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146 results about "Tellurium oxide" patented technology

Tellurium oxide may refer to either of these: Tellurium monoxide, TeO Tellurium dioxide, TeO₂ Tellurium trioxide, TeO₃

Method for preparing tellurium dioxide from tellurium slag

The invention relates to a method for preparing tellurium dioxide from tellurium slag. According to the technical scheme, the method comprises the following steps of: adding tellurium slag to sulfuric acid solution, stirring at normal temperature, adding 10% oxydol at the temperature of 30-40 DEG C, and then heating to 80-90 DEG C, and leaching under normal pressure; adding copper powder to leachate, carrying out replacement reaction at the temperature of 90-95 DEG C for 2 hours, and carrying out solid-liquid separation to obtain copper telluride slag; adding copper telluride slag to sulfuricacid solution, adding 10% oxydol, stirring at the temperature of 90 DEG C for 1 hour, and filtering; adding sodium carbonate to filtrate for neutralizing the filtrate till pH of the filtrate is 3, and filtering; adding NaOH to filter residue, carrying out alkali leaching and stirring at the temperature of 85-95 DEG C for 1 hour, and filtering; and adding H2SO4 to filtrate for neutralizing the filtrate till pH of the filtrate is 6-7, filtering, washing and drying to obtain a product. The method has the characteristics that: low-grade tellurium-containing material discarded by a copper anode mud production enterprise is used as a raw material to produce high-purity tellurium dioxide, the process is reasonable and pollution-free, and the recovery rate of tellurium is high.
Owner:LIAONING UNIVERSITY

Method for comprehensively recovering valuable metal from copper tellurium slag

The invention discloses a method for comprehensively recovering valuable metal from copper tellurium slag. The copper tellurium slag is dissolved by using nitric acid, so that silver, copper and bismuth in the copper tellurium slag are basically dissolved in a solution; tellurium is oxidized into tellurium oxide, thereby entering undissolved slag. Silver, copper and bismuth are separated and recovered via fractional precipitation of the solution; and tellurium is separated and recovered via alkaline leaching of the undissolved slag. The method solves the problems that cost of a conventional process is high, copper recovery rate and tellurium recovery rate are not high, and that silver and bismuth cannot be recovered in the conventional process; influences on the environment of the production process are reduced; a whole process is simple; and pollutions toward the environment is small. The method is simple in the whole production process, low in cost and small pollutions toward the environment, has high comprehensive recovery rate, and realizes complete separation of silver, copper, bismuth and tellurium. The obtained products have high purity; and the recovery rate of silver, copper, bismuth and tellurium is higher than 99%.
Owner:SIHUI CITY HONGMING PRECIOUS METALS

Method for recovering tellurium from high-tellurium residues

The invention discloses a method for recovering tellurium from high-tellurium residues in an efficient and environment-friendly mode. The method includes the steps of breaking the high-tellurium residues, slowly adding hydrochloric acid and hydrogen peroxide into the high-tellurium residues, controlling the temperature and continuously stirring to carry out oxidizing leaching; carrying out liquid-solid separation after the residues are completely dissolved, wherein tellurium oxide as the major element enters leaching solutions, valuable metal such as Pb and Ag enters leaching residues in the mode of chloride salt, and lead and silver residues return to a lead smelting system to recover the valuable metal; and adjusting the pH value of the tellurium-containing leaching solutions to be 5.0-6.0 through sodium hydroxide solutions, obtaining TeO2 sediments, carrying out liquid preparation after TeO2 is roasted and nitrate is removed and returning to the electrodeposition process to directly recover the tellurium. According to the method, the high-tellurium residues is directly leached to recover the tellurium through the hydrochloric acid and the hydrogen peroxide, the direct recovery rate of the tellurium can reach above 95%, so that efficient recovery of the tellurium is realized, the recovery rate of silver can reach above 99.0%, and the recovery rate of lead can reach above 97.6%. The method has the advantages that the technological processes are simple, needed equipment is reduced, the production cost is low, the environment friendliness is high and the comprehensive recovery degree is high, thereby having wide application prospects.
Owner:CHENZHOU CITY JINGUI SILVER IND CO LTD

