closed type reverse electrodialysis generation device based on asymmetric ion exchange membranes. A reverse electrodialysis module of the generation device comprises asymmetric zwitterion exchange membranes in alternative arrangement, the diffusion of the ion is convenient, the thickness of the membrane layer is comparatively small at the same time, so that the membrane resistance is effectively reduced; secondly, by adopting the carbon nano-tube / lithium manganate electrode which is free from combining with the cathode and anode chambers, a salinity gradient generationdevice is simplified; furthermore, the device further performs heat exchange process in the system while utilizing the waste heat, and the energy is saved when the waste heat is converted into the electric energy; the working liquid is recycled in the whole generation process, the consumption of the salt and the water is greatly saved. The generation method based on the generation device has theadvantages of being small in membrane resistance, small in concentration polarization phenomenon, and high in generation efficiency. Numerous problems in the prior art are solved, and the method and device have good application prospect in the salinity gradient generation field.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI +1

Dopamine-assisted modified hybrid composite forward osmosis membrane and preparation method thereof

The invention relates to the technical field of membrane separation, and provides a dopamine-assisted modified hybrid composite forward osmosis membrane and a preparation method thereof. An aqueous solution containing inorganic salt and ethanol is used as a coagulating bath; the phase separation speed and the crystallinity of polyvinylidene fluoride are regulated and controlled, a polyvinylidene fluoride membrane surface with a micro-nano structure is constructed, the supporting membrane is endowed with large porosity and high specific surface area, rapid diffusion of a salt solution in membrane pores in the forward osmosis process is promoted, concentration polarization is reduced, membrane resistance is reduced, and the water flux of the forward osmosis membrane is increased; the preparation method comprises the following steps: simultaneously depositing a hydrophilic biomass material and ZIF-8 on the surface of the supporting membrane by utilizing the super-strong adhesion characteristic and multi-active functional groups of dopamine to construct a defect-free hydrophilic hybrid selective cortex and improve the salt rejection rate; ZIF-8 nano particles are generated in situ anduniformly dispersed in the cortex, so that the problem of interfacial compatibility of the hybrid material is solved, and meanwhile, a nano water channel is provided by a cavity in ZIF-8, so that thewater flux is improved while the salt rejection rate is ensured.
Owner:绍兴市俱和环保科技有限公司

Renewable ultrathin multilayer composite forward osmosis membrane as well as preparation method and application thereof

ActiveCN112999899AConcentration polarization is not significantHigh solute retentionMembranesSemi-permeable membranesPolyamidePervaporation membrane
The invention discloses a renewable ultrathin multilayer composite forward osmosis membrane as well as a preparation method and application thereof. The forward osmosis membrane comprises a PE microporous supporting layer, a micro-crosslinked polyamide layer, a super-hydrophilic hybrid layer and an adsorption catalysis functional layer. The preparation method comprises the following steps: performing interfacial polymerization reaction on an acyl chloride monomer and an amine monomer on the surface of a PE microporous membrane, performing heat treatment to generate a micro-crosslinked polyamide layer, reacting with a mixed solution containing a polyphenol compound and polyhedral oligomeric silsesquioxane to generate a super-hydrophilic hybrid layer, and fully contacting with a metal compound aqueous solution, and reducing metal irons through microwave heatingto generate the super-hydrophilic hybrid layer. The concentration polarization of the PE microporous support membrane is not obvious, the solute rejection rate of the micro-crosslinked polyamide layer is high, the water molecule permeation resistance of the super-hydrophilic hybrid layer is weak, the pollutant removal capacity of the adsorption catalysis functional layer is high, the high-performance and renewable forward osmosis membrane is obtained, and seawater desalination, sewage purification, pollutant catalytic degradation and the like can be achieved.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

A closed reverse electrodialysis power generation method and device based on asymmetric ion exchange membrane

The invention provides a closed type reverse electrodialysis generation device based on asymmetric ion exchange membranes. A reverse electrodialysis module of the generation device comprises asymmetric zwitterion exchange membranes in alternative arrangement, the diffusion of the ion is convenient, the thickness of the membrane layer is comparatively small at the same time, so that the membrane resistance is effectively reduced; secondly, by adopting the carbon nano-tube / lithium manganate electrode which is free from combining with the cathode and anode chambers, a salinity gradient generationdevice is simplified; furthermore, the device further performs heat exchange process in the system while utilizing the waste heat, and the energy is saved when the waste heat is converted into the electric energy; the working liquid is recycled in the whole generation process, the consumption of the salt and the water is greatly saved. The generation method based on the generation device has theadvantages of being small in membrane resistance, small in concentration polarization phenomenon, and high in generation efficiency. Numerous problems in the prior art are solved, and the method and device have good application prospect in the salinity gradient generation field.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI +1

Method for preparing carbon nano tube modified bipolar membrane with anion groups

