The invention provides a high-yield propylene catalytic
cracking catalyst and a preparation method and application thereof.The preparation method comprises the steps that
ammonium sulfate is adopted as an exchanger, a precipitator is added after
rare earth ion exchange and before
ammonium sulfate exchange, the precipitator and
rare earth ions preferentially generate a
precipitation precursor of
rare earth oxide, and then the
precipitation precursor of the rare earth
oxide is obtained; therefore, the rare earth modified Y-type
molecular sieve with low
sulfate radical content, high
crystallinity and good stability is prepared. Fully and uniformly mixing water, the rare earth modified Y-type
molecular sieve, the ZSM-5
molecular sieve, clay and a binder, and then carrying out homogenizing,
spray drying and third
roasting to prepare a Na-containing catalyst; the preparation method comprises the following steps: mixing and pulping water and Na-containing catalyst particles, adding a
phosphorus-containing substance to carry out
sodium reduction modification on a Na-containing catalyst, filtering, washing with water, and
drying to obtain a finished product of the catalyst. The finished product catalyst uses the rare earth modified Y-type molecular
sieve with the characteristics as an
active component, so that the finished product catalyst has the advantages of high propylene yield, strong heavy oil conversion capability, high liquid yield and the like.