134 results about "Iron group" patented technology

The principal object of the present invention is to provide a coated cemented carbide tool whose both properties of breakage resistance and wear resistance are improved and whose life is lengthened.The present invention has been made to achieve this object and is related with a coated cemented carbide cutting tool comprising a substrate consisting of a matrix of WC and a binder phase of an iron group metal and a plurality of coated layers provided on a surface of the substrate, in which (a) an innermost layer, adjacent to the substrate, of the coated layers consists essentially of titanium nitride having a thickness of 0.1 to 3 mum, (b) on a mirror-polished cross-sectional microstructure of the said tool, an average crack interval in the coated film on a ridge of a cutting edge and/or rake face is smaller than an average crack interval in the coated layer on a flank face, (c) at least 50% of the cracks in the coated film on the said ridge of the cutting edge and/or rake face have ends of the cracks in the said innermost titanium nitride layer, in a layer above the titanium nitride layer or in an interface between these layers and (d) an average crack length in the coated film on the said ridge of the cutting edge and/or rake face is shorter than an average film thickness on the flank face.According to the present invention, quantitatively specifying the crack intervals and positions of the ends of the cracks in the coated layer results in excellent breakage resistance as well as wear resistance.

There is provided a method of manufacturing a carbon nanotube so as to be able to increase the yield of a web and to increase the amount of a carbon nanotube contained in the web. A high-energy heat source is caused to act on carbon in the presence of catalysts. The catalysts include a main catalyst made of at least one metal which is selected from the group consisting of an iron group element, a platinum group element, and a rare earth element, and an auxiliary catalyst made of a material which causes an exothermic reaction in a process of generating the web including the carbon nanotube. The auxiliary catalyst is made of a material for generating a carbide more stable in terms of thermal energy than a carbide generated by the main catalyst. The free formation energy of the carbide generated from the material is smaller than the free formation energy of the carbide generated by the main catalyst. The main catalyst is made of at least one metal which is selected from the group consisting of Fe, Co, Ni, Rh, Ru, Pd, Pt, Y, La, and Ce. The auxiliary catalyst is made of at least one material selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, B, Al, and Si. Typically the main catalyst is made of Ni-Y, and the auxiliary catalyst is made of Ti.

A process for the preparation of a catalyst useful for conducting carbon monoxide hydrogenation reactions, particularly Fischer-Tropsch reactions; the catalyst compositions, use of the catalyst compositions for conducting such reactions, and the products of these reactions. The steps of the process for producing the catalyst comprise impregnating a powder, or particulate refractory inorganic oxide solids, preferably silica, with a) a soluble compound or salt of a catalytic metal of the Iron Group, preferably cobalt, and b) a soluble compound, or salt, of a Group VIII noble metal, preferably platinum, suitably by sequential contact of the solids with a solution of (a) and a solution of (b), by sequential contact of the solids with a solution of (b) and a solution of (a), or by contact with a solution which contains both (a) and (b). The metals impregnated solids, or particulate solids precursor material, after impregnation with the Group VIII noble metal, is washed with a hydrocarbyl ammonium hydroxide or ammonium hydroxide solution, the material shaped, dried and calcined, and the metals components thereof thereafter reduced to form the finished catalyst. The catalyst formed from the hydrocarbyl ammonium hydroxide or ammonium hydroxide-washed catalyst precursor, quite surprisingly, is more active and selective in conducting a carbon monoxide hydrogenation reaction to produce hydrocarbon waxes, with lower gas make, than a catalyst of corresponding composition similarly prepared except that the catalyst was prepared from a catalyst precursor which was not washed with a hydrocarbyl ammonium hydroxide or ammonium hydroxide solution.

The invention discloses a novel metal-ceramic bond diamond grinding wheel having the high strength and form-holding property in metal bond grinding wheels and the high self-sharpening property in ceramic bond grinding wheels, and a production method thereof. The metal-ceramic bond diamond grinding wheel is produced by: 1, preparing powder mixture out of 60-70% of copper-plated diamond powder, 15-20% of (W, Ti)C powder, 5-10% of tin powder, and 5-15% of iron group powders; mixing according to the above components and ratio to obtain the powder mixture; 2, forming, namely pressing the powder mixture into blanks by pressure forming; 3, sintering, namely subjecting the blanks to inert atmosphere low-pressure sintering, heating the blanks to 850-1050DEG C during sintering, and holding the temperature for 10-30 minutes. The copper-plated diamond powder is composed of particles with average particle size of 5-80 micrometers, and the particles are composed of diamond cores and copper coatings covering the diamond cores. Inert atmosphere during sintering is 5-10Mpa.

