The invention discloses a preparation process of calcium carbonate. The preparation process comprises the following steps: (1) adding calcium nitrate into deionized water, and preparing calcium nitrate solution with the mass fraction being 40-60%; (2) adding ammonia water into the calcium nitrate solution, adding calcium hydroxide, and stirring uniformly, thus obtaining refined liquid; (3) ultrasonically atomizing the refined liquid into refined an atomized matter, introducing the refined atomized matter into a carbonization tower, and then adding ammonium hydrogen carbonate to carry out carbonization reaction, thus obtaining an intermediate product, i.e., a calcium carbonate material; (4) after adding the intermediate product (calcium carbonate material) into the deionized water, heating,then adding into a stainless-steel spherical container, placing the spherical container on a grinder, and starting the grinder; (5) carrying out solid-liquid separation on feed liquid obtained in thestep (4), and drying and roasting obtained solid to obtain the calcium carbonate. The preparation process of the calcium carbonate disclosed by the invention has the beneficial effects that the calcium carbonate prepared by the process is high in purity, yield and quality, and energy consumption is low.