The invention discloses a preparation method of a
xylem-derived array type through-pore structure hard carbon negative
electrode material, which comprises the following steps: crushing
plant xylem, washing to remove impurities, and
drying to obtain a hard carbon precursor; under the protection of
inert gas, the hard carbon precursor is heated to 550-700 DEG C for pre-
carbonization treatment for 2-3 h, and a
xylem precursor is obtained; under the protection of
inert gas, the xylem precursor subjected to pre-
carbonization treatment continues to be heated to 1200-1450 DEG C, heat preservation and high-temperature
pyrolysis are conducted for 1-3 h, the array pore channel structure hard carbon material is obtained after washing and
drying, and the
heating temperature rise speed is 2-5 DEG C / min. The hard carbon negative
electrode material disclosed by the invention shows excellent first effect and rate capability. The preparation method disclosed by the invention is simple and feasible in process, wide in
raw material source and low in cost, and the obtained hard carbon negative
electrode material has the advantages of high capacity, excellent rate capability, high initial coulombic efficiency and the like.