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95results about How to "High in manganese" patented technology

High-nickel-series and full-concentration gradient lithium ion battery positive electrode material and preparation method thereof

The invention provides a high-nickel-series and full-concentration gradient lithium ion battery positive electrode material and a preparation method thereof and belongs to the field of lithium ion battery positive electrode materials. The structural formula of the positive electrode material is LiNixCoyMnzO2@LiNiaCobMncO2, wherein x is more than or equal to 0.7 and smaller than or equal to 1.0, y is more than or equal to 0.1 and smaller than or equal to 0.3, z is more than or equal to 0.05 and smaller than or equal to 0.1, a is more than or equal to 0.4 and smaller than or equal to 0.5, b is more than or equal to 0.1 and smaller than or equal to 0.3 and c is more than or equal to 0.25 and smaller than or equal to 0.3; the sum of the x, the y and the z is equal to 1, and the sum of the a, the b and the c is equal to 1; the positive electrode material is spherical and has a core-shell-type structure; in a process from a core of an inner core to the surface of a shell, the contents of nickel, cobalt and manganese are distributed in linear concentration gradient; the content of the nickel is gradually reduced, and the content of the cobalt is not changed or is gradually increased; and the content of the manganese is gradually increased. The invention further provides the preparation method of the high-nickel-series and full-concentration gradient lithium ion battery positive electrode material. The positive electrode material provided by the invention has high capability, high circulating performance and high safety performance.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Flexible manganese oxide nano fibrous membrane and preparation method thereof

The invention relates to a flexible manganese oxide nano fibrous membrane and a preparation method thereof. The preparation method comprises the following steps: dissolving a manganese source a non-manganese metal salt in a solvent, sequentially adding a coupling agent and a surfactant, and uniformly mixing to obtain a uniform and stable precursor solution with a three-dimensional interpenetrating network structure; delivering the precursor solution into a spinneret of an electrostatic spinning device, and connecting the spinneret to a high-voltage power supply to perform electrostatic spinning, thereby obtaining a precursor nano fibrous membrane; and putting the precursor nano fibrous membrane into a box-type resistance furnace, and calcining in an air atmosphere to finally obtain the flexible manganese oxide nano fibrous membrane. The method has the advantages of simple preparation technique and low cost; the obtained manganese oxide nano fibrous membrane has the advantages of favorable flexibility, environment friendliness, low price, higher electrochemical catalytic activity and the like, and thus, can be made into oxidizers, catalysts, adsorbents and other products; and the manganese oxide nano fibrous membrane has wide application prospects in the field of chemical industry.
Owner:嘉兴富瑞邦新材料科技有限公司

Method for preparing white carbon black and manganese fertilizer from manganese leaching residue

The invention discloses a method for preparing white carbon black and manganese fertilizer from manganese leaching residue. The method comprises the following steps: 1, washing the manganese leaching residue with dilute sulphuric acid solution and running water in turn to obtain the residue; 2, conducting reaction between the residue and 25 to 40% strong base solution by mass at 90 to 120 DEG C for 2 to 5 h, and filtering to obtain filtrate; 3, decoloring the filtrate with active carbon and then carboxyl-terminated hyperbranched polyester at 100 to 120 DEG C to obtain the aqueous solution of silicate; 4, adding water and then inorganic acid and carboxyl-terminated hyperbranched polyester for reaction at 40 to 90 DEG C for 0.5 to 2 h to obtain the white carbon black; and 5, drying and dehydrating the residue obtained in step 2 and adding into a high-speed mixer, adding phosphoric acid, anticaking agent and manganese sulfate into the high-speed mixer, and mixing at room temperature for 10 to 20 min to obtain the manganese fertilizer. The method is simple in process and low in cost and is suitable for industrial production; and the silicon dioxide content of the prepared white carbonblack is more than 95% by mass, the specific area is more than 270 m<2> / g and the particle size is less than 50 nm.
Owner:SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES

Aluminum-magnesium alloy welding wire for improving Mn content

The invention discloses an aluminum-magnesium alloy welding wire for improving the Mn content. The aluminum-magnesium alloy welding wire is characterized in that the Mn content in the welding wire is improved by 1.0-2.0 wt%; if calculated in percentage by weight, the other chemical components of the welding wire comprise 4.5-5.5% of Mg, less than or equal to 0.15% of Si, less than or equal to 0.25% of Fe, less than or equal to 0.15% of Cr, less than or equal to 0.15% of Ti, less than or equal to 0.10% of Cu, less than or equal to 0.10% of Zn and less than or equal to 0.15% of Zr; and the balance are Al and inevitable impurity elements. The optimal addition quantity of Mn in the welding wire is 1.5 wt%. Because the Mn content in the aluminum-magnesium alloy welding wire provided by the invention is reached about the maximum solubility of Mn in a solid solution in an aluminum-magnesium alloy phase diagram, the Mn Al6 dispersoid particle is furthest separated out in the aluminum-magnesium alloy, so that the strength of a welded joint can be improved. After a lot of tests are carried out, compared with Al-5Mg alloy welding wires, such as 5356, 5183 and 5087 welding wires imported from a foreign country, the percentage elongation of the welding joint of the welding wire provided by the invention is approximate to that of the imported welding wires, while the yield strength and the tensile strength of the welding wire provided by the invention are improved and are more approximate to the level of an aluminum-magnesium alloy base metal.
Owner:NORTHEASTERN UNIV