Preparation method for flexible fabric composite thermoelectric material

The present invention belongs to the field of material science and provides a preparation method for flexible Bi2Te3 / PEDOT: PSS / fabric composite thermoelectric material. The preparation method comprises the following steps: weighing tartrate, bismuth nitrate pentahydrate, tellurium dioxide, potassium hydroxide and deionized water according to the material ratio, and adding the same to a container to form a mixed solution; then putting the fabric into the solution, performing stirring, adding potassium borohydride, performing continuous stirring for a period of time, stopping stirring and placing and heating the container in a thermostatic waterbath for reaction; after the reaction is completed, repeatedly washing the obtained Bi2Te3 / fabric composite material with deionized water and ethanol and then subjecting the obtained material to vacuum drying, and placing a dried product in dimethyl sulfoxide doping PEDOT: PSS mixed solution for processing; and finally performing vacuum drying to obtain Bi2Te3 / PEDOT: PSS / fabric composite thermoelectric material. The flexible fabric thermoelectric material prepared by the method has a broad application prospect in the field of wearable electronics, and has huge market potential.
Owner:SHANGHAI INST OF TECH

Method for extracting high-purity tellurium oxides from copper anode mud

The invention discloses a method for extracting high-purity tellurium oxides from copper anode mud. The method comprises the steps as follows: firstly, sulfuric acid is added in the copper anode mud at first, sodium chlorate is then added in the copper anode mud, the mixture is heated, silver and lead are precipitated in residues and are separated out, and gold, copper, bismuth, tellurium and selenium enter leach liquor; secondly, common salt is added in leach liquor that is processed in the first step, the mixture is mixed and resolved, then gaseous SO2 is pumped in mixed liquor for 1 hour, and gold, tellurium and selenium are reduced and deposited and then are processed through pressure filtration; thirdly, in step A, sulfuric acid is added in deposited residues of the gold, tellurium and selenium, then catalytic agents are added in the mixture, then sodium chlorate is added in the mixture until the color of the deposited residues is transformed into the color of tellurium oxides, and pressure filtration is carried out; in step B, sodium hydroxide is added in the deposited residues that are processed in the step A, the mixture is processed through pressure filtration, and then sodium tellurite and sodium selenite solution are obtained; and fourthly, sulfuric acid is added in sodium tellurite and sodium selenite solution which are obtained in the third step, sodium selenite remains in liquid, and tellurium dioxide is precipitated and separated out.
Owner:湖南省金润碲业有限公司

Novel bismuth smelting separation method

InactiveCN102534257AReduce moistureSolve the problem of high volume and high moistureElemental selenium/telluriumTe elementSlurry
The invention discloses a novel bismuth smelting separation method. According to the method, bismuth compounds and water are mixed and stirred to a slurry state according to a mass ratio being 1:(1-2) to form a slurry mixture, then, sodium hydroxide is added into the slurry mixture according to the bismuth to sodium hydroxide mass ratio being 1:(0.5-0.8), the temperature is controlled to be 90 to 95 DEG C, the materials are stirred for reaction for 1 to 2 hours so that the bismuth is converted into bismuth tellurium oxides to be dissolved into aqueous alkali, then, the filtering is carried out so that bismuth oxides and tellurium-containing solution are separated to respectively obtain bismuth oxides and tellurium lye, the bismuth oxides are washed by water, and the bismuth oxides are reduced and smelted to produce bismuth metal. The novel bismuth smelting separation method has the advantages that the bismuth compounds are converted into the bismuth oxides though alkaline addition, the bismuth oxides have small size, low moisture content and high bismuth content, the smelting energy consumption is reduced, only the bismuth oxides are produced, negative ions such as nitrate radicals, chlorine radicals and carbonic acid radicals are eliminated, poisonous gas generated in the smelting process is eliminated, the bismuth oxides are thoroughly separated from tellurium, nitrate radicals and the like after being filtered and washed, the impurity tellurium is eliminated, the bismuth purity is improved, the bismuth metal is produced through reduction and smelting, and the recovery rate of the bismuth reaches 99 percent.
Owner:SIHUI CITY HONGMING PRECIOUS METALS +1
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