The invention discloses a high-calcium-aluminum slag ball. The high-calcium-aluminum slag ball comprises metallic aluminum (Al), aluminum oxide (Al2O3), silicon dioxide (SiO2), calcium fluoride (CaF2), calcium oxide (CaO), water (H2O) and other inevitable impurities. The component of the slag ball comprises, by weight, 48 parts to 52 parts of the metallic aluminum, 9 parts to 9.9 parts of aluminum oxide, 4 parts to 5 parts of silicon dioxide, 5 parts to 10 parts of calcium fluoride, 20 parts to 24.9 parts of calcium oxide and 0.2 part to 0.5 part of water. When low-carbon steel is smelted, in the steel tapping process, a certain number of high-calcium-aluminum slag balls are added, and therefore, the soluble aluminum proportion in molten steel can be greatly improved, and the contents of ferric oxide and manganese oxide are reduced, and cleanness of the molten steel is improved; and by means of the high-calcium-aluminum slag balls, the deoxidization effect is good, steel slag fluidity is improved, the slag remanufacturing requirement of the refining process is met, and meanwhile, the production cost can be reduced.