Preparing method for electric-conduction and anti-corrosion cobalt and manganese spinel coating

The invention provides a preparing method for an electric-conduction and anti-corrosion cobalt and manganese spinel coating. The preparing method includes the following steps that firstly, surface pretreatment is conducted on a ferrite stainless steel base body; secondly, a cobalt and manganese alloy-manganese hydroxide compound coating is prepared on the surface of the ferrite stainless steel base body on which surface pretreatment is conducted in the first step through a double-electrode electrochemical deposition method; thirdly, first thermal transition treatment is conducted, and the cobalt and manganese alloy-manganese hydroxide compound coating is obtained; and fourthly, second thermal transition treatment is conducted, and the electric-conduction and anti-corrosion cobalt and manganese spinel coating is obtained. The preparing method is simple in technology and low in equipment requirement and cost, the adhesion force between the prepared coating and the base body is good, density is high, the coating comprises an Mn1.5Co1.5O4 spinel layer highest in electric conductivity in a cobalt and manganese spinel system, and harsh working conditions of the surface of a solid oxide fuel cell metal connector can be better met.
Owner:XIAN UNIV OF SCI & TECH

Converter slag fluoride-free fusing agents and method for producing the same

ActiveCN102839252AHigh activityReduce ton consumption costManufacturing convertersSteelmakingMetallic aluminum
The invention relates to converter slag fluoride-free fusing agents and a method for producing the converter slag fluoride-free fusing agents. The converter slag fluoride-free fusing agents comprise metallic aluminum, manganese oxide, aluminum oxide, iron and iron oxide, silica, calcium oxide, magnesium oxide and other unavoidable impurities, and are suitable for slagging in the process of converter steelmaking. Used raw materials are common, balling process is advanced and reliable, and the fluoride-free fusing agents are convenient to use. The converter slag fluoride-free fusing agents and the method for producing the converter slag fluoride-free fusing agents have the advantages of obviously improving reaction kinetics conditions of a molten pool, being high in slag activity, well resolving the problems of steel-bonding of an oxygen lance, metal splashing and poor capacity of sulphur (S)-removing and phosphorus (P)-removing of slag due to re-drying of the slag, lowering tetrafluoroethylene (TFe) content of the slag, increasing yield of ferrum (Fe) in liquid steel, reducing cost of the liquid steel per ton, shortening smelting time, improving content and yield of manganese in the liquid steel, reducing corrosion to a furnace lining, having good slag-splashing and furnace-protection effects, being favorable for environment protection and achieving fluoride-free steel-making due to the fact that fluoride (F-) does not exist, and meeting the requirements for cleaning in the converter steel-making production process.
Owner:西峡县恒基冶材有限公司

Manufacturing method of high manganese high nitrogen low nickel non-magnetic stainless steel and product thereof

ActiveCN106868423AHigh symmetrical stabilityIncreased symmetrical stabilityFoundry mouldsElectric furnaceNiobiumNon magnetic
The invention provides a manufacturing method of a high manganese high nitrogen low nickel non-magnetic stainless steel and a product thereof. The stainless steel is single phase austenite stainless steel which comprises the following chemical components in percentages by mass: greater than 0 but less than or equal to 0.1% of C, less than or equal to 0.01% of S, less than or equal to 0.015% of P, greater than 0 but less than or equal to 1.0% of Si, greater than or equal to 16% but less than or equal to 18% of Mn, greater than 0 but less than or equal to 2% of Ni, greater than or equal to 10% but less than or equal to 14% of Cr, greater than or equal to 1% but less than or equal to 2% of N, greater than or equal to 0.3% but less than or equal to 1% of Cu, greater than or equal to 0.3% but less than or equal to 5% of Mo, greater than or equal to 0.3% but less than or equal to 1% of Nb and the balance of Fe. The manufacturing method comprises the following steps: heating and smelting raw materials, and performing decarbonization, desulfuration and deoxygenation; raising the temperature to 1600 DEG C and adding nickel; adjusting the temperature of a bath to 1550 DEG C, and adding ferromolybdenum, ferrocolumbium and a metal copper; adding a desoxidant for secondary deoxidization, introducing nitrogen, adjusting the temperature of the bath to 1610-1620 DEG C, and adding nitrogen containing ferrochromium; adjusting the temperature of the bath to 1150-1250 DEG C, introducing nitrogen, adding nitrided ferromanganese, pouring, quenching and air cooling, and machining to form a panel, heating the panel to 650-700 DEG C, keeping the temperature for 30min, and performing furnace cooling to room temperature. The stainless steel through deep punching is still non-magnetic, and needs not to be annealed and demagnetized. The manufacturing method is high in nitrogen-increasing efficiency and low in loss of equipment.
Owner:宁波市博祥新材料科技有限公司