The invention relates to a method for preparing a carbon nano tube modified bipolar membrane with anion groups. The method comprises the following steps of: preparing a sodium carboxymethylcellulose (CMC) aqueous solution or a sodium alginate (SA) aqueous solution by using sodium carboxymethylcellulose or sodium alginate, adding a carbon nano tube with the anion groups, stirring and defoaming under reduced pressure to obtain viscous membrane liquid; casting the viscous membrane liquid in a smooth culture dish to prepare a cation exchange membrane; stirring and dissolving chitosan in 1 to 10 mass percent of acetic acid aqueous solution to prepare 1 to 10 mass percent of chitosan acetic acid aqueous solution, dripping 2.5 volume percent of glutaraldehyde solution slowly with stirring, and defoaming under the reduced pressure to obtain a chitosan (CS) anion membrane liquid; and forming a membrane of the CS anion membrane liquid, fixing the membrane to a prepared cation membrane layer, and airing at room temperature to obtain the bipolar membrane. Due to the adoption of the carbon nano tube modified cation membrane layer with the anion groups, the bipolar membrane has the characteristics of high water dissociation efficiency, small membrane impedance, low tank voltage, high compatibility of two membrane layers and the like.
Owner:FUJIAN NORMAL UNIV

Solid-state ion conductor and lithium-enrich manganese-based material composite electrode and lithium ion battery

The invention provides a solid-state ion conductor and lithium-enrich manganese-based material composite electrode. The solid-state ion conductor and lithium-enrich manganese-based material compositeelectrode comprises a lithium-enrich manganese-based material and a solid-state ion conductor, and the chemical formula of the lithium-enrich manganese-based material is xLi2MnO3.(1-x)LiMO2, wherein xis greater than 0 and less than 1, and M is one or more of Mn, Ni and Co; and the chemical formula of the solid-state ion conductor is Li<1+a>[AB<2-c>(DO4)3] or Li<2+alpha>E<beta>G<3+gamma>. The invention further provides a lithium ion battery comprising the composite electrode. The solid-state ion conductor has excellent ionic conductivity and is composited in the lithium-enrich manganese-based electrode, and the lithium ion transmission rate of the electrode can be increased. In the battery charging and discharging processes, the solid-state ion conductor participates in the forming process of a solid electrolyte membrane on the surface of the lithium-enrich manganese-based material, the membrane impedance of the lithium-enrich manganese-based positive electrode is lowered, and thusthe rate performance and cycling stability of the lithium-enrich manganese-based electrode are improved.
Owner:CHINA AUTOMOTIVE BATTERY RES INST CO LTD

Preparation method for polystyrene/polyvinylidene fluoride cation exchange membrane

The invention discloses a preparation method for a polystyrene / polyvinylidene fluoride cation exchange membrane. According to the method, polyvinylidene fluoride is used as a matrix material for the membrane. The method comprises the following steps: dissolving polyvinylidene fluoride and then fully mixing dissolved polyvinylidene fluoride with styrene and a cross-linking agent so as to obtain a homogeneous polymer solution; carrying out heat-initiated crosslinking copolymerization so as to obtain gelatinoid with an interpenetrating network structure; subjecting the gelatinoid to polymer physical processing so as to obtain polystyrene / polyvinylidene composite powder; then preparing cation exchange powder by using a sulfonation method for a storng-acid cation exchange resin as reference; and finally preparing the cation exchange membrane by using a hot pressing molding method for a heterogeneous cation exchange membrane. The polystyrene / polyvinylidene fluoride cation exchange composite high polymer membrane prepared in the invention has the interpenetrating network structure, so the structural defect of incompatibility between cation exchange resin powder and a high polymer binder in conventional heterogeneous cation exchange membranes is eradicated, membrane resistance is substantially reduced, and comprehensive properties of the polystyrene / polyvinylidene fluoride cation exchange membrane in the invention are closer to comprehensive properties of cation exchange membranes.
Owner:辽宁易辰膜科技有限公司

Polyvinylidene fluoride/polyalkenes sulfonate cation exchange alloy membrane preparation method

InactiveCN103223304AExcellent electrochemical performanceEliminate incompatible structural defectsSemi-permeable membranesOrganosolvIon exchange
The invention discloses a polyvinylidene fluoride/polyalkenes sulfonate cation exchange alloy membrane preparation method, which uses polyvinylidene fluoride as a matrix material of the sulfonic acid type cation exchange membrane, and comprises the following methods: completely dissolving polyvinylidene fluoride and alkene sulfonate by organic solvent and water, dissolving a cross-linking agent and an initiator into, and obtaining a homogeneous high-molecular composite solution; and then heating and copolymerizing the composite solution for forming a jelly with an interpenetrating network structure, extruding, solidifying, pelleting, drying, crushing or the like, thereby obtaining a cation exchange alloy powder; finally using a hot pressing moulding method, adding auxiliary material, banburying, milling, pulling sheet, hot pressing, cooling and obtaining polyvinylidene fluoride/polyalkenes sulfonate cation exchange alloy membrane. The cation exchange alloy membrane manufactured by the invention has a high-molecular interpenetrating network structure and a low membrane surface resistor, thereby avoiding a sulfonation reaction step with violent condition, and easily realizing a large scale industrial production.
Owner:NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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