The present invention provides a method for producing a sintered NdFeB magnet having high coercivity and capable of being brought into applications without lowering its residual magnetic flux density or maximum energy product and without reprocessing. The method for producing a sintered NdFeB magnet according to the present invention includes applying a substance containing dysprosium (Dy) and/or terbium (Tb) to the surface of the sintered NdFeB magnet forming a base body and then heating the magnet to diffuse Dy and/or Tb through the grain boundary and thereby increase the coercivity of the magnet. This method is characterized in that: (1) the substance containing Dy or Tb to be applied to the surface of the sintered NdFeB magnet is substantially a metal powder; (2) the metal powder is composed of a rare-earth element R and an iron-group transition element T, or composed of R, T and another element X, the element X capable of forming an alloy or intermetallic compound with R and/or T; and (3) the oxygen content of the sintered NdFeB magnet forming the base body is 5000 ppm or lower. The element T may contain nickel (Ni) or cobalt (Co) to produce an anticorrosion effect.

A process for the preparation of a catalyst which is highly active for the synthesis of hydrocarbons from mixtures of hydrogen and carbon monoxide. A silica or silica-containing support is treated with a solution containing both an Iron Group metal, or metals, and nitrous acid, nitric acid, or a nitro-containing organo, or nitro-containing hydrocarbyl compound, or compounds, sufficient to hydroxylate the surface thereof and increase the number of hydroxyl groups on the surface of the support such that the metal component will be highly dispersed, this increasing the activity of the catalyst in a hydrocarbon synthesis reaction as contrasted with that of a catalyst of similar composition, similarly prepared except that the support component of the catalyst was not contacted and simultaneously treated with both the Iron Group metal and the acid.

There is disclosed a die (10) for forming a honeycomb body having a structure provided with groovy slits (2) on a front face thereof, the slits being formed by cell blocks (3) and back holes (4) on a back surface thereof, each hole being communicatively connected with the slit. The die (10) is made of cemented carbide having wear resistance. The cemented carbide is formed by compacting, followed by sintering at high temperature, metal carbide powder of transition metal element series with an iron group metal binder having toughness. A connection area ratio of the back hole (4) and the cell block (3) is 35 to 65%. According to the die for forming a honeycomb body and the die jig for forming a honeycomb body using the same, wear resistance of the die or the die jig can be enhanced when the raw material containing the material having very high hardness such as SiC and the like is extruded as well as the defect in shape of an extruded body due to wear of the die can be overcome.

The invention relates to an iron group fischer-tropsch synthesis catalyst and its preparation method. The iron group fischer-tropsch synthesis catalyst comprises the components of Fe, Cu, K, Li and SiO2 with weight proportion of 100:0.1-15:0.1-10:0.05-10:2-50. On the premise of good fischer-tropsch synthesis activity and methane selectivity, the iron group fischer-tropsch synthesis catalyst is capable of reducing water gas shift reaction activity in a system and enhancing the effective utilization rate of CO reaction gas.

This invention relates to powder metallurgy, more specifically, to methods of fabricating hard alloy items. The invention can be used as an iron, cobalt or nickel base binder for the fabrication of diamond cutting tools for the construction industry and stone cutting, including segmented cutting discs of different designs and wires for reinforced concrete and asphalt cutting used in the renovation of highway pavements, runways in airports, upgrading of metallurgical plants, nuclear power plants, bridges and other structures, monolithic reinforced concrete cutting drills, as well as discs and wires for the quarry production of natural stone and large scale manufacturing of facing construction materials. This invention achieves the objective of providing binders for the fabrication of diamond tools having higher wear resistance without a significant increase in the sintering temperature, as well as higher hardness, strength and impact toughness. The achievement of these objectives by adding an iron group metal as the main component of the binder composition and alloying additives in the form of nanosized powder in accordance with this invention is illustrated with several examples of different type binders for the fabrication of diamond tools.

The patent is about a kind of steel/iron group complex wear resistant board enhanced by tungsten carbide grain and the preparation technology of it. It is made by the compound of tungsten carbide hard grain and tenacious steel/ iron group. The volume percent of tungsten carbide grain is -2.5-+2mm: 30-40%; -2-+1mm: 30-40%; -1- +0.3mm: 25-30%, the steel/iron groups will infiltrate into the interspace of the tungsten carbide hard grains, after they has been melt, the thickness of the composite layer is 4-5mm. This patent has also published the preparation technology of it, adhesion agent is not need according to this patent, the complex board gained not only owns high rigidity and great flexibility module as cream grain, but also owns the high tenacity of metal, and it greatly improves the shock abrasion resistance ability of the wear resistance board.

The present invention provides a cemented carbide with superior strength and toughness by refining the WC in the alloy uniformly and by restricting the growth of coarse WC efficiently. In this cemented carbide, WC with a mean particle diameter of no more than 0.3 microns serves as a hard phase and at least one type of iron group metal element at 5.5-15 percent by mass serves as a binder phase. In addition to this hard phase and binder phase, this cemented carbide contains 0.005-0.06 percent by mass of Ti, Cr at a weight ratio relative to the binder phase of at least 0.04 and no more than 0.2, with the remaining portion being formed from inevitable impurities. In particular, this cemented carbide does not contain Ta.

A multilayer ceramic capacitor includes: a ceramic multilayer structure having ceramic dielectric layers and internal electrode layers alternately stacked, the internal electrode layers being mainly composed of a transition metal other than an iron group, end edges of the internal electrode layers being alternately exposed to a first end face and a second end face; and a pair of external electrodes provided on the first end face and the second end face, wherein the external electrode includes a base conductive layer that includes glass of less than 7 weight % and is mainly composed of a transition metal other than an iron group or a noble metal, and a first plated film that covers the base conductive layer, has a thickness that is half of a thickness of the base conductive layer or more and is mainly composed of a transition metal other than an iron group.

The invention relates to a novel magnetic material and a preparation method thereof. The novel magnetic material is a magnetic material which consists of iron group metals and platinum group metals. The preparation method uses a polyol as a reaction solvent and a reducing agent; various metal ions forming the magnetic material are simultaneously reduced from a solution; and the magnetic material is manufactured. The magnetic material is provided with high hysteresis heating property; at the same time, through changing the composition of the magnetic material, Curie temperature of the magnetic material can be adjusted to be close to the physiological temperature of a human body; and the magnetic material has the advantages of little metal dissolving amount and biological safety, and can be applied to cure a tumor through a magnetic-thermo method.

The cutting member comprises WC, two or more solid solutions of WC and compounds selected from carbides, nitrides and carbonitrides of metals of the groups 4a, 5a and 6a in the Periodic Table, and at least one metal of the iron group; and at least one of the two or more solid solutions being a solid solution having a high Nb or Zr content, whereby the wear resistance and plastic deformation resistance are improved in case of cutting hardly machinable materials such as stainless steel, thereby making it possible to prolong the service life of the cutting member.

An object of the invention is to provide an electroplating solution composition capable of obtaining a plated film excellent in adhesiveness to a coated film and excellent in corrosion resistance without surface treatment. The present invention relates to an organic polymer composite zinc alloy electroplating solution composition containing: (A) 1 to 600 g/l of Zn ion, (B) 1 to 600 g/l of an iron-group-element ion, and (C) 0.1 to 200 g/l, in terms of W ion, of tungstic acid-based compound, and (D) 0.5 to 500 g/l of water-soluble or water-dispersible organic polymer compound having a number average molecular weight of 1,000 to 1,000,000.

An R-T-B based permanent magnet includes main phase grains composed of R₂T₁₄B type compound. R is a rare earth element. T is iron group element(s) essentially including Fe or Fe and Co. B is boron. The magnet contains at least C, Ga, and M selected from Zr, Ti, and Nb in addition to R, T, and B. B is contained at 0.71 mass % to 0.88 mass %. C is contained at 0.15 mass % to 0.34 mass %. Ga is contained at 0.40 mass % to 1.40 mass %. M is contained at 0.25 mass % to 2.50 mass %. A formula (1) of 0.14≦[C]/([B]+[C])≦0.30 and a formula (2) of 5.0≦[B]+[C]−[M]≦5.6 are satisfied, where [B], [C], and [M] are respectively a content of B, C, and M by atom %.

One or more metal salts of at least one iron group metal containing organic groups are dissolved in at least one polar solvent and complex bound with at least one complex former comprising functional groups in the form of OH or NR3, (R=H or alkyl). In addition, at least one insoluble, reducible salt of at least one iron group metal is suspended in the solution. Hard constituent powder and, optionally, a soluble carbon source are added to the solution. The solvent is evaporated and the powder mass is heat treated in inert and/or reducing atmosphere. As a result, a powder mixture is obtained which, after addition of a pressing agent, can be compacted and sintered according to standard practice to form a body containing hard constituents in a binder phase.