Lithium battery waste recycling method and application thereof

The invention provides a lithium battery waste recycling method and application thereof, and relates to the technical field of waste battery recycling. The method comprises the following steps that firstly, reflux extraction is carried out on lithium battery waste by utilizing a countercurrent washing method to obtain a lithium-rich solution and lithium-removed black powder; then the lithium-rich solution and the lithium-removed black powder are treated respectively, aluminum hydroxide and crude lithium carbonate are extracted from the lithium-rich solution through precipitation and reduction methods, and meanwhile, the lithium-removed black powder is subjected to acid dissolution leaching before reduction leaching; metal impurity ions except cobalt, nickel and manganese in a leaching solution are removed by combining the oxidation-reduction property of metal with the modes of extraction, precipitation and the like; and finally, concentrating and crystallizing are carried out, and cobalt-nickel-manganese mixed salt crystals with high manganese content and cobalt-nickel-manganese mixed salt crystals with high cobalt and nickel contents are respectively prepared by utilizing a hot filtering method and a cooling filtering method. The recycling method has the advantages of being simple in technological process and easy to operate, and the purpose of comprehensively recycling valuable metal from the lithium battery waste is achieved.
Owner:GUANGDONG JIANA ENERGY TECH CO LTD +1

Method for removing manganese from molten iron in top and bottom combined blown convertor

InactiveCN102559982AHigh efficiency of manganese removalWide variety of sourcesProcess efficiency improvementSlagScrap
The invention discloses a simple, efficient and low-cost method for removing manganese from molten iron in a top and bottom combined blown convertor. The final manganese content of the convertor is controlled to be less than 0.05 weight percent. The method comprises the following specific steps of: adding steel scrap into the convertor, adding the molten iron into the convertor, adding a demanganization agent into the liquid level of the molten iron, supplying oxygen to the liquid level of the molten iron by using an oxygen lance from the top, supplying stirring gas into the molten iron from the bottom, monitoring the CO content of converter gas, and pouring initial slag out when the inhibition of the carbon oxidation is converted into intense carbon oxidation, wherein the amount of poured slag is not less than 60 percent of the total slag amount; and adding the demanganization agent into the liquid level of the molten iron. Compared with the conventional method for removing manganese by a common blowing process or a convertor duplex manganese removal process, the method has the advantages that: special manganese removal equipment is not required, a mature top and bottom combined blown convertor blowing technology is fully utilized, and the dynamical condition for removing manganese from the molten iron is fully met, the common demanganization agent used as the raw material is used, sources are wide, and price is low.
Owner:HEBEI SHOUGANG QIAN AN IRON & STEEL CO LTD +1

Process method for producing high-pure spherical heavy manganese carbonate

The invention relates to a process method for producing high-pure spherical heavy manganese carbonate. The process method comprises the following steps of a. preparing a manganese carbonate solution; b. preparing an ammonium hydrogen carbonate solution, filling ammonia into the ammonium bicarbonate solution to form an ammonium bicarbonate solution; c. adding water and crystal seeds of manganese carbonate into a reactor, stirring and heating to a temperature of 40-90 DEG C; and d. dropwise adding a manganese sulfate solution and the ammonium bicarbonate solution with equal molar ratio at the same time into the reactor, controlling reaction time for 4-8 hours, washing and suction filtering, and thus high-pure spherical heavy manganese carbonate is obtained, wherein the heavy manganese carbonate is in spherical shapes; average particle size is 10-20 micrometers; manganese content is larger than 44.5% (weight percentage); a tap density is 2.0-2.4 g / cm3, the content of Ca is no more than 100 PPm; the content of Mg is no more than 150 PPm; and the content of Pb is no more than 50 PPm. The high-pure spherical heavy manganese carbonate prepared by the process has high manganese content of manganese carbonate and low content of impurities. Chemical manganese dioxide produced by the high-pure spherical heavy manganese carbonate can effectively increase chemical performance of batteries.
Owner:湖北开元化工科技股份有限公